1,2-DIAMINO-4-(TRIFLUOROMETHOXY)BENZENE

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Names

[ CAS No. ]:
136705-65-2

[ Name ]:
1,2-DIAMINO-4-(TRIFLUOROMETHOXY)BENZENE

[Synonym ]:
(+)-1,2-Bis[(2R,5R)-2,5-diisopropylphospholano]benzene
iPr-DuPhos ligand
MFCD02684549
1,2-Bis[(2R,5R)-2,5-diisopropyl-1-phospholanyl]benzene
(2R,5R)-Pr-duphos
(R,R)-i-Pr-DUPHOS
(-)-1,2-bis[(2R,5R)-2,5-diisoprohylphospholano]benzene

Chemical & Physical Properties

[ Boiling Point ]:
502ºC at 760 mmHg

[ Melting Point ]:
40ºC

[ Molecular Formula ]:
C26H44P2

[ Molecular Weight ]:
418.57500

[ Flash Point ]:
273.4ºC

[ Exact Mass ]:
418.29200

[ PSA ]:
27.18000

[ LogP ]:
7.58700

[ Vapour Pressure ]:
1.02E-09mmHg at 25°C

[ Index of Refraction ]:
n20/D 1.5701

[ Storage condition ]:
2-8°C

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
36/37/38

[ Safety Phrases ]:
26-36/37/39

[ RIDADR ]:
NONH for all modes of transport

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • (3S,6S)-2,7-dimethyloctane-3,6-diol
  • 1,2-bis(phosphino)benzene
  • (3S,6S)-3,6-dihydroxy-2,7-dimethyloctane cyclic sulfate

DownStream

Related Compounds

  • 1,2-Dichloro-4-(trifluoromethoxy)benzene
  • 1,2-difluoro-4-(trifluoromethoxy)benzene
  • 1,2-diamino-4-(p-chlorophenoxy)-benzene
  • 1,2-Diamino-4,5-methylenedioxybenzene, dihydrochloride
  • 1,2-diamino-4-chloro-5-ethylbenzene
  • 1,2-DIAMINO-4,5-DIIODOBENZENE
  • 1-(Furan-2-ylmethyl)-3-(1-((5-phenyl-1,2,4-oxadiazol-3-yl)methyl)pyrrolidin-3-yl)urea
  • N-cyclopropyl-3-(2-methylbenzyl)tetrahydro-2H-pyran-4-sulfonamide
  • tert-butyl (1-(1-(2-methylbenzyl)-1H-benzo[d]imidazol-2-yl)piperidin-3-yl)carbamate
  • 2-Cyclopropyl-3-methyloxolan-3-amine
  • (1-(1-(2-methylbenzyl)-1H-benzo[d]imidazol-2-yl)piperidin-3-yl)methanol
  • tert-butyl ((1-(1-(2-methylbenzyl)-1H-benzo[d]imidazol-2-yl)piperidin-2-yl)methyl)carbamate
  • 2-(chloromethyl)-3-(2-methylbenzyl)-3H-imidazo[4,5-b]pyridine
  • [6-(Aminomethyl)piperidin-2-yl]methanol
  • tert-Butyl 3-((1-(2-methylbenzyl)-1H-benzo[d]imidazol-2-yl)amino)piperidine-1-carboxylate
  • tert-Butyl 3-((1-(2-methylbenzyl)-1H-benzo[d]imidazol-2-yl)amino)pyrrolidine-1-carboxylate
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