1,2-DIAMINO-4-(TRIFLUOROMETHOXY)BENZENE

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Names

[ CAS No. ]:
136705-65-2

[ Name ]:
1,2-DIAMINO-4-(TRIFLUOROMETHOXY)BENZENE

[Synonym ]:
(+)-1,2-Bis[(2R,5R)-2,5-diisopropylphospholano]benzene
iPr-DuPhos ligand
MFCD02684549
1,2-Bis[(2R,5R)-2,5-diisopropyl-1-phospholanyl]benzene
(2R,5R)-Pr-duphos
(R,R)-i-Pr-DUPHOS
(-)-1,2-bis[(2R,5R)-2,5-diisoprohylphospholano]benzene

Chemical & Physical Properties

[ Boiling Point ]:
502ºC at 760 mmHg

[ Melting Point ]:
40ºC

[ Molecular Formula ]:
C26H44P2

[ Molecular Weight ]:
418.57500

[ Flash Point ]:
273.4ºC

[ Exact Mass ]:
418.29200

[ PSA ]:
27.18000

[ LogP ]:
7.58700

[ Vapour Pressure ]:
1.02E-09mmHg at 25°C

[ Index of Refraction ]:
n20/D 1.5701

[ Storage condition ]:
2-8°C

MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
36/37/38

[ Safety Phrases ]:
26-36/37/39

[ RIDADR ]:
NONH for all modes of transport

Synthetic Route

Precursor & DownStream

Precursor

  • (3S,6S)-2,7-dimethyloctane-3,6-diol
  • 1,2-bis(phosphino)benzene
  • (3S,6S)-3,6-dihydroxy-2,7-dimethyloctane cyclic sulfate

DownStream


Related Compounds

  • 1,2-Dichloro-4-(trifluoromethoxy)benzene
  • 1,2-difluoro-4-(trifluoromethoxy)benzene
  • 1,2-diamino-4-(p-chlorophenoxy)-benzene
  • 1,2-Diamino-4,5-methylenedioxybenzene, dihydrochloride
  • 1,2-diamino-4-chloro-5-ethylbenzene
  • 1,2-DIAMINO-4,5-DIIODOBENZENE
  • 3-cyano-6-cyclopropyl-2-(methylsulfanyl)-N-[4-(1H-1,2,3,4-tetrazol-1-yl)phenyl]pyridine-4-carboxamide
  • N-(2-Fluorophenyl)quinazolin-4-amine
  • 2-Amino-5-(4-chlorophenoxy)benzoic acid
  • ethyl 4-((2-methoxybenzyl)carbamoyl)-3,5-dimethyl-1H-pyrrole-2-carboxylate
  • 2-Amino-5-(3-chlorophenoxy)benzoic acid
  • N-(1-cyanocyclohexyl)-2-[(5-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]propanamide
  • 2-[2-(4-Methoxyphenyl)-1,3-thiazol-4-yl]-1-[4-(2-phenylethenesulfonyl)piperazin-1-yl]ethan-1-one
  • 4-{[4-Chloro-2-(trifluoromethyl)phenyl]carbamoyl}butanoic acid
  • N-(3-methoxyphenyl)-2-(6-methyl-2,4-dioxo-1,3-diazaspiro[4.5]decan-3-yl)acetamide
  • 3-allyl-8-(2-hydroxyphenyl)-1,7-dimethyl-1H-imidazo[2,1-f]purine-2,4(3H,8H)-dione
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