Tris(1-Chloro-2-Propyl) Phosphate

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Names

[ CAS No. ]:
13674-84-5

[ Name ]:
Tris(1-Chloro-2-Propyl) Phosphate

[Synonym ]:
UNII:CRT22GFY70
tris(1-chloropropan-2-yl) phosphate
MFCD00040408
Phosphoric acid tris(2-chloro-1-methylethyl) ester
EINECS 237-158-7
Tris(1-chloro-2-propanyl) phosphate
Tris(1-Chloro-2-Propyl) Phosphate

Chemical & Physical Properties

[ Density]:
1.3±0.1 g/cm3

[ Boiling Point ]:
358.5±22.0 °C at 760 mmHg

[ Molecular Formula ]:
C9H18Cl3O4P

[ Molecular Weight ]:
327.570

[ Flash Point ]:
249.7±30.0 °C

[ Exact Mass ]:
326.000824

[ PSA ]:
54.57000

[ LogP ]:
1.53

[ Vapour Pressure ]:
0.0±0.8 mmHg at 25°C

[ Index of Refraction ]:
1.462

[ Water Solubility ]:
<0.1 g/100 mL at 19.5 ºC

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
TC9000000
CHEMICAL NAME :
Phosphoric acid, tris(2-chloro-1-methylethyl) ester
CAS REGISTRY NUMBER :
13674-84-5
LAST UPDATED :
199710
DATA ITEMS CITED :
6
MOLECULAR FORMULA :
C9-H18-Cl3-O4-P
MOLECULAR WEIGHT :
327.59
WISWESSER LINE NOTATION :
G1Y1&OPO&OY1&1GOY1&1G

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
3600 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0517713
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
56 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#05768 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - E0041 No. of Facilities: 6 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 120 (estimated) No. of Female Employees: 12 (estimated)

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302

[ Precautionary Statements ]:
P301 + P312 + P330

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xn: Harmful;

[ Risk Phrases ]:
R22

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
1.0

[ RTECS ]:
TC9000000

[ HS Code ]:
2919900090

Synthetic Route

Precursor & DownStream

Precursor

  • epoxypropane

DownStream

Customs

[ HS Code ]: 2919900090

[ Summary ]:
2919900090 other phosphoric esters and their salts, including lactophosphates; their halogenated, sulphonated, nitrated or nitrosated derivatives。supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward)。VAT:17.0%。tax rebate rate:9.0%。MFN tariff:6.5%。general tariff:30.0%

Articles

Tri (2-chloroisopropyl) phosphate--an unexpected organochlorine contaminant in some charcoal air-sampling sorbent tubes.

Am. Ind. Hyg. Assoc. J. 52(9) , 398-400; discussion 401, (1991)

Air sampling in a government building was necessary in response to reports of a cancer cluster. SKC (Eighty Four, Pa.) charcoal coconut shell-based sorbent tubes (226-01 lot 120) were recommended for ...

Chemical and microbiological parameters as possible indicators for human enteric viruses in surface water.

Int. J. Hyg. Environ. Health 213(3) , 210-6, (2010)

There are still conflicting results on the suitability of chemical and microbiological parameters as indicators for the viral contamination of surface waters. In this study, conducted over 20 months, ...

Seasonal fluctuations of organophosphate concentrations in precipitation and storm water runoff.

Chemosphere 78(8) , 958-64, (2010)

To investigate seasonal fluctuations and trends of organophosphate (flame retardants, plasticizers) concentrations in rain and snow, precipitation samples were collected in 2007-2009 period at a dense...


More Articles


Related Compounds

  • Tris(1-chloro-2-propyl) Phosphate-d18
  • Bis-(1-chloro-2-propyl)phosphate
  • tris[2-bromo-1-(chloromethyl)ethyl] phosphate
  • tris-(1-chloro-2-methoxy-ethyl)-[1,3,5]triazine
  • TDCPP-d15
  • Benzene,1,1',1''-(1-chloro-1-ethenyl-2-ylidene)tris-