(-)-1,2-bis-((2S,5S)-2,5-Dimethylphospholano)ethane

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Names

[ CAS No. ]:
136779-26-5

[ Name ]:
(-)-1,2-bis-((2S,5S)-2,5-Dimethylphospholano)ethane

[Synonym ]:
(S,S)-Me-BPE
1,2-Bis[(2S,5S)-2,5-dimethyl-1-phospholanyl]ethane
MFCD01073771

Chemical & Physical Properties

[ Density]:
0.938 g/mL at 25ºC

[ Boiling Point ]:
64-67ºC0.06 mm Hg

[ Molecular Formula ]:
C14H28P2

[ Molecular Weight ]:
258.32000

[ Flash Point ]:
162.1ºC

[ Exact Mass ]:
258.16700

[ PSA ]:
27.18000

[ LogP ]:
5.09180

[ Vapour Pressure ]:
0.000285mmHg at 25°C

[ Index of Refraction ]:
n20/D 1.535

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H250

[ Precautionary Statements ]:
P222-P231-P422

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
F

[ Risk Phrases ]:
R11;R17

[ RIDADR ]:
UN 2845 4.2/PG 1

Synthetic Route

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Precursor & DownStream

Precursor

  • (2R,5R)-2,5-Hexanediol
  • (2R,5R)-hexane-2,5-diyl dimethanesulfonate
  • 1,2-bis(phosphino)ethane
  • (4R,7R)-4,7-dimethyl-[1,3,2]dioxathiepane 2,2-dioxide
  • 1,2-bis(tosyloxy)ethane
  • (2S,5S)-2,5-dimethyl-1-phenylphospholane

DownStream

Related Compounds

  • 4-[3-Chloro-4-(trifluoromethyl)phenyl]piperidine
  • 3-Nitro-4-(4-piperidinyloxy)pyridine hydrochloride
  • 4-[(1-Methyl-4-piperidinyl)oxy]-1-butanamine
  • 1,3-Dimethyl-cyclobutylamine
  • n-Isopropyl-6-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzo[d]isothiazole-3-carboxamide
  • 3-(But-3-en-1-yl)pyridin-2-amine
  • 4-(1H-1,2,4-triazol-3-yl)butan-2-ol
  • 4-(3-Chloro-5-methylpyridin-2-yl)piperazine-1-carboxylic acid tert-butyl ester
  • 3-Tert-butyl-5-chloropyridin-2-amine
  • 2-[5-Fluoro-2-(propan-2-yl)phenyl]acetic acid
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