(-)-1,2-bis-((2S,5S)-2,5-Dimethylphospholano)ethane

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Names

[ CAS No. ]:
136779-26-5

[ Name ]:
(-)-1,2-bis-((2S,5S)-2,5-Dimethylphospholano)ethane

[Synonym ]:
(S,S)-Me-BPE
1,2-Bis[(2S,5S)-2,5-dimethyl-1-phospholanyl]ethane
MFCD01073771

Chemical & Physical Properties

[ Density]:
0.938 g/mL at 25ºC

[ Boiling Point ]:
64-67ºC0.06 mm Hg

[ Molecular Formula ]:
C14H28P2

[ Molecular Weight ]:
258.32000

[ Flash Point ]:
162.1ºC

[ Exact Mass ]:
258.16700

[ PSA ]:
27.18000

[ LogP ]:
5.09180

[ Vapour Pressure ]:
0.000285mmHg at 25°C

[ Index of Refraction ]:
n20/D 1.535

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H250

[ Precautionary Statements ]:
P222-P231-P422

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
F

[ Risk Phrases ]:
R11;R17

[ RIDADR ]:
UN 2845 4.2/PG 1

Synthetic Route

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Precursor & DownStream

Precursor

  • (2R,5R)-2,5-Hexanediol
  • (2R,5R)-hexane-2,5-diyl dimethanesulfonate
  • 1,2-bis(phosphino)ethane
  • (4R,7R)-4,7-dimethyl-[1,3,2]dioxathiepane 2,2-dioxide
  • 1,2-bis(tosyloxy)ethane
  • (2S,5S)-2,5-dimethyl-1-phenylphospholane

DownStream

Related Compounds

  • tert-butyl N-[(1S)-1-(4-methyl-1H-imidazol-5-yl)-3-oxopropyl]carbamate
  • tert-butyl N-[(1S)-1-(1H-imidazol-5-yl)-3-oxopropyl]carbamate
  • 5-(1H-indol-7-yl)pyridine-2-carbaldehyde
  • [1-(5-Bromothiophen-3-yl)-2,2-difluorocyclopropyl]methanamine
  • 2-[1-(3-Bromo-2-methoxyphenyl)cyclopropyl]ethan-1-amine
  • 1-{5-Chlorothieno[3,2-b]pyridin-2-yl}propan-2-one
  • 3-(3-bromo-1-methyl-1H-pyrazol-5-yl)-1,1,1-trifluoropropan-2-amine
  • 1-(6-Chloro-5-methylpyridin-3-yl)-2-methylpropan-2-amine
  • (2-{5-Chlorothieno[3,2-b]pyridin-2-yl}cyclopropyl)methanamine
  • 3-({4-chloro-7H-pyrrolo[2,3-d]pyrimidin-5-yl}oxy)-3-methylazetidine
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