(-)-1,2-bis-((2S,5S)-2,5-Dimethylphospholano)ethane

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Names

[ CAS No. ]:
136779-26-5

[ Name ]:
(-)-1,2-bis-((2S,5S)-2,5-Dimethylphospholano)ethane

[Synonym ]:
(S,S)-Me-BPE
1,2-Bis[(2S,5S)-2,5-dimethyl-1-phospholanyl]ethane
MFCD01073771

Chemical & Physical Properties

[ Density]:
0.938 g/mL at 25ºC

[ Boiling Point ]:
64-67ºC0.06 mm Hg

[ Molecular Formula ]:
C14H28P2

[ Molecular Weight ]:
258.32000

[ Flash Point ]:
162.1ºC

[ Exact Mass ]:
258.16700

[ PSA ]:
27.18000

[ LogP ]:
5.09180

[ Vapour Pressure ]:
0.000285mmHg at 25°C

[ Index of Refraction ]:
n20/D 1.535

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H250

[ Precautionary Statements ]:
P222-P231-P422

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
F

[ Risk Phrases ]:
R11;R17

[ RIDADR ]:
UN 2845 4.2/PG 1

Synthetic Route

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Precursor & DownStream

Precursor

  • (2R,5R)-2,5-Hexanediol
  • (2R,5R)-hexane-2,5-diyl dimethanesulfonate
  • 1,2-bis(phosphino)ethane
  • (4R,7R)-4,7-dimethyl-[1,3,2]dioxathiepane 2,2-dioxide
  • 1,2-bis(tosyloxy)ethane
  • (2S,5S)-2,5-dimethyl-1-phenylphospholane

DownStream

Related Compounds

  • 6-(4-fluorophenyl)-N-(2-(3-(4-fluorophenyl)-6-oxopyridazin-1(6H)-yl)ethyl)-3-methylimidazo[2,1-b]thiazole-2-carboxamide
  • N-(2-(3-(4-fluorophenyl)-6-oxopyridazin-1(6H)-yl)ethyl)benzo[c][1,2,5]thiadiazole-5-carboxamide
  • 3-(2,4-dioxo-3,4-dihydropyrimidin-1(2H)-yl)-N-(2-(3-(4-fluorophenyl)-6-oxopyridazin-1(6H)-yl)ethyl)propanamide
  • N-(2-(3-(4-fluorophenyl)-6-oxopyridazin-1(6H)-yl)ethyl)-3-(4-oxoquinazolin-3(4H)-yl)propanamide
  • N-(2-(3-(4-methoxyphenyl)-6-oxopyridazin-1(6H)-yl)ethyl)isoxazole-5-carboxamide
  • ethyl 4-(2-(5-amino-3-(methylthio)-4-tosyl-1H-pyrazol-1-yl)acetamido)benzoate
  • N-(2-(3-(4-ethoxyphenyl)-6-oxopyridazin-1(6H)-yl)ethyl)-2-((4-fluorophenyl)thio)acetamide
  • 2-(benzo[d]isoxazol-3-yl)-N-(2-(3-(4-ethoxyphenyl)-6-oxopyridazin-1(6H)-yl)ethyl)acetamide
  • N-(2-(3-(4-ethoxyphenyl)-6-oxopyridazin-1(6H)-yl)ethyl)-2,5-dimethylfuran-3-carboxamide
  • N-(2-(3-(4-ethoxyphenyl)-6-oxopyridazin-1(6H)-yl)ethyl)-1-(methylsulfonyl)piperidine-4-carboxamide
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