(1-Bromovinyl)trimethylsilane

Suppliers

Names

[ Name ]:
(1-Bromovinyl)trimethylsilane

[Synonym ]:
MFCD00014927
1-bromoethenyl(trimethyl)silane
α-Trimethylsilylvinyl Bromide
1-Bromo-1-trimethylsilylethylene
(1-BroMovinyl)triMethylsilane
EINECS 237-195-9
(1-Bromovinyl)(trimethyl)silane
Silane, (1-bromoethenyl)trimethyl-

Chemical & Physical Properties

[ Density]:
1.2±0.1 g/cm3

[ Boiling Point ]:
124.9±13.0 °C at 760 mmHg

[ Molecular Formula ]:
C₅H₁₁BrSi

[ Molecular Weight ]:
179.130

[ Flash Point ]:
9.4±0.0 °C

[ Exact Mass ]:
177.981339

[ LogP ]:
2.09

[ Vapour density ]:
>1 (vs air)

[ Vapour Pressure ]:
15.1±0.2 mmHg at 25°C

[ Index of Refraction ]:
1.445

[ Storage condition ]:
2-8°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225

[ Precautionary Statements ]:
P210

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
F

[ Risk Phrases ]:
11

[ Safety Phrases ]:
S16-S23-S24/25

[ RIDADR ]:
UN 1993 3/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
II

[ Hazard Class ]:
3.1

[ HS Code ]:
2931900090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

Vinyltrimethylsilane
1,2-Dibromoethyltrimethylsilane
Chlorotrimethylsilane
bromoethene
(2-Bromovinyl)benzene
METHYLMAGNESIUM IODIDE
1-bromoethenyl(trichloro)silane
Silane,1,1'-ethenylidenebis[1,1,1-trimethyl-
METHYLMAGNESIUM BROMIDE

DownStream

2-trimethylsilylprop-2-enoic acid
dodecene
trimethyl-(3-trimethylsilylbuta-1,3-dien-2-yl)silane
3-Ethenylpyridine
TMS-acetylene
trimethyl-[(E)-2-phenylethenyl]silane
trimethyl-(1-phenylethenyl)silane
2-trimethylsilylpropane-1,3-diol

Customs

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

Articles

Abnormal products of palladium catalysed coupling reactions of (1-bromovinyl) trimethylsilane. Ennis DS and Gilchrist TL.

Tetrahedron Lett. 30(28) , 3735-36, (1989)