Sulfurol

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Names

[ CAS No. ]:
137-00-8

[ Name ]:
Sulfurol

[Synonym ]:
4-Methyl-5-thiazole
5-(2-hydroxyethyl)-4-methyl-1,3-thiazole
Hemineurine
4-Methyl-5-Thiazoleethanol
5-Thiazoleethanol, 4-methyl-
4-Methylthiazol-5ylethanol
5-(β-Hydroxyethyl)-4-methylthiazole
5-(2-Hydroxyethyl)-4-methylthiazole
Sulfurol
2-(4-Methylthiazole-5-yl)ethanol
4-Methyl-5-thiazolylethanol
T5N CSJ D2Q E1
FEMA NUMBER 3204
EINECS 205-272-6
4-Methyl-5-(β-hydroxyethyl)thiazole
MHT
MFCD00005339
2-(4-Methyl-1,3-thiazol-5-yl)ethanol
thiaminethiazole
FEMA 3204
SULPHUROL ENHANCER
4-methylthiazole-5-thiazoleethanol

Chemical & Physical Properties

[ Density]:
1.2±0.1 g/cm3

[ Boiling Point ]:
272.4±0.0 °C at 760 mmHg

[ Molecular Formula ]:
C₆H₉NOS

[ Molecular Weight ]:
143.20

[ Flash Point ]:
109.7±23.2 °C

[ Exact Mass ]:
143.040482

[ PSA ]:
61.36000

[ LogP ]:
0.04

[ Vapour Pressure ]:
0.0±0.6 mmHg at 25°C

[ Index of Refraction ]:
1.564

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36-S24/25

[ RIDADR ]:
UN3334 9

[ WGK Germany ]:
3

[ HS Code ]:
29341000

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

3-chloro-5-hydroxypentan-2-one
Thioformamide
4-methyl-5-thiazoleacetic acid
5-Methyl-2,3-dihydrofuran
3-Acetyl-1-propanol
(2,4-dioxo-1,2,3,4-tetrahydro-pyrimidin-5-ylmethyl)-dithiocarbamic acid 3-acetoxy-1-acetyl-propyl ester
Thiamine hydrochloride
Vitamin B1
2(3H)-THIAZOLETHIONE, 5-(2-HYDROXYETHYL)-4-METHYL-
2-(2-bromo-4-methyl-thiazol-5-yl)-ethanol

DownStream

3-BENZYL-5-(2-HYDROXYETHYL)-4-METHYLTHIAZOLIUM CHLORIDE
5-Ethenyl-4-methylthiazole
5-Formyl-4-methylthiazole
3-Ethyl-5-(2-hydroxyethyl)-4-methylthiazol-3-ium bromide
2-(4-Methyl-1,3-thiazol-5-yl)ethanamine
Clomethiazole
4-Methyl-5-thiazoleethanol-5-propanoate
1-[4-methyl-5-(2-phenylmethoxyethyl)-1,3-thiazol-2-yl]-2-phenylethanone
3,4-DIMETHYL-5-(2-HYDROXYETHYL)THIAZOLIUM IODIDE
5-Thiazolepropanal,4-methyl-

Customs

[ HS Code ]: 2934100090

[ Summary ]:
2934100090 other compounds containing an unfused thiazole ring (whether or not hydrogenated) in the structure VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0%

Articles

Metabolomic profiling of Burkholderia pseudomallei using UHPLC-ESI-Q-TOF-MS reveals specific biomarkers including 4-methyl-5-thiazoleethanol and unique thiamine degradation pathway.

Cell Biosci. 5 , 26, (2015)

Burkholderia pseudomallei is an emerging pathogen that causes melioidosis, a serious and potentially fatal disease which requires prolonged antibiotics to prevent relapse. However, diagnosis of melioi...

Synthesis and odor evaluation of five new sulfur-containing ester flavor compounds from 4-ethyloctanoic acid.

Molecules 15(8) , 5104-11, (2010)

Five sulfur-containing flavor compounds were synthesized for the first time by the reaction of 4-ethyloctanoyl chloride with sulfur-containing alcohols or mercaptans. The synthesized compounds are 3-(...

Characterization of thiI, a new gene involved in thiazole biosynthesis in Salmonella typhimurium.

J. Bacteriol. 179(13) , 4399-402, (1997)

Thiamine pyrophosphate (TPP) is a required cofactor in Salmonella typhimurium that is generated de novo by the condensation of 4-amino-5-hydroxymethyl pyrimidine (HMP) pyrophosphate and 4-methyl-5-(be...