vanadium oxytrifluoride

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Names

[ CAS No. ]:
13709-31-4

[ Name ]:
vanadium oxytrifluoride

[Synonym ]:
VANADIUM OXYTRIFLUORIDE
EINECS 237-250-7
Vanadium(V) trifluoride oxide
MFCD00042555

Chemical & Physical Properties

[ Density]:
2.45

[ Boiling Point ]:
480 °C

[ Melting Point ]:
300 °C

[ Molecular Formula ]:
F3OV

[ Molecular Weight ]:
123.93600

[ Exact Mass ]:
123.93400

[ PSA ]:
17.07000

[ LogP ]:
1.14180

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS05, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H302 + H312 + H332-H314

[ Supplemental HS ]:
Contact with acids liberates very toxic gas.

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
C,Xi

[ Risk Phrases ]:
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed . R32:Contact with acids liberates very toxic gas. R34:Causes burns.

[ Safety Phrases ]:
S26-S36/37/39-S45

[ RIDADR ]:
UN 3260 8/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
II

[ Hazard Class ]:
6.1

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • trifluorochlorine
  • Vanadium(V) trichloride oxide
  • Bromine trifluoride
  • VANADIUM PENTAFLUORIDE
  • Sulfur trioxide

DownStream

Articles

The gas-phase on-line production of vanadium oxytrihalides, VOX3 and their identification by infrared spectroscopy.

Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 56(14) , 2693-8, (2000)

A new route has been devised, leading to the production of VOX3 molecules where X=F, Br and I by an on-line process using vanadium oxytrichloride, VOCl3 as a starting compound passed over the followin...

Synthesis of tylocrebrine and related phenanthroindolizidines by VOF3-mediated oxidative aryl-alkene coupling.

Org. Lett. 13(2) , 196-9, (2011)

A highly convergent strategy to prepare phenanthroindolizidines is reported involving three consecutive C-C coupling reactions. This sequence features a novel VOF(3)-mediated aryl-alkene coupling in t...


More Articles

Related Compounds

  • VANADIUM TELLURIDE
  • VANADIUM SILICIDE
  • vanadium naphthenate oxide
  • Vanadium 2-ethylhexanoate
  • vanadium(4+) tetraformate
  • vanadium iv oxide bis(hexafluoropentanedionate), monohydrate
  • 4-({1-[2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)ethyl]-1H-imidazol-4-yl}formamido)-2-methylbut-2-enoic acid
  • 2-{N-benzyl-1-[3-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)furan-2-yl]formamido}acetic acid
  • (2R)-2-[2-cyclobutyl-3-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)propanamido]-4-(methylsulfanyl)butanoic acid
  • (2S)-2-({5-[({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)methyl]oxolan-3-yl}formamido)hexanoic acid
  • 5-({5-[({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)methyl]oxolan-3-yl}formamido)-2-methylpentanoic acid
  • 3-cyclohexyl-2-[(3R)-3-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)butanamido]propanoic acid
  • 1-[({5-[({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)methyl]oxolan-3-yl}formamido)methyl]cyclobutane-1-carboxylic acid
  • 2-(N-ethyl-1-{5-[({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)methyl]-1-methyl-1H-pyrazol-4-yl}formamido)acetic acid
  • rac-2-({1-[(3R,5R)-5-[({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)methyl]oxolane-3-carbonyl]azetidin-3-yl}oxy)acetic acid
  • 2-({1-[3-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-4,4,4-trifluorobutanoyl]azetidin-3-yl}oxy)acetic acid
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