Xenon difluoride

Names

[ CAS No. ]:
13709-36-9

[ Name ]:
Xenon difluoride

[Synonym ]:
difluoroxenon
MFCD00040538
EINECS 237-251-2
Xenon difluoride

Chemical & Physical Properties

[ Density]:
4.32 g/mL at 25 °C(lit.)

[ Melting Point ]:
129 °C(lit.)

[ Molecular Formula ]:
F₂Xe

[ Molecular Weight ]:
169.29000

[ Flash Point ]:
None

[ Exact Mass ]:
169.90100

[ LogP ]:
0.45960

[ Vapour Pressure ]:
3.8 mm Hg ( 25 °C)

MSDS

Safety Information

[ Symbol ]:

GHS03, GHS05, GHS06

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H272-H301-H314-H330

[ Precautionary Statements ]:
Missing Phrase - N15.00950417-P210-P220-P280-P304 + P340 + P310-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
O,T+,T

[ Risk Phrases ]:
R8:Contact with combustible material may cause fire. R25:Toxic if swallowed. R26:Very Toxic by inhalation. R34:Causes burns.

[ Safety Phrases ]:
S17-S26-S28-S36/37/39-S45

[ RIDADR ]:
UN 3087 5.1/PG 2

[ WGK Germany ]:
3

[ RTECS ]:
ZE1294166

[ Packaging Group ]:
II

[ Hazard Class ]:
5.1

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

HYDROFLUORIC ACID
trifluoromethyl hypofluorite
Xenon tetrafluoride oxide
xenone trioxide
heptafluorobutyronitrile
xenon difluoride * AsF5
Trifluoroacetonitrile

DownStream

Fluorobenzene
1,4-Difluorobenzene
1,2-Difluorobenzene
Chloropentafluoroethane
TRIFLUOROCHLOROETHYLENE
1-chloro-2,2-difluoroethenylxenon(II) tetrafluoroborate
bf3
difluoro(1,1,2,2,3,3,4,4,5,5,6,6,6-tridecafluorohexyl)borane
trans-1H-perfluorohexene
Perfluorohexane

Articles

Synthesis of α,α-difluoroethyl aryl and heteroaryl ethers.

Org. Lett. 14(15) , 3944-7, (2012)

Fluorine plays a critical role in modern medicinal chemistry due to its unique properties, and new methods for its incorporation into target molecules are of high interest. An efficient new method for...

Fluorination with XeF(2).(1) 44. Effect of Geometry and Heteroatom on the Regioselectivity of Fluorine Introduction into an Aromatic Ring.

J. Org. Chem. 63 , 878, (1998)

Xenon difluoride induced aryl iodide reductive elimination: a simple access to difluoropalladium(II) complexes.

Inorg. Chem. 47(1) , 5-7, (2008)

Palladium(II) aryliodo complexes bearing chelating diphosphine ligands react with XeF2, giving iodoarene and rare palladium(II) difluoro complexes. The reaction is general with regard to the aryl grou...