5-methylfuran-2-carbonitrile

Names

[ Name ]:
5-methylfuran-2-carbonitrile

[Synonym ]:
5-methyl-2-furonitrile
2-Furancarbonitrile,5-methyl
MFCD02093782
5-methyl-2-furancarbonitrile
2-cyano-5-methylfuran
5-Methyl-furan-2-carbonitril
5-methyl-furan-2-carbonitrile

Chemical & Physical Properties

[ Density]:
1.02 g/mL at 25ºC(lit.)

[ Boiling Point ]:
173-176ºC(lit.)

[ Molecular Formula ]:
C₆H₅NO

[ Molecular Weight ]:
107.11000

[ Flash Point ]:
139 °F

[ Exact Mass ]:
107.03700

[ PSA ]:
36.93000

[ LogP ]:
1.45968

[ Vapour Pressure ]:
0.976mmHg at 25°C

[ Index of Refraction ]:
n20/D 1.484(lit.)

MSDS

Safety Information

[ Symbol ]:

GHS02, GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H226-H302-H312-H332

[ Precautionary Statements ]:
P280

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xn: Harmful;

[ Risk Phrases ]:
R20/21/22

[ Safety Phrases ]:
S26

[ RIDADR ]:
UN 1993 3/PG 1

[ HS Code ]:
2932190090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

5-Methyl-2-furaldehyde
(E)-5-methylfurfuraldoxime
2-(Chloromethyl)furan
Sodium cyanide
POTASSIUM CYANIDE
furtrethonium iodide
Water
Furfuryl alcohol
HYDROGEN CYANIDE

DownStream

5-Methyl-2-furaldehyde
5-Methyl-2-furoic acid
5-methyl-2-furancarboximidamide()
5-methylfuran-2-carboxamide

Customs

[ HS Code ]: 2932190090

[ Summary ]:
2932190090 other compounds containing an unfused furan ring (whether or not hydrogenated) in the structure VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0%

Articles

Reactions in the β-Furan Series—Synthesis and Reactions of 3-Chloromethylfuran and Some Related Compounds. Sherman E and Amstutz ED.

J. Am. Chem. Soc. 72(5) , 2195-2199., (1950)

The preparation of 2-Furanacetic acid. Plucker III J and Amstutz ED.

J. Am. Chem. Soc. 62(6) , 1512-1513, (1940)

(5-methylfuran-2-yl)(phenyl)methanol
(5-methylfuran-2-yl)oxy-tri(propan-2-yl)silane
(5-methylfuran-2-yl)-[4-(4-nitrophenyl)piperazin-1-yl]methanone
5-methylfuran-2-sulfonyl chloride
5-Methylfuran-2-propionaldehyde
5-methylfuran-2-carbonyl chloride
N-(cyclopropylmethyl)-2,2-difluoro-2H-1,3-benzodioxol-5-amine
4-(4-((4-Chlorophenyl)sulfonyl)piperazin-1-yl)-6-isopropoxy-2-methylpyrimidine
4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
2-(4-oxobenzo[d][1,2,3]triazin-3(4H)-yl)-N-(2-(thiophen-2-yl)ethyl)propanamide
2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
(4-Methyl-tetrahydro-furan-2-yl)-methanol
2-(6-Bromo-4-oxoquinolin-1(4H)-yl)acetic acid
N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide