Di-tert-butylchlorophosphane

Suppliers

Names

[ Name ]:
Di-tert-butylchlorophosphane

[Synonym ]:
Di-tert-butylchlorophosphine
Phosphinous chloride, di-tert-butyl-
MFCD00008815
di(tert-butyl)chlorophosphine
Phosphinous chloride, P,P-bis(1,1-dimethylethyl)-
Chlorodi-tert-butylphosphine
Di-tert-butylchlorophosphane
Di-tert-butylphosphinous chloride
Phosphinous chloride, bis(1,1-dimethylethyl)-
Di-tert-butylchlorophosphine,AcroSeal
ditert-butyl(chloro)phosphane
Bis(2-methyl-2-propanyl)phosphinous chloride

Chemical & Physical Properties

[ Density]:
0.951 g/mL at 25 °C(lit.)

[ Boiling Point ]:
191.6±0.0 °C at 760 mmHg

[ Melting Point ]:
2-3°C

[ Molecular Formula ]:
C₈H₁₈ClP

[ Molecular Weight ]:
180.655

[ Flash Point ]:
61.1±0.0 °C

[ Exact Mass ]:
180.083466

[ PSA ]:
13.59000

[ LogP ]:
4.28

[ Vapour Pressure ]:
0.7±0.3 mmHg at 25°C

[ Index of Refraction ]:
n20/D 1.482(lit.)

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
C:Corrosive;

[ Risk Phrases ]:
R34

[ Safety Phrases ]:
S26-S36/37/39-S45-S25

[ RIDADR ]:
UN 3265 8/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
II

[ Hazard Class ]:
8

[ HS Code ]:
2903199000

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

Phosphine, di-tert-butyl-
TERT-BUTYLMAGNESIUM CHLORIDE
tetrakis(tert-butyl)diphosphine
tert-butyl chloride
Carbon tetrachloride
Pivaloyl chloride
1,1-Di-tert-butyl-2-[phenyl(trimethylsilyl)methylen]diphosphan

DownStream

2-Iodo-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl
di-t-Bu-XPhos
Di(tert-butyl)(phenyl)phosphine
Di-tert-butylneopentylphosphine
vBRIDP
ditert-butyl-chloro-sulfanylidene-λ5-phosphane
Di-t-butyl(i-propyl)phosphine
ditert-butyl(ethyl)phosphane
ditert-butyl(fluoro)phosphane
benzyl(ditert-butyl)phosphane

Customs

[ HS Code ]: 2903199000

[ Summary ]:
2903199000 other saturated chlorinated derivatives of acyclic hydrocarbons。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%

Articles

Synthesis and characterization of R2PN=P(iBuNCH2CH2)3N: a new bulky electron-rich phosphine for efficient Pd-assisted Suzuki-Miyaura cross-coupling reactions.

J. Org. Chem. 72 , 2816, (2007)

Pro-azaphosphatrane 1a [P(iBuNCH2CH2)3N] reacts with iodine under mild conditions to give [IP(iBuNCH2CH2)3N]I in excellent yield, which on subsequent reaction with ammonia followed by deprotonation wi...

di-tert-butylsulfinyl thioanhydride
di-tert-butyl 4-hydroxyheptanedioate
(Di-tert-butylsilyl)bis(trimethylsilyl)methan
di-tert-butyl(4-methoxyphenoxy)silanol
di-tert-butyltin dichloride
DI-TERT-BUTYL GLUTARATE
2-amino-5H,6H,7H,8H-[1,2,4]triazolo[1,5-a]pyridin-6-ol
tert-butyl N-(3-aminopropyl)-N-[(2-fluoroethyl)carbamothioyl]carbamate
2-{1-[({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)methyl]cyclopropaneamido}-3-fluorobenzoic acid
2-{[2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)pent-4-ynamido]methyl}pyridine-4-carboxylic acid
2-cyclohexyl-2-[3-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-2,2-dimethylpropanamido]acetic acid
3-[3-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-2,2-dimethylpropanamido]bicyclo[2.2.1]heptane-2-carboxylic acid
1-amino-3-(4-methoxy-1H-pyrazol-1-yl)cyclopentane-1-carboxylic acid
2-{N-ethyl-2-[3-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)cyclobutyl]acetamido}acetic acid
1-{2-[1-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)cyclobutyl]acetyl}piperidine-4-carboxylic acid
1-amino-3-(4,5-diiodo-1H-imidazol-1-yl)cyclopentane-1-carboxylic acid

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