(S)-xyl-BINAP

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Names

[ CAS No. ]:
137219-86-4

[ Name ]:
(S)-xyl-BINAP

[Synonym ]:
(S)-xylyl-BINAP
Phosphine, 1,1'-[1,1'-binaphthalene]-2,2'-diylbis[1,1-bis(3,5-dimethylphenyl)-
(S)-xyl-BINAP
(R)-DM-BINAP
1,1'-Binaphthalene-2,2'-diylbis[bis(3,5-dimethylphenyl)phosphine]
(R)-(+)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl
MFCD01630821
(R)-(+)-2,2′-Bis(di-3,5-xylylphosphino)-1,1′-binaphthyl
(R)-(+)-XylBINAP

Chemical & Physical Properties

[ Boiling Point ]:
825.3±65.0 °C at 760 mmHg

[ Melting Point ]:
187-191ºC

[ Molecular Formula ]:
C52H48P2

[ Molecular Weight ]:
734.885

[ Flash Point ]:
485.3±40.6 °C

[ Exact Mass ]:
734.323120

[ PSA ]:
27.18000

[ LogP ]:
17.06

[ Vapour Pressure ]:
0.0±2.9 mmHg at 25°C

MSDS

Click to get detail MSDS

Safety Information

[ Hazard Codes ]:
Xi

[ RIDADR ]:
NONH for all modes of transport

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • bis(3,5-dimethylphenyl)bromophosphine
  • (+/-)-2,2-Dibromo-1,1-Binaphthyl
  • (R)-trifluoro-methanesulfonic acid 2’-trifluoromethanesulfonyloxy [1,1’]binapthalenyl-2-yl ester
  • 3,5-dimethylphenylmagnesium bromide
  • Bis(3,5-dimethylphenyl)chlorophosphine
  • [bis-(3,5-dimethylphenyl)](diethylamino)phosphine

DownStream

Related Compounds

  • (S)-xyl-BINAP
  • [(S)-Xyl-Binap RuCl benzene]Cl
  • [RuCl(p-cymene)((S)-xylbinap)]Cl
  • (11BS)-(2,2,2',2'-tetramethyl-[4,4'-bibenzo[d][1,3]dioxole]-5,5'-diyl)bis(bis(3,5-dimethylphenyl)phosphane)
  • (S)-Xyl-SDP
  • Ruthenium, [(3S)-4,4'-bis[bis(3,5-dimethylphenyl)phosphino-κP]-2,2',6,6'-tetramethoxy[3,3'-bipyridine]][(2S)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine-κN1,κN2]dichloro-, (OC-6-14)
  • 2-(2,4-difluorophenyl)-N-[(pyrazin-2-yl)methyl]acetamide
  • 6-(difluoromethyl)-N-(2-fluorophenyl)-2-methylpyrimidin-4-amine
  • 6-(difluoromethyl)-N-(4-fluorophenyl)-2-methylpyrimidin-4-amine
  • 6-(difluoromethyl)-N-(3-fluoro-4-methylphenyl)-2-methylpyrimidin-4-amine
  • 4-[4-(2-Methoxyphenyl)piperazin-1-yl]-2,5,6-trimethylpyrimidine
  • 4-[4-(3-Methoxyphenyl)piperazin-1-yl]-2,5,6-trimethylpyrimidine
  • 2-Cyclopropyl-4,5-dimethyl-6-(4-phenylpiperazin-1-yl)pyrimidine
  • 2-{4-[(2,4-difluorophenyl)methyl]piperazin-1-yl}-N,N,6-trimethylpyrimidin-4-amine
  • 3-methoxy-N-methyl-N-({1-[6-methyl-2-(methylsulfanyl)pyrimidin-4-yl]piperidin-4-yl}methyl)pyrazin-2-amine
  • 2-cyclopropyl-N-[2-(3-methoxyphenyl)ethyl]pyrimidin-4-amine
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