Nickel sulfamate

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Names

[ CAS No. ]:
13770-89-3

[ Name ]:
Nickel sulfamate

[Synonym ]:
Nickel bis(sulphamidate)
nickel(2+),disulfamate
EINECS 237-396-1
MFCD00137261

Chemical & Physical Properties

[ Density]:
1.913g/cm3

[ Melting Point ]:
205ºC

[ Molecular Formula ]:
H4N2NiO6S2

[ Molecular Weight ]:
250.86500

[ Exact Mass ]:
249.88600

[ PSA ]:
155.54000

[ LogP ]:
0.90380

[ Stability ]:
Stable. Incompatible with oxidizing agents.

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
QR9275000
CHEMICAL NAME :
Nickel (II) sulfamate
CAS REGISTRY NUMBER :
13770-89-3
LAST UPDATED :
199712
DATA ITEMS CITED :
33
MOLECULAR FORMULA :
H4-N2-O6-S2.Ni
MOLECULAR WEIGHT :
250.89

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
250 mg/kg
REFERENCE :
CBCCT* "Summary Tables of Biological Tests," National Research Council Chemical-Biological Coordination Center. (National Academy of Science Library, 2101 Constitution Ave., NW, Washington, DC 20418) Volume(issue)/page/year: 4,320,1952 *** REVIEWS *** ACGIH TLV-TWA 0.1 mg(Ni)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 1 mg(Ni)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,178,1971 OSHA PEL (Gen Indu):8H TWA 1 mg(Ni)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 1 mg(Ni)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 1 mg(Ni)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 1 mg(Ni)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-ARAB Republic of Egypt:TWA 0.1 mg(Ni)/m3 JAN 1993 OEL-AUSTRALIA:TWA 1 mg(Ni)/m3 JAN 1993 OEL-BELGIUM:TWA 1 mg(Ni)/m3 (insoluble compounds) JAN 1993 OEL-DENMARK:TWA 0.05 mg(Ni)/m3;Carcinogen JAN 1993 OEL-DENMARK:TWA 1 mg(Ni)/m3 (insoluble compounds) JAN 1993 OEL-FINLAND:TWA 0.1 mg(Ni)/m3;Skin;Carcinogen (insoluble compounds) JAN 1993 OEL-FRANCE:TWA 1 mg(Ni)/m3 JAN 1993 OEL-GERMANY;Carcinogen JAN 1993 OEL-HUNGARY:STEL 0.005 mg(Ni)/m3;Carcinogen (insoluble compounds) JAN 1993 OEL-JAPAN:TWA 1 mg(Ni)/m3;Carcinogen JAN 1993 OEL-THE NETHERLANDS:TWA 0.1 mg(Ni)/m3 JAN 1993 OEL-THE NETHERLANDS:TWA 1 mg(Ni)/m3 (insoluble compounds) JAN 1993 OEL-THE PHILIPPINES:TWA 1 mg(Ni)/m3 JAN 1993 OEL-RUSSIA:STEL 0.05 mg(Ni)/m3 JAN 1993 OEL-SWEDEN:TWA 0.5 mg(Ni)/m3 JAN 1993 OEL-SWITZERLAND:TWA 0.5 mg(Ni)/m3 (insoluble compounds) JAN 1993 OEL-SWITZERLAND:TWA 0.5 mg(Ni)/m3;Carcinogen JAN 1993 OEL-THAILAND:TWA 1 mg(Ni)/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 0.5 mg(Ni)/m3 (insoluble compounds) JAN 1993 OEL-UNITED KINGDOM:TWA 1 mg(Ni)/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO NICKEL, INORGANIC-air:10H CA TWA 0.015 mg(Ni)/m3 REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992 NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 50470 No. of Facilities: 256 (estimated) No. of Industries: 10 No. of Occupations: 9 No. of Employees: 900 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 50470 No. of Facilities: 488 (estimated) No. of Industries: 19 No. of Occupations: 18 No. of Employees: 11182 (estimated) No. of Female Employees: 3593 (estimated)

Safety Information

[ Hazard Codes ]:
F,T,T+

[ Risk Phrases ]:
R10:Flammable. R15:Contact with water liberates extremely flammable gases. R20:Harmful by inhalation. R24/25:Toxic in contact with skin and if swallowed . R36/38:Irritating to eyes and skin . R44:Risk of explosion if heated under confinement. R36/37/38:Irr

[ Safety Phrases ]:
S26-S36/37-S43-S45-S36/37/39-S28A

[ RIDADR ]:
UN 1992 3/PG 2

[ WGK Germany ]:
2

[ RTECS ]:
US3675000

[ Packaging Group ]:
II

[ Hazard Class ]:
4.3

[ HS Code ]:
2922499990

Customs

[ HS Code ]: 2922499990

[ Summary ]:
HS:2922499990 other amino-acids, other than those containing more than one kind of oxygen function, and their esters; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:6.5% General tariff:30.0%


Related Compounds

  • Nickel sulfamate
  • nickel(2+) trifluoroacetate
  • Nickel Carbonate
  • nickel,tin (1:3)
  • nickel phosphate
  • Nickel,tetrakis[4-(1-ethylpropyl)pyridine]bis(thiocyanato-S)- (9CI)
  • 3-{[(Tert-butoxy)carbonyl][(4-methoxyphenyl)methyl]amino}propanoic acid
  • Acetamide, 2-chloro-N-[4-[(4-chlorophenyl)methoxy]phenyl]-
  • 1-[4-[4-(2-Methoxyphenyl)-1-piperazinyl]phenyl]ethanone
  • 4-{[(Tert-butoxy)carbonyl][(4-fluorophenyl)methyl]amino}butanoic acid
  • [3-(Methoxycarbonyl)phenyl]methyl 3-cyano-6-cyclopropyl-2-(methylsulfanyl)pyridine-4-carboxylate
  • (2,5-Dimethoxyphenyl)methyl 3-cyano-6-cyclopropyl-2-(methylsulfanyl)pyridine-4-carboxylate
  • (3-Methyl-1,2-oxazol-5-yl)methyl 3-cyano-6-cyclopropyl-2-(methylsulfanyl)pyridine-4-carboxylate
  • (7-chloro-2H-1,3-benzodioxol-5-yl)methyl 3-cyano-6-cyclopropyl-2-(methylsulfanyl)pyridine-4-carboxylate
  • 5-Chloro-4-(((5-methyl-4h-1,2,4-triazol-3-yl)thio)methyl)-1,2,3-thiadiazole
  • 3-(1-(2-Cyanoethyl)-3,5-dimethyl-1H-pyrazol-4-yl)-N-(4-(morpholine-4-carbonyl)benzyl)propanamide
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