limonene

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Names

[ CAS No. ]:
138-86-3

[ Name ]:
limonene

[Synonym ]:
Cyclohexene, 4-Isopropenyl-1-methyl-
EINECS 227-815-6
p-mentha-1,8-diene
(±)-p-Mentha-1,8-diene
Mentha-1,8-diene, DL
4-(1-methylethenyl)-1-methyl-cyclohexene
Methyl-4-isopropenyl-1-cyclohexene
Limonene, dl-
Methyl-4-isopropenylcyclohexene
(±)-Limonene
Cyclohexene, 1-methyl-4-(1-methylethenyl)-
Dipanol
DL-p-mentha-1,8-diene
p-Mentha-1,8-diene, (±)-
Methyl-4-(1-methylethenyl)cyclohexene
Unitene
(±)-(RS)-limonene
Depanol
a-limonene
p-menth-1,8-diene
Nesol
MFCD00001558
1-Methyl-4-methylethenylcyclohexene
Mentha-1,8-diene
α-Limonene
Cinen
Eulimen
limonene, (±)-isomer
4-Isopropenyl-1-methylcyclohexene
dycom
Ciene
Limonene
Limonene, (±)-
Cinene
1,8-p-Mentadiene
1-methyl-4-(prop-1-en-2-yl)cyclohexene
p-Mentha-1,8-diene, DL-

Chemical & Physical Properties

[ Density]:
0.8±0.1 g/cm3

[ Boiling Point ]:
175.4±20.0 °C at 760 mmHg

[ Melting Point ]:
-84--104 °C

[ Molecular Formula ]:
C10H16

[ Molecular Weight ]:
136.234

[ Flash Point ]:
42.8±0.0 °C

[ Exact Mass ]:
136.125198

[ LogP ]:
4.45

[ Vapour density ]:
4.7 (vs air)

[ Vapour Pressure ]:
1.5±0.2 mmHg at 25°C

[ Index of Refraction ]:
1.468

[ Stability ]:
Stable. Flammable. Incompatible with strong oxidizing agents.

[ Water Solubility ]:
<1 g/100mL

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
OS8100000
CHEMICAL NAME :
p-Mentha-1,8-diene
CAS REGISTRY NUMBER :
138-86-3
LAST UPDATED :
199712
DATA ITEMS CITED :
12
MOLECULAR FORMULA :
C10-H16
MOLECULAR WEIGHT :
136.26
WISWESSER LINE NOTATION :
L6UTJ A1 DY1&U1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
FCTXAV Food and Cosmetics Toxicology. (London, UK) V.1-19, 1963-81. For publisher information, see FCTOD7. Volume(issue)/page/year: 12,703,1974 ** ACUTE TOXICITY DATA **
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
5300 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
FCTXAV Food and Cosmetics Toxicology. (London, UK) V.1-19, 1963-81. For publisher information, see FCTOD7. Volume(issue)/page/year: 12,703,1974
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
5550 uL/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
ZYZAEU Zhongguo Yaoxue Zazhi. Chinese Pharmacuetical Journal. (China International Book Trading Corp., POB 2820, Beijing, Peop. China) V.24- 1989- Volume(issue)/page/year: 24,700,1989
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
1010 uL/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
ZYZAEU Zhongguo Yaoxue Zazhi. Chinese Pharmacuetical Journal. (China International Book Trading Corp., POB 2820, Beijing, Peop. China) V.24- 1989- Volume(issue)/page/year: 24,700,1989
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Unreported
SPECIES OBSERVED :
Mammal - species unspecified
DOSE/DURATION :
4600 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
RCTOE4 Reviews of Environmental Contamination and Toxicology. (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ 07094) V.98- 1987- Volume(issue)/page/year: 113,47,1990 *** REVIEWS *** TOXICOLOGY REVIEW ZKKOBW Zeitschrift fuer Krebsforschung und Klinische Onkologie. (Berlin, Fed. Rep. Ger.) V.76-92, 1971-78. For publisher information, see JCROD7. Volume(issue)/page/year: 78,99,1972 *** U.S. STANDARDS AND REGULATIONS *** EPA FIFRA 1988 PESTICIDE SUBJECT TO REGISTRATION OR RE-REGISTRATION FEREAC Federal Register. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) V.1- 1936- Volume(issue)/page/year: 54,7740,1989 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - M1342 No. of Facilities: 3959 (estimated) No. of Industries: 70 No. of Occupations: 60 No. of Employees: 45463 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - M1342 No. of Facilities: 12642 (estimated) No. of Industries: 103 No. of Occupations: 90 No. of Employees: 185336 (estimated) No. of Female Employees: 45650 (estimated)

Safety Information

[ Symbol ]:

GHS02, GHS07, GHS09

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H226-H315-H317-H410

[ Precautionary Statements ]:
P273-P280-P501

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant;N:Dangerousfortheenvironment;

[ Risk Phrases ]:
R10;R38;R43;R50/53

[ Safety Phrases ]:
S24-S37-S60-S61

[ RIDADR ]:
UN 2052 3/PG 3

[ WGK Germany ]:
2

[ RTECS ]:
OS8350000

[ Packaging Group ]:
III

[ Hazard Class ]:
3

[ HS Code ]:
2942000000

Synthetic Route

Precursor & DownStream

Precursor

  • (+)-limonene oxide
  • 1-methyl-4-isopropyl-1-cyclohexene
  • Alpha-pinene
  • Terpin Monohydrate
  • (2Z,6E)-3,7-dimethyl-8-trimethylsilyl-2,6-octadien-1-ol
  • Geraniol
  • (2Z,6E)-3,7-dimethyl-8-tributylstannyl-2,6-octadien-1-ol
  • DL-carvone
  • trimethyl((4-(prop-1-en-2-yl)cyclohex-1-en-1-yl)methyl)silane

DownStream

  • 4-(2-iodopropan-2-yl)-1-methylcyclohexene
  • Terpinine-4-ol
  • Piperitenone
  • Cyclohexene,4-(1-methoxy-1-methylethyl)-1-methyl-
  • 1-methoxy-4-(1-methoxy-1-methylethyl)-1-methylcyclohexane
  • 1-methoxy-1-methyl-4-(1-methylvinyl)cyclohexane
  • Cineole
  • Terpineol
  • Cyclohexanemethanol, 4-hydroxy-.alpha., .alpha.,4-trimethyl-
  • DL-carvone

Customs

[ HS Code ]: 2942000000

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Related Compounds

  • Limonene
  • Limonene
  • limonene
  • Limonene
  • a-limonene
  • DL-Limonene
  • (2S,4R)-1-[6-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)hexanoyl]-4-hydroxypyrrolidine-2-carboxylic acid
  • 4,4,5,5,5-Pentafluoro-1-nitropent-1-ene
  • rac-4-{[(1R,2S)-2-[({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)methyl]cyclopentyl]formamido}pentanoic acid
  • (2S)-2-{[(1RS,2SR)-2-[({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)methyl]cyclopentyl]formamido}-4-hydroxybutanoic acid
  • 3-(1-Benzothiophen-3-yl)oxolane-2,5-dione
  • O-[2-(2,3,4-trimethoxyphenyl)propyl]hydroxylamine
  • 1-(1-Benzylpiperidine-3-carbonyl)-4,4-difluoropiperidine
  • 2-(azetidin-2-yl)-6-methoxy-1H-indole
  • N-methyl-1-(quinoxalin-2-yl)cyclopropan-1-amine
  • 5-(morpholin-3-yl)-1H-indole
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