(3-Phenoxyphenyl)methanol

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Names

[ CAS No. ]:
13826-35-2

[ Name ]:
(3-Phenoxyphenyl)methanol

[Synonym ]:
Benzenemethanol, 3-phenoxy-
(3-Phenoxyphenyl)methanol
3-(Hydroxymethyl)diphenyl Ether
EINECS 237-525-1
3-phenoxybenzylalcohol
MFCD00004636
3-Phenoxybenzyl alcohol

Chemical & Physical Properties

[ Density]:
1.2±0.1 g/cm3

[ Boiling Point ]:
377.8±0.0 °C at 760 mmHg

[ Melting Point ]:
4-7°C

[ Molecular Formula ]:
C13H12O2

[ Molecular Weight ]:
200.233

[ Flash Point ]:
151.3±17.4 °C

[ Exact Mass ]:
200.083725

[ PSA ]:
29.46000

[ LogP ]:
3.03

[ Vapour Pressure ]:
0.0±0.9 mmHg at 25°C

[ Index of Refraction ]:
1.596

[ Stability ]:
Stable. Combustible. Incompatible with strong oxidizing agents.

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
DP0775400
CHEMICAL NAME :
Benzyl alcohol, m-phenoxy-
CAS REGISTRY NUMBER :
13826-35-2
BEILSTEIN REFERENCE NO. :
0475312
LAST UPDATED :
199710
DATA ITEMS CITED :
9
MOLECULAR FORMULA :
C13-H12-O2
MOLECULAR WEIGHT :
200.25

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0537668 ** ACUTE TOXICITY DATA **
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
1496 mg/kg
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity) Behavioral - ataxia Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0537669
TYPE OF TEST :
LC - Lethal concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
>2 gm/m3/1H
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0537668
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
2040 mg/kg
TOXIC EFFECTS :
Brain and Coverings - other degenerative changes
REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 35(1),47,1991
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
575 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
JAFCAU Journal of Agricultural and Food Chemistry. (American Chemical Soc., Distribution Office Dept. 223, POB 57136, West End Stn., Washington, DC 20037) V.1- 1953- Volume(issue)/page/year: 25,9,1977
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
10 gm/kg
TOXIC EFFECTS :
Behavioral - muscle weakness Behavioral - ataxia Skin and Appendages - dermatitis, other (after systemic exposure)
REFERENCE :
NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0537669

Safety Information

[ Symbol ]:

GHS07, GHS09

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302-H400

[ Precautionary Statements ]:
P273

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xn:Harmful;

[ Risk Phrases ]:
R22

[ Safety Phrases ]:
S26-S36/37

[ RIDADR ]:
UN 3082 9 / PGIII

[ WGK Germany ]:
3

[ RTECS ]:
DP0775400

[ HS Code ]:
2909491000

Synthetic Route

Precursor & DownStream

Precursor

  • 8-Hydroxyquinoline
  • 3-Hydroxybenzyl alcohol
  • (3-phenoxyphenyl)methyl acetate
  • 3-Phenoxybenzoic acid
  • Boron trifluoride etherate
  • 3-Phenoxybenzaldehyde
  • 1-Methyl-3-phenoxybenzene
  • 1-(CHLOROMTHYL)-3-PHENOXY BENZENE
  • Chlorobenzene
  • alpha-cyano-3-phenoxybenzyl acetate

DownStream

  • 3-Phenoxybenzoic acid
  • methyl 3-phenoxybenzoate
  • 3-Phenoxybenzaldehyde
  • 3-phenoxyphenylacetic acid
  • 3-PHENOXYPHENYLACETONITRILE
  • 1-(Chloromethyl)-3-phenoxybenzene
  • Etofenprox
  • etofenprox-desethyl
  • Permethrin
  • 3-Phenoxybenzonitrile

Customs

[ HS Code ]: 2909491000

[ Summary ]:
2909491000 (3-phenoxyphenyl)methanol。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。Lowest tariff:4.0%。General tariff:11.0%

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Related Compounds

  • (S)-(cyano)(3-phenoxyphenyl)methanol
  • formic acid,(3-phenoxyphenyl)methanol
  • methanesulfonic acid,(3-phenoxyphenyl)methanol
  • 4-methylbenzenesulfonic acid,(3-phenoxyphenyl)methanol
  • m-phenoxy-p-fluorobenzyl alcohol
  • (3-PHENOXYPHENYL)ACETALDEHYDE
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 4-Methylspiro[indoline-3,4'-piperidin]-2-one
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 3-Pyridinecarboxylic acid,4-(methylamino)-5-nitro-6-phenyl-,ethyl ester
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 2-(6-Bromo-1,3-dioxaindan-5-yl)propan-2-amine
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde