triphenyl(trimethylsilylimino)-λ5-phosphane

Names

[ CAS No. ]:
13892-06-3

[ Name ]:
triphenyl(trimethylsilylimino)-λ5-phosphane

[Synonym ]:
Ph3P=NSiMe3
N-Trimethylsilyliminotriphenylphosphorane
MFCD01321268

Chemical & Physical Properties

[ Density]:
1g/cm3

[ Boiling Point ]:
428.9ºC at 760 mmHg

[ Melting Point ]:
76-82ºC(lit.)

[ Molecular Formula ]:
C21H24NPSi

[ Molecular Weight ]:
349.48100

[ Flash Point ]:
213.2ºC

[ Exact Mass ]:
349.14200

[ PSA ]:
22.17000

[ LogP ]:
4.99900

[ Vapour Pressure ]:
3.66E-07mmHg at 25°C

[ Index of Refraction ]:
1.548

MSDS

Click to get detail MSDS

Safety Information

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2931900090

Precursor & DownStream

Precursor

  • Azidotrimethylsilane
  • Triphenylphosphine
  • [[chloro(trimethylsilyl)amino]-dimethylsilyl]methane
  • Chlorotrimethylsilane
  • Triphenylphosphine imine
  • Hexamethyldisilazane

DownStream

  • N-(triphenyl-λ5-phosphanylidene)benzenesulfonamide
  • trimethylsilyl isocyanate
  • N-(1-phenyl-2,2,2-trifluoroethylidene)-N'-(triphenylphosphoranediyl)urea
  • N-Trimethylsilylbenzaldimine
  • 1-(4-methoxyphenyl)-N-trimethylsilylmethanimine
  • (triphenyl-λ5-phosphanylidene)cyanamide

Customs

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

Articles

Pyridine-phosphinimine ligand-accelerated Cu(I)-catalyzed azide-alkyne cycloaddition for preparation of 1-(pyridin-2-yl)-1,2,3-triazole derivatives.

Org. Biomol. Chem. 12(31) , 5954-63, (2014)

A series of phosphinimine ligands were designed and used in the Cu(i)-catalyzed azide-alkyne cycloaddition (CuAAC) reaction of tetrazolo[1,5-a]pyridines and alkynes for the first time. By optimizing t...


More Articles

Related Compounds

  • triphenoxy(trimethylsilylimino)-λ5-phosphane
  • TRICHLORO(TRIMETHYLSILYL)PHOSPHORANIMINE
  • tributoxy(trimethylsilylimino)-λ5-phosphane
  • tributyl(trimethylsilylimino)-λ5-phosphane
  • triethoxy(trimethylsilylimino)-λ5-phosphane
  • heptylidene(triphenyl)-λ5-phosphane
  • 2-((2-Methyl-5-nitrophenyl)sulfonyl)-1-phenyl-1,2,3,4-tetrahydropyrrolo[1,2-a]pyrazine
  • 5-fluoro-N-[2-(4-fluorobenzenesulfonyl)-2-(furan-2-yl)ethyl]-2-methoxybenzene-1-sulfonamide
  • 4-ethoxy-N-(2-((4-fluorophenyl)sulfonyl)-2-(furan-2-yl)ethyl)benzenesulfonamide
  • N-[2-(2-furyl)-2-(2-thienylsulfonyl)ethyl]-3,4-dimethoxybenzenesulfonamide
  • N-[2-(2-furyl)-2-(2-thienylsulfonyl)ethyl]-2,4,6-trimethylbenzenesulfonamide
  • N-[2-(2-furyl)-2-(2-thienylsulfonyl)ethyl]benzenesulfonamide
  • N-(3,4-dimethoxyphenyl)-2-((6-ethyl-1,3-dimethyl-2,4-dioxo-1,2,3,4-tetrahydropyrido[2,3-d]pyrimidin-5-yl)thio)acetamide
  • 4-chloro-N-[2-(furan-2-yl)-2-(thiophene-2-sulfonyl)ethyl]benzene-1-sulfonamide
  • 4-fluoro-N-[2-(2-furyl)-2-(2-thienylsulfonyl)ethyl]-2-methylbenzenesulfonamide
  • 1-(2-Fluorophenyl)-2-((2-methyl-5-nitrophenyl)sulfonyl)-1,2,3,4-tetrahydropyrrolo[1,2-a]pyrazine