Methyl 4-bromo-2-methoxybenzoate

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Names

[ CAS No. ]:
139102-34-4

[ Name ]:
Methyl 4-bromo-2-methoxybenzoate

[Synonym ]:
4-Bromo-2-methoxybenzoic acid methyl ester
Methyl 4-bromo-2-methoxybenzoate
MFCD06797867
Benzoic acid, 4-bromo-2-methoxy-, methyl ester

Chemical & Physical Properties

[ Density]:
1.5±0.1 g/cm3

[ Boiling Point ]:
304.0±22.0 °C at 760 mmHg

[ Melting Point ]:
33ºC(lit.)

[ Molecular Formula ]:
C9H9BrO3

[ Molecular Weight ]:
245.070

[ Flash Point ]:
137.7±22.3 °C

[ Exact Mass ]:
243.973495

[ PSA ]:
35.53000

[ LogP ]:
2.91

[ Vapour Pressure ]:
0.0±0.6 mmHg at 25°C

[ Index of Refraction ]:
1.538

MSDS

Safety Information

[ Symbol ]:

GHS06

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H301

[ Precautionary Statements ]:
P301 + P310

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;Gloves;type P2 (EN 143) respirator cartridges

[ Hazard Codes ]:
T

[ Risk Phrases ]:
R25

[ Safety Phrases ]:
S45

[ RIDADR ]:
UN 2811 6.1/PG 3

[ WGK Germany ]:
3.0

[ Packaging Group ]:
III

[ Hazard Class ]:
6.1

[ HS Code ]:
2918990090

Synthetic Route

Precursor & DownStream

Precursor

  • 4-Bromo-2-hydroxybenzoic acid
  • methyl iodide
  • Methyl 4-bromo-2-hydroxybenzoate
  • 4-Bromo-2-methoxybenzoic acid

DownStream

  • 4-Bromo-2-methoxybenzaldehyde
  • 4-Bromo-2-methoxybenzoic acid
  • 3-methoxy-4-methoxycarbonylphenylboronic acid pinacol ester
  • 3-METHOXY-[1,1'-BIPHENYL]-4-CARBOXYLIC ACID
  • 4-Bromo-2-methoxybenzyl alcohol
  • 4-bromo-2-methoxybenzamide
  • 7-Chloro-2-phenyl-2,3-dihydro-1H-[1,3,2]diazaphospholo[4,5-d]pyri midine 2-oxide

Customs

[ HS Code ]: 2918990090

[ Summary ]:
2918990090. other carboxylic acids with additional oxygen function and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%


Related Compounds

  • methyl 4-bromo-2-fluoro-6-methoxybenzoate
  • Methyl 4-bromo-5-iodo-2-methoxybenzoate
  • Methyl 4-bromo-5-fluoro-2-methoxybenzoate
  • Methyl 4-bromo-5-chloro-2-methoxybenzoate
  • Methyl 4-bromo-2,6-dinitrobenzoate
  • methyl 4-bromo-2,3-dimethylbenzoate