Carbon monooxide-molybdenum (6:1)

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Names

[ CAS No. ]:
13939-06-5

[ Name ]:
Carbon monooxide-molybdenum (6:1)

[Synonym ]:
Carbon monooxide - molybdenum (6:1)
EINECS 237-713-3
carbon monoxide,molybdenum
Molybdenum hexacarbonyl
Hexacarbonylmolybdenum
Hexacarbonylmolybdenum(0)
MFCD00003466

Chemical & Physical Properties

[ Density]:
1.96 g/mL at 25 °C(lit.)

[ Boiling Point ]:
156 °C(lit.)

[ Melting Point ]:
150 °C (dec.)(lit.)

[ Molecular Formula ]:
C6MoO6

[ Molecular Weight ]:
264.001

[ Exact Mass ]:
265.874908

[ Vapour density ]:
9.1 (vs air)

[ Water Solubility ]:
insoluble

MSDS

Safety Information

[ Symbol ]:

GHS06

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H300 + H310 + H330

[ Precautionary Statements ]:
P260-P264-P280-P284-P301 + P310-P302 + P350

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;Gloves;type P2 (EN 143) respirator cartridges

[ Hazard Codes ]:
T+:Verytoxic;

[ Risk Phrases ]:
R26/27/28

[ Safety Phrases ]:
S36/37/39-S45-S36/37-S28A-S22

[ RIDADR ]:
UN 3466 6.1/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
II

[ Hazard Class ]:
6.1

[ HS Code ]:
2931909090

Synthetic Route

Precursor & DownStream

Precursor

  • carbon monoxide
  • Molybdenum
  • Molybdenum, [(2,3,5,6-h)-bicyclo[2.2.1]hepta-2,5-diene]tetracarbonyl-
  • tris(η4-(1-oxo-1-phenylprop-2-ene))molybdenum(0)
  • (η6-C6H5CH3)Mo(CO)3
  • (CO)5Mo(=C(OLi)Ph)

DownStream

  • Methyl 2-benzoylbenzoate
  • 2-Fluorobenzophenone
  • 4-tert-Butylbenzoylacetonitrile
  • Phenyl(3-pyridinyl)methanone
  • 3-(2,4-Dimethylphenyl)-3-oxopropanenitrile
  • 3-(2-Methoxyphenyl)-3-oxopropanenitrile
  • 4'-CYANO-2-PHENYLACETOPHENONE
  • 2-Phenylacetophenone
  • Benzamide
  • 2-Methyl-indanone

Customs

[ HS Code ]: 2931909090

Articles

Determination of Ni(CO)4, Fe(CO)5, Mo(CO)6, and W(CO)6 in sewage gas by using cryotrapping gas chromatography inductively coupled plasma mass spectrometry.

J. Environ. Monit. 1(1) , 33-7, (1999)

Evidence for the occurrence of Ni(CO)4 in addition to Mo(CO)6 and W(CO)6 in fermentation gases from a municipal sewage treatment plant is presented for the first time. The gases were sampled at the to...

In situ generation of carbon monoxide from solid molybdenum hexacarbonyl. A convenient and fast route to palladium-catalyzed carbonylation reactions.

J. Comb. Chem. 4(2) , 109-11, (2002)

Microwave-promoted aminocarbonylations of aryl chlorides using Mo(CO)(6) as a solid carbon monoxide source.

J. Comb. Chem. 8(1) , 4-6, (2006)


More Articles


Related Compounds

  • Benzenesulfonamide,N-(2,3-dichloropropyl)-
  • Carbon monooxide-tungsten (6:1)
  • Carbon monooxide-ruthenium (4:1)
  • Carbon monooxide-rhodium (8:3)
  • Carbon monooxide-rhodium (3:1)
  • Molybdenum monooxide
  • 6-(Chloromethyl)-2-methylnon-2-ene
  • rac-methyl (3R,4S)-4-(5-fluoro-2-methylphenyl)pyrrolidine-3-carboxylate
  • Tert-butyl 5,5-dimethyl-2-(3-oxoprop-1-en-1-yl)piperidine-1-carboxylate
  • N-methyl-1-(1-methylcycloheptyl)methanesulfonamide
  • 3-(Azidomethyl)-2,5-dibromopyridine
  • Tert-butyl 2-amino-3-(3,5-dichloropyridin-4-yl)propanoate
  • rac-(3R,4R)-1-[2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-3-methylpentanoyl]-3,4-dimethylpyrrolidine-3-carboxylic acid
  • 4-(2-Bromoethenyl)-2-methoxy-1-(propan-2-yloxy)benzene
  • 1-[2-(2-Bromo-4-chlorophenyl)propan-2-yl]cyclopropan-1-amine
  • 2-[1-(1,3-Benzothiazol-2-yl)cyclopropyl]propan-2-amine
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