3-Methyl-4-fluorophenylboronic acid

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Names

[ CAS No. ]:
139911-27-6

[ Name ]:
3-Methyl-4-fluorophenylboronic acid

[Synonym ]:
Boronic acid, B-(4-fluoro-3-methylphenyl)-
3-Methyl-4-fluorophenylboronic acid 4-Fluoro-3-methylbenzeneboronic acid
4-Fluoro-m-tolylboronic acid
QBQR DF C1
MFCD01863527
(4-Fluoro-3-methylphenyl)boronic acid
4-Fluoro-3-methylbenzeneboronic acid
B-(4-Fluoro-3-methylbenzene)boronic acid
3-Methyl-4-fluorophenylboronic acid
4-Fluoro-3-methylphenylboronic acid

Chemical & Physical Properties

[ Density]:
1.2±0.1 g/cm3

[ Boiling Point ]:
282.0±50.0 °C at 760 mmHg

[ Melting Point ]:
212-217 °C(lit.)

[ Molecular Formula ]:
C7H8BFO2

[ Molecular Weight ]:
153.947

[ Flash Point ]:
124.3±30.1 °C

[ Exact Mass ]:
154.060135

[ PSA ]:
40.46000

[ LogP ]:
2.10

[ Vapour Pressure ]:
0.0±0.6 mmHg at 25°C

[ Index of Refraction ]:
1.506

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36/37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2931900090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Triisopropylborate
  • 5-Bromo-2-fluorotoluene

DownStream

  • 4'-FLUORO-3'-METHYL-[1,1'-BIPHENYL]-4-CARBOXYLIC ACID

Customs

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

Related Compounds

  • 3-((dimethylamino)Methyl)-4-fluorophenylboronic acid
  • 3-((4-ethylpiperazin-1-yl)Methyl)-4-fluorophenylboronic acid
  • 3-((4-(tert-butoxycarbonyl)piperazin-1-yl)Methyl)-4-fluorophenylboronic acid
  • 2-((4-(tert-butoxycarbonyl)piperazin-1-yl)Methyl)-4-fluorophenylboronic acid
  • 3-Methyl-4-hydroxybenzoic acid
  • 3-Cyano-4-Fluorophenylboronic Acid, Pinacol Ester
  • Methyl 6,7-dimethoxy-4-(2-oxo-2-(p-tolylamino)ethoxy)quinoline-2-carboxylate
  • N-(3,4-difluorophenyl)-2-{[1-(4-isopropylphenyl)-6-oxo-1,6-dihydropyridazin-3-yl]thio}acetamide
  • Methyl 6,7-dimethoxy-4-({[4-(propan-2-yl)phenyl]carbamoyl}methoxy)quinoline-2-carboxylate
  • Methyl 4-{[(4-fluorophenyl)carbamoyl]methoxy}-6,7-dimethoxyquinoline-2-carboxylate
  • Methyl 6,7-dimethoxy-4-{[(2-methylphenyl)carbamoyl]methoxy}quinoline-2-carboxylate
  • Methyl 6,7-dimethoxy-4-(2-oxo-2-(m-tolylamino)ethoxy)quinoline-2-carboxylate
  • Methyl 4-(2-(mesitylamino)-2-oxoethoxy)-6,7-dimethoxyquinoline-2-carboxylate
  • Methyl 4-(2-((2,4-dimethylphenyl)amino)-2-oxoethoxy)-6,7-dimethoxyquinoline-2-carboxylate
  • Methyl 4-(2-((2-chloro-4-methylphenyl)amino)-2-oxoethoxy)-6,7-dimethoxyquinoline-2-carboxylate
  • N-(4-fluorobenzyl)-1-[3-(morpholin-4-ylsulfonyl)pyridin-2-yl]piperidine-4-carboxamide
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