5-Bromo-2-(methylsulfanyl)pyrimidine

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Names

[ CAS No. ]:
14001-67-3

[ Name ]:
5-Bromo-2-(methylsulfanyl)pyrimidine

[Synonym ]:
5-Bromo-2-methylthiopyrimidine
5-Bromo-2-(methylsulfanyl)pyrimidine
Pyrimidine, 5-bromo-2-(methylthio)-
5-bromo-2-methylsulfanylpyrimidine
T6N CNJ BS1 EE

Chemical & Physical Properties

[ Density]:
1.7±0.1 g/cm3

[ Boiling Point ]:
281.2±13.0 °C at 760 mmHg

[ Melting Point ]:
63-68℃

[ Molecular Formula ]:
C5H5BrN2S

[ Molecular Weight ]:
205.076

[ Flash Point ]:
123.9±19.8 °C

[ Exact Mass ]:
203.935669

[ PSA ]:
51.08000

[ LogP ]:
2.01

[ Appearance of Characters ]:
Crystalline Powder of Flakes | White

[ Vapour Pressure ]:
0.0±0.6 mmHg at 25°C

[ Index of Refraction ]:
1.636

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS05, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H302-H314

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
Xi: Irritant;Xn: Harmful;

[ Risk Phrases ]:
22-34

[ Safety Phrases ]:
26-36/37/39-45

[ RIDADR ]:
UN 1759 8/PG 2

[ Packaging Group ]:
Ⅱ

[ Hazard Class ]:
8.0

[ HS Code ]:
2933599090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 5-Bromo-2-chloropyrimidine
  • Sodium thiomethoxide
  • 2-Methylthiopyrimidine
  • 5-Bromo-4-chloro-2-(methylthio)pyrimidine
  • Carbon tetrachloride
  • 4,5-dibromo-2-methylsulfanyl-4,5-dihydro-pyrimidine
  • 5-Bromo-2-(methylsulfanyl)-4-pyrimidine-carboxylic acid
  • Ethanol

DownStream

  • 2-(Methylthio)pyrimidin-5-ol
  • 5-Bromo-2-(methylsulfonyl)pyrimidine
  • 2-(methylthio)pyrimidine-5-boronic acid
  • 5-Bromo-2-hydroxypyrimidine
  • 2-(methylthio)pyrimidine-5-boronic acid pinacol ester
  • 2-Methylthiopyrimidine
  • dimethylbis-(2-methylthiopyrimidin-5-yl)tin
  • 2-methylthio-5-trimethylstannylpyrimidine
  • 2-Methoxy-5-bromopyrimidine
  • 2-Methylthio-5-(tributylstannyl)pyrimidine

Customs

[ HS Code ]: 2933599090

[ Summary ]:
2933599090. other compounds containing a pyrimidine ring (whether or not hydrogenated) or piperazine ring in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Related Compounds

  • 5-bromo-2-(methylsulfanyl)pyrimidine-4-carboxylic acid
  • 5-bromo-2-methylsulfanyl-1H-pyrimidine-4,6-dione
  • 5-bromo-2-(methylsulfanyl)-4-[(methylsulfonyl)methyl]pyrimidine
  • 5-bromo-2,4-bis[(4-nitrophenyl)methylsulfanyl]pyrimidine
  • 5-BROMO-2-METHOXY-4-(METHYLTHIO)PYRIMIDINE
  • 5-bromo-2-iodo-4-methylsulfanylpyrimidine
  • 1-[7-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)heptanoyl]-4-methylpyrrolidine-3-carboxylic acid
  • 2-[N-(butan-2-yl)-3-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-2,2,3-trimethylbutanamido]acetic acid
  • 7-[2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-1,3-thiazole-4-carbonyl]-7-azabicyclo[2.2.1]heptane-2-carboxylic acid
  • 3-{N-ethyl-1-[4-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)phenyl]formamido}-2-methylpropanoic acid
  • 3,5-dichloro-2-[3-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-2-methylpropanamido]benzoic acid
  • 4-bromo-2-[(2R)-2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-3-methylbutanamido]benzoic acid
  • 3-{3-[({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)methyl]-5-methylhexanoyl}-1,3-thiazolidine-4-carboxylic acid
  • 2-(1-{2-[3-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)phenyl]acetyl}azetidin-3-yl)acetic acid
  • (2S)-2-{[2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-4-methyl-1,3-thiazol-5-yl]formamido}-4-methylpentanoic acid
  • 1-[3-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)propanoyl]-1,2,3,4-tetrahydroquinoline-4-carboxylic acid
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