trans-Dichlorobis(triphenylphosphine)platinum(II)

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Names

[ CAS No. ]:
14056-88-3

[ Name ]:
trans-Dichlorobis(triphenylphosphine)platinum(II)

[Synonym ]:
MFCD00010825

Chemical & Physical Properties

[ Melting Point ]:
≥300ºC(lit.)

[ Molecular Formula ]:
C36H30Cl2P2Pt

[ Molecular Weight ]:
790.55500

[ Exact Mass ]:
789.08500

[ PSA ]:
27.18000

[ LogP ]:
8.26610

MSDS

Safety Information

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
26-37/39

[ WGK Germany ]:
3

Synthetic Route

Precursor & DownStream

Precursor

  • Bis(benzonitrile)dichloroplatinum(II)
  • Triphenylphosphine
  • Platinum-triphenylphosphine (1:4)
  • cis-[Cl2Pt(S(O)Me2)2]

DownStream

  • Platinum,bis(benzenethiolato)bis(triphenylphosphine)-
  • trans-[Pt(P(phenyl)3)2Cl(SC6H5)]
  • cis-Pt(SPh)2(PPh3)2
  • trans-{(PPh3)2Pt(CNC6H11)Cl}BF4
  • sodium chloride
  • trans-{(PPh3)2Pt(CNBu-t)Cl}BF4
  • trans-{(PPh3)2Pt(CNC6H4-p-Me)Cl}BF4

Related Compounds

  • 2-(4-(4-Chloro-1,3,5-triazin-2-ylamino)pyridin-2-yl)propan-2-ol
  • 1-(2,3,4-Trifluorophenyl)propan-2-ol
  • 2-(Bromomethyl)-6-(difluoromethyl)-4-fluoropyridine-3-acetonitrile
  • 2-(Bromomethyl)-6-(difluoromethyl)-3-iodopyridine-5-methanol
  • 1-(3-Chloro-2-fluorophenyl)ethane-1,2-diol
  • 2-(Chloromethyl)-3-(difluoromethyl)-4-iodopyridine-6-acetonitrile
  • 2-(Bromomethyl)-6-cyano-3-(difluoromethyl)-4-(trifluoromethoxy)pyridine
  • US10093646, Example 8
  • 1-[1-(6-Chloropyrimidin-4-yl)pyrrolidin-3-yl]ethan-1-ol
  • 2-amino-1-(6-chloro-1H-indol-3-yl)propan-1-one
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