Ethyl (4-methylphenyl)acetate

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Names

[ CAS No. ]:
14062-19-2

[ Name ]:
Ethyl (4-methylphenyl)acetate

[Synonym ]:
p-Tolylacetic Acid Ethyl Ester
Ethyl (4-methylphenyl)acetate
MFCD00009181
Benzeneacetic acid, 4-methyl-, ethyl ester
Ethyl 4-Methylphenylacetate
ethyl 2-(4-methylphenyl)acetate
4-Methylphenylacetic Acid Ethyl Ester
EINECS 237-904-1
Ethyl p-Tolylacetate

Chemical & Physical Properties

[ Density]:
1.0±0.1 g/cm3

[ Boiling Point ]:
240.1±0.0 °C at 760 mmHg

[ Melting Point ]:
62-63

[ Molecular Formula ]:
C11H14O2

[ Molecular Weight ]:
178.228

[ Flash Point ]:
109.4±0.0 °C

[ Exact Mass ]:
178.099380

[ PSA ]:
26.30000

[ LogP ]:
2.96

[ Vapour Pressure ]:
0.0±0.4 mmHg at 25°C

[ Index of Refraction ]:
1.502

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2916399090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Ethanol
  • Tolylacetic acid
  • 4-Tolylboronic acid
  • ethyl 2-bromoacetate
  • carbon monoxide
  • p-Xylene
  • 4-Bromotoluene
  • Potassium monoethyl malonate
  • ethyl 2-tributylstannylacetate
  • (E)-2-(1H-1,2,3-benzotriazol-1-yl)-1-(4-methylphenyl)ethenyl trifluoromethanesulfonate

DownStream

  • 2-(p-Tolyl)acetohydrazide
  • 2-(p-Tolyl)propanoic acid
  • cumin carbinol
  • 2,1,3-BENZOXADIAZOLE-5-CARBALDEHYDE 1-OXIDE
  • Diethyl 2-(p-tolyl)malonate
  • toluene, p-(2-bromoethyl)-
  • 4-Tolylmethylcarbinol
  • Tolylacetic acid
  • P-METHYLPHENYLACETALDEHYDE
  • 2-(3-Chlorophenyl)-1-(3-pyridinyl)-1-ethanone

Customs

[ HS Code ]: 2916399090

[ Summary ]:
2916399090 other aromatic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Articles

The condensation of acetylenic esters with ethyl phenylacetates. Al-Jallo HN and Al-Hajjar FH.

J. Chem. Soc. Sect. C 15 , 2056-58, (1970)

Synthesis of 2-(4-bromomethylphenyl) propionic acid and ester. Liu Z-X and Cheng Q-R.

Chemical Reagents 4 , 021, (2011)

Ring-Closing Metathesis Enabled Efficient Synthesis of ?-Butenolide Antifungal Agent (-)-Incrustoporin and its Analogues. Fernandes RA, et al.

Asian J. Org. Chem. 3(1) , 58-62, (2014)


More Articles

Related Compounds

  • Ethyl [(4-methylphenyl)sulfanyl]acetate
  • Ethyl [(4-methylphenyl)amino]acetate
  • ethyl 4-methylphenyl(phenylsulfonyl)acetate
  • ethyl [(4-methylphenyl)sulfonyl](1-methylpyrrolidin-2-ylidene)acetate
  • Ethyl(4-methylphenyl)carbodiimid
  • ethyl-(4-methylphenyl)-propoxyphosphane