Diethyl chloromalonate

Suppliers

Names

[ CAS No. ]:
14064-10-9

[ Name ]:
Diethyl chloromalonate

[Synonym ]:
Diethyl 2-chloromalonate
Propanedioic acid, 2-chloro-, diethyl ester
2-CHLORO-MALONIC ACID DIETHYL ESTER
MFCD00009140
Diethyl chloromalonate
EINECS 237-913-0
Diethyl chloro malonate

Chemical & Physical Properties

[ Density]:
1.2±0.1 g/cm3

[ Boiling Point ]:
222.0±0.0 °C at 760 mmHg

[ Molecular Formula ]:
C7H11ClO4

[ Molecular Weight ]:
194.613

[ Flash Point ]:
103.3±0.0 °C

[ Exact Mass ]:
194.034592

[ PSA ]:
52.60000

[ LogP ]:
1.30

[ Vapour Pressure ]:
0.1±0.4 mmHg at 25°C

[ Index of Refraction ]:
1.439

[ Storage condition ]:
-20?C Freezer, Under Inert Atmosphere

MSDS

Safety Information

[ Symbol ]:

GHS05, GHS07, GHS09

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314-H335-H400

[ Precautionary Statements ]:
P261-P273-P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
C:Corrosive

[ Risk Phrases ]:
R34;R36/37

[ Safety Phrases ]:
S26-S27-S28-S36/37/39-S45

[ RIDADR ]:
UN 3265 8/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
8

[ HS Code ]:
29171990

Synthetic Route

Customs

[ HS Code ]: 2917190090

[ Summary ]:
2917190090 acyclic polycarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Articles

K2CO3-promoted domino reactions: construction of functionalized 2,3-dihydrobenzofurans and clofibrate analogues.

J. Org. Chem. 76(17) , 7222-8, (2011)

The K(2)CO(3)-catalyzed domino reactions (Michael alkylation, Mannich alkylation, and aldol alkylation) of salicylic aldehyde derivatives (2-hydroxyaryl-α,β-unsaturated ketones, 2-hydroxyarylnitroalke...

Preparation of 2-amino-4(3H)-oxopyrimido[5,4-b] [1,4]thiazines (5-thiapterins) and their evaluation as cofactors for phenylalanine hydroxylase.

J. Med. Chem. 26(4) , 559-63, (1983)

Reaction of diethyl chloromalonate with beta-mercapto amines, 9, gave 1,4-thiazin-3-ones, 10, which were alkylated exclusively at the lactam oxygen with triethyloxonium tetrafluoroborate and subsequen...

Preparation of cycloaddition chemistry of thio-and selenocarbonyls derived from reaction of elemental sulfur and selenium with stabilized a-halo anions. Abelman MM.

Tetrahedron Lett. 32(50) , 7389-92, (1990)


More Articles


Related Compounds

  • diethyl 2-hydroxy-3-(1,2,4-triazol-1-yl)propylphosphonate
  • diethyl (4-methoxyphenylthio)methylphosphonate
  • diethyl N-methylaminomethylphosphonate
  • diethyl 1-cyano-1-(4-isobutylphenyl)ethylphosphate
  • diethyl 2-(1-ethylsulfanyl-2-methylpropyl)propanedioate
  • diethyl 2-benzyl-2-pentylpropanedioate