Diethyl chloromalonate
Suppliers
Names
[ CAS No. ]:
14064-10-9
[ Name ]:
Diethyl chloromalonate
[Synonym ]:
Diethyl 2-chloromalonate
Propanedioic acid, 2-chloro-, diethyl ester
2-CHLORO-MALONIC ACID DIETHYL ESTER
MFCD00009140
Diethyl chloromalonate
EINECS 237-913-0
Diethyl chloro malonate
Chemical & Physical Properties
[ Density]:
1.2±0.1 g/cm3
[ Boiling Point ]:
222.0±0.0 °C at 760 mmHg
[ Molecular Formula ]:
C7H11ClO4
[ Molecular Weight ]:
194.613
[ Flash Point ]:
103.3±0.0 °C
[ Exact Mass ]:
194.034592
[ PSA ]:
52.60000
[ LogP ]:
1.30
[ Vapour Pressure ]:
0.1±0.4 mmHg at 25°C
[ Index of Refraction ]:
1.439
[ Storage condition ]:
-20?C Freezer, Under Inert Atmosphere
MSDS
Safety Information
[ Symbol ]:
GHS05, GHS07, GHS09
[ Signal Word ]:
Danger
[ Hazard Statements ]:
H314-H335-H400
[ Precautionary Statements ]:
P261-P273-P280-P305 + P351 + P338-P310
[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ Hazard Codes ]:
C:Corrosive
[ Risk Phrases ]:
R34;R36/37
[ Safety Phrases ]:
S26-S27-S28-S36/37/39-S45
[ RIDADR ]:
UN 3265 8/PG 2
[ WGK Germany ]:
3
[ Packaging Group ]:
III
[ Hazard Class ]:
8
[ HS Code ]:
29171990
Synthetic Route
Customs
[ HS Code ]: 2917190090
[ Summary ]:
2917190090 acyclic polycarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%
Articles
J. Org. Chem. 76(17) , 7222-8, (2011)
The K(2)CO(3)-catalyzed domino reactions (Michael alkylation, Mannich alkylation, and aldol alkylation) of salicylic aldehyde derivatives (2-hydroxyaryl-α,β-unsaturated ketones, 2-hydroxyarylnitroalke...
J. Med. Chem. 26(4) , 559-63, (1983)
Reaction of diethyl chloromalonate with beta-mercapto amines, 9, gave 1,4-thiazin-3-ones, 10, which were alkylated exclusively at the lactam oxygen with triethyloxonium tetrafluoroborate and subsequen...
Preparation of cycloaddition chemistry of thio-and selenocarbonyls derived from reaction of elemental sulfur and selenium with stabilized a-halo anions. Abelman MM.Tetrahedron Lett. 32(50) , 7389-92, (1990)