Methyl 3-Amino-3-deoxy-α-D-mannopyranoside, Hydrochloride

Names

[ CAS No. ]:
14133-35-8

[ Name ]:
Methyl 3-Amino-3-deoxy-α-D-mannopyranoside, Hydrochloride

[Synonym ]:
METHYL 3-AMINO-3-DEOXY-α-D-MANNOPYRANOSIDE HYDROCHLORIDE

Chemical & Physical Properties

[ Melting Point ]:
238-240ºC

[ Molecular Formula ]:
C7H16ClNO5

[ Molecular Weight ]:
229.65900

[ Exact Mass ]:
229.07200

[ PSA ]:
105.17000

Safety Information

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Methyl-3-nitro-3-desoxy-α-D-mannopyranosid
  • (2R)-3-hydroxy-2-[(1S)-1-methoxy-2-oxoethoxy]propanal
  • alpha-D-Methylglucoside

DownStream

  • swainsonine

Articles

Direct stereocontrolled synthesis of 3-amino-3-deoxy-beta-mannopyranosides: importance of the nitrogen protecting group on stereoselectivity.

J. Org. Chem. 72 , 5183-92, (2007)

The highly stereocontrolled synthesis of the 3-amino-3-deoxy-beta-mannopyranosides is achieved by means of thioglycoside donors protected with a 4,6-O-benzylidene or alkylidene acetal and a benzyliden...


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