Salcomine

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Names

[ CAS No. ]:
14167-18-1

[ Name ]:
Salcomine

[Synonym ]:
N,N'-Ethylenebis(salicylideneiminato)cobalt(II)
N,N'-Bis(salicylidene)ethylenediiminocobalt(II)
SalcoMine [=N,N'-Bis(salicylidene)ethylenediiMinocobalt(II)]
Cobalt, [2,2'-[1,2-ethanediylbis(nitrilomethylidyne)]bis[phenolato-κO](2-)]-
MFCD00000009
N,N'-Disalicylalethylenediamine Cobalt(II)
{2,2'-[1,2-Ethanediylbis(nitrilomethylylidene)]diphenolato-κO(2-)}cobalt
EINECS 238-012-5
Salcomine

Chemical & Physical Properties

[ Boiling Point ]:
498.2ºC at 760 mmHg

[ Molecular Formula ]:
C16H14CoN2O2

[ Molecular Weight ]:
325.228

[ Exact Mass ]:
325.038727

[ PSA ]:
43.18000

[ LogP ]:
1.78200

[ Vapour Pressure ]:
4.65E-10mmHg at 25°C

[ Stability ]:
Stable. Incompatible with strong acids, strong oxidizing agents.

[ Water Solubility ]:
Insoluble in water. Soluble in benzene, chloroform, and pyridine.

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
GG0590000
CHEMICAL NAME :
Cobalt, N,N'-ethylenebis(salicylideneiminato)-
CAS REGISTRY NUMBER :
14167-18-1
LAST UPDATED :
199710
DATA ITEMS CITED :
3
MOLECULAR FORMULA :
C16-H14-Co-N2-O2

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
390 mg/m3/5.5H
TOXIC EFFECTS :
Lungs, Thorax, or Respiration - structural or functional change in trachea or bronchi Lungs, Thorax, or Respiration - chronic pulmonary edema Lungs, Thorax, or Respiration - other changes
REFERENCE :
AMRL** Aerospace Medical Research Laboratory Report. (Aerospace Technical Div., Air Force Systems Command, Wright-Patterson Air Force Base, OH 45433) Volume(issue)/page/year: TR-74-78,1974

Safety Information

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ WGK Germany ]:
2

[ RTECS ]:
GG0590000

Synthetic Route

Precursor & DownStream

Precursor

  • Cobalt acetate
  • n,n'-bis(salicylidene)ethylenediamine
  • [(aqua)(Co(III))(sal2en)]hydroxide
  • [(N,N’-bis(salicylidene)ethylenediamine)Co3+(acetate)]
  • Diethyl ketomalonate

DownStream


Related Compounds

  • (2S,4S)-1-[(2R)-2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)pentanoyl]-4-hydroxypyrrolidine-2-carboxylic acid
  • (2S)-2-{[(1RS,2SR)-2-[({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)methyl]cyclopentyl]formamido}propanoic acid
  • 2-[(2R)-2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-N-(2-hydroxyethyl)-3-(1H-imidazol-4-yl)propanamido]acetic acid
  • (2R)-2-[(2S)-2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-3-(1H-imidazol-5-yl)propanamido]butanoic acid
  • 2-{2-[2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)ethoxy]acetamido}-2-methylcyclohexane-1-carboxylic acid
  • 3-[(2S)-3-(dimethylamino)-2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)propanamido]propanoic acid
  • 4-(2-{3-[({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)methyl]cyclopentyl}acetamido)-3-hydroxybutanoic acid
  • 1-(2-{3-[({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)methyl]cyclopentyl}-N-methylacetamido)cyclopropane-1-carboxylic acid
  • 3-cyclopropyl-3-[2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)butanamido]-2,2-difluoropropanoic acid
  • 3-cyclopropyl-3-[2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)pent-4-enamido]-2,2-difluoropropanoic acid
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