tert-butyl 3-(methanesulfonyloxy)azetidine-1-carboxylate

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Names

[ CAS No. ]:
141699-58-3

[ Name ]:
tert-butyl 3-(methanesulfonyloxy)azetidine-1-carboxylate

[Synonym ]:
tert-Butyl 3-[(methylsulfonyl)oxy]azetidine-1-carboxylate
2-Methyl-2-propanyl 3-[(methylsulfonyl)oxy]-1-azetidinecarboxylate
tert-butyl 3-methylsulfonyloxyazetidine-1-carboxylate
1-Azetidinecarboxylic acid, 3-[(methylsulfonyl)oxy]-, 1,1-dimethylethyl ester
tert-Butyl 3-[(methylsulfonyl)oxy]-1-azetanecarboxylate

Chemical & Physical Properties

[ Density]:
1.3±0.1 g/cm3

[ Boiling Point ]:
378.5±31.0 °C at 760 mmHg

[ Melting Point ]:
69 °C

[ Molecular Formula ]:
C9H17NO5S

[ Molecular Weight ]:
251.300

[ Flash Point ]:
182.7±24.8 °C

[ Exact Mass ]:
251.082748

[ PSA ]:
81.29000

[ LogP ]:
-0.01

[ Vapour Pressure ]:
0.0±0.9 mmHg at 25°C

[ Index of Refraction ]:
1.504

[ Storage condition ]:
2-8°C

MSDS

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Safety Information

[ Symbol ]:

GHS06

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H301

[ Precautionary Statements ]:
P301 + P310

[ Hazard Codes ]:
T+

[ RIDADR ]:
2811.0

[ Hazard Class ]:
6.1

[ HS Code ]:
2933990090

Synthetic Route

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Precursor & DownStream

Precursor

  • Methanesulfonyl chloride
  • 1-N-Boc-3-hydroxyazetidine
  • Di-tert-butyl dicarbonate
  • 3-Azetidinyl methanesulfonate hydrochloride (1:1)
  • 3-(Methanesulfonyloxy)azetidine

DownStream

  • 1-Boc-3-(Aminomethyl)azetidine
  • 1-Boc-3-cyano azetidine
  • 2-Methyl-2-propanyl 3-iodo-1-azetidinecarboxylate
  • 1-Boc-3-(4-Bromo-1H-pyrazol-1-yl)azetidine
  • tert-butyl 3-[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyrazol-1-yl]azetidine-1-carboxylate

Customs

[ HS Code ]: 2933990090

[ Summary ]:
2933990090. heterocyclic compounds with nitrogen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Related Compounds

  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 2-Methyl-3-(quinolin-3-yl)propan-1-amine
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • tert-Butyl-DL-alanine
  • 4-amino-N-[2-tert-butyl-1-(tetrahydro-2H-pyran-4-ylmethyl)-1H-benzimidazol-5-yl]-N-ethylbenzenesulfonamide