(2',5'-bis-O-(tert-butyldimethylsilyl)-beta-ribofuranosyl)-3'-spiro-5''-(4''-amino-1'',2''-oxathiole-2'',2''-dioxide)thymine

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Names

[ CAS No. ]:
141781-17-1

[ Name ]:
(2',5'-bis-O-(tert-butyldimethylsilyl)-beta-ribofuranosyl)-3'-spiro-5''-(4''-amino-1'',2''-oxathiole-2'',2''-dioxide)thymine

[Synonym ]:
Tsao-T
C24H43N3O8SSi2
2',5'-bis-O-(tert-butyldimethylsilyl)-3'-spiro-5''-(4''-amino-1'',2''-oxathiole-2'',2''-dioxide)pyrimidine
2,4(1H,3H)-Pyrimidinedione,1-(4-amino-9-(((1,1-dimethylethyl)dimethylsilyl)oxy)-6-((((1,1-dimethylethyl)dimethylsilyl)oxy)methyl)-1,7-dioxa-2-thiaspiro(4,4)non-3-en-8-yl)-5-methyl-,S,S-dioxide. (5R-(5alpha,6beta,8beta,9alpha))
3qo9

Chemical & Physical Properties

[ Density]:
1.22g/cm3

[ Molecular Formula ]:
C24H43N3O8SSi2

[ Molecular Weight ]:
589.85000

[ Exact Mass ]:
589.23100

[ PSA ]:
160.58000

[ LogP ]:
5.24690

[ Index of Refraction ]:
1.541

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • [(2R,3R,4R,5R)-4-[tert-butyl(dimethyl)silyl]oxy-2-[[tert-butyl(dimethyl)silyl]oxymethyl]-3-cyano-5-(5-methyl-2,4-dioxopyrimidin-1-yl)oxolan-3-yl] methanesulfonate
  • tert-Butyldimethylsilyl chloride
  • 5-O-Benzoyl-1,2-O-(1-methylethylidene)pentofuranos-3-ulose
  • ((3aR,5R,6R,6aR)-6-cyano-6-hydroxy-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxol-5-yl)methyl benzoate
  • [(6R,8R,9R)-9-acetyloxy-4-amino-8-(5-methyl-2,4-dioxopyrimidin-1-yl)-2,2-dioxo-1,7-dioxa-2λ6-thiaspiro[4.4]non-3-en-6-yl]methyl benzoate

DownStream

  • 1-[(6R,8R,9R)-4-amino-9-[tert-butyl(dimethyl)silyl]oxy-6-[[tert-butyl(dimethyl)silyl]oxymethyl]-2,2-dioxo-1,7-dioxa-2λ6-thiaspiro[4.4]non-3-en-8-yl]-5-methyl-3-(3-methylbut-2-enyl)pyrimidine-2,4-dione
  • 1-[(6R,8R,9R)-4-amino-9-[tert-butyl(dimethyl)silyl]oxy-6-(hydroxymethyl)-2,2-dioxo-1,7-dioxa-2λ6-thiaspiro[4.4]non-3-en-8-yl]-5-methylpyrimidine-2,4-dione
  • 1-[(6R,8R)-4-amino-6-[[tert-butyl(dimethyl)silyl]oxymethyl]-2,2-dioxo-1,7-dioxa-2λ6-thiaspiro[4.4]non-3-en-8-yl]-5-methylpyrimidine-2,4-dione
  • 4-amino-1-[(6R,8R,9R)-4-amino-9-[tert-butyl(dimethyl)silyl]oxy-6-[[tert-butyl(dimethyl)silyl]oxymethyl]-2,2-dioxo-1,7-dioxa-2λ6-thiaspiro[4.4]non-3-en-8-yl]-5-methylpyrimidin-2-one
  • 1-[(6R,8R,9R)-4-amino-6-[[tert-butyl(dimethyl)silyl]oxymethyl]-9-hydroxy-2,2-dioxo-1,7-dioxa-2λ6-thiaspiro[4.4]non-3-en-8-yl]-5-methylpyrimidine-2,4-dione
  • 1-[(6R,8R,9R)-4-amino-9-[tert-butyl(dimethyl)silyl]oxy-6-[[tert-butyl(dimethyl)silyl]oxymethyl]-2,2-dioxo-1,7-dioxa-2λ6-thiaspiro[4.4]non-3-en-8-yl]-3-ethyl-5-methylpyrimidine-2,4-dione

Related Compounds

  • 5-Fluoro-3-methyl-2-(phenylmethoxycarbonylamino)benzoic acid
  • 5-Fluoro-2-[methyl(phenylmethoxycarbonyl)amino]benzoic acid
  • 1-Phenylmethoxycarbonyl-2,3-dihydroindole-4-carboxylic acid
  • 6-Methyl-2-[methyl(phenylmethoxycarbonyl)amino]pyrimidine-4-carboxylic acid
  • 4-Fluoro-3-methyl-2-(phenylmethoxycarbonylamino)benzoic acid
  • 4-[(2-Methylpropan-2-yl)oxycarbonylamino]-2-methylsulfanyl-1,3-thiazole-5-carboxylic acid
  • 6-{[(tert-butoxy)carbonyl]amino}-1H-purine-2-carboxylic acid
  • 4-{[(Tert-butoxy)carbonyl]amino}pyrimidine-2-carboxylic acid
  • 4-{[(Tert-butoxy)carbonyl]amino}-5-methylthiophene-2-carboxylic acid
  • 3-{[(Tert-butoxy)carbonyl]amino}-4-chloro-2-methylbenzoic acid
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