(2',5'-bis-O-(tert-butyldimethylsilyl)-beta-ribofuranosyl)-3'-spiro-5''-(4''-amino-1'',2''-oxathiole-2'',2''-dioxide)thymine

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Names

[ CAS No. ]:
141781-17-1

[ Name ]:
(2',5'-bis-O-(tert-butyldimethylsilyl)-beta-ribofuranosyl)-3'-spiro-5''-(4''-amino-1'',2''-oxathiole-2'',2''-dioxide)thymine

[Synonym ]:
Tsao-T
C24H43N3O8SSi2
2',5'-bis-O-(tert-butyldimethylsilyl)-3'-spiro-5''-(4''-amino-1'',2''-oxathiole-2'',2''-dioxide)pyrimidine
2,4(1H,3H)-Pyrimidinedione,1-(4-amino-9-(((1,1-dimethylethyl)dimethylsilyl)oxy)-6-((((1,1-dimethylethyl)dimethylsilyl)oxy)methyl)-1,7-dioxa-2-thiaspiro(4,4)non-3-en-8-yl)-5-methyl-,S,S-dioxide. (5R-(5alpha,6beta,8beta,9alpha))
3qo9

Chemical & Physical Properties

[ Density]:
1.22g/cm3

[ Molecular Formula ]:
C24H43N3O8SSi2

[ Molecular Weight ]:
589.85000

[ Exact Mass ]:
589.23100

[ PSA ]:
160.58000

[ LogP ]:
5.24690

[ Index of Refraction ]:
1.541

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • [(2R,3R,4R,5R)-4-[tert-butyl(dimethyl)silyl]oxy-2-[[tert-butyl(dimethyl)silyl]oxymethyl]-3-cyano-5-(5-methyl-2,4-dioxopyrimidin-1-yl)oxolan-3-yl] methanesulfonate
  • tert-Butyldimethylsilyl chloride
  • 5-O-Benzoyl-1,2-O-(1-methylethylidene)pentofuranos-3-ulose
  • ((3aR,5R,6R,6aR)-6-cyano-6-hydroxy-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxol-5-yl)methyl benzoate
  • [(6R,8R,9R)-9-acetyloxy-4-amino-8-(5-methyl-2,4-dioxopyrimidin-1-yl)-2,2-dioxo-1,7-dioxa-2λ6-thiaspiro[4.4]non-3-en-6-yl]methyl benzoate

DownStream

  • 1-[(6R,8R,9R)-4-amino-9-[tert-butyl(dimethyl)silyl]oxy-6-[[tert-butyl(dimethyl)silyl]oxymethyl]-2,2-dioxo-1,7-dioxa-2λ6-thiaspiro[4.4]non-3-en-8-yl]-5-methyl-3-(3-methylbut-2-enyl)pyrimidine-2,4-dione
  • 1-[(6R,8R,9R)-4-amino-9-[tert-butyl(dimethyl)silyl]oxy-6-(hydroxymethyl)-2,2-dioxo-1,7-dioxa-2λ6-thiaspiro[4.4]non-3-en-8-yl]-5-methylpyrimidine-2,4-dione
  • 1-[(6R,8R)-4-amino-6-[[tert-butyl(dimethyl)silyl]oxymethyl]-2,2-dioxo-1,7-dioxa-2λ6-thiaspiro[4.4]non-3-en-8-yl]-5-methylpyrimidine-2,4-dione
  • 4-amino-1-[(6R,8R,9R)-4-amino-9-[tert-butyl(dimethyl)silyl]oxy-6-[[tert-butyl(dimethyl)silyl]oxymethyl]-2,2-dioxo-1,7-dioxa-2λ6-thiaspiro[4.4]non-3-en-8-yl]-5-methylpyrimidin-2-one
  • 1-[(6R,8R,9R)-4-amino-6-[[tert-butyl(dimethyl)silyl]oxymethyl]-9-hydroxy-2,2-dioxo-1,7-dioxa-2λ6-thiaspiro[4.4]non-3-en-8-yl]-5-methylpyrimidine-2,4-dione
  • 1-[(6R,8R,9R)-4-amino-9-[tert-butyl(dimethyl)silyl]oxy-6-[[tert-butyl(dimethyl)silyl]oxymethyl]-2,2-dioxo-1,7-dioxa-2λ6-thiaspiro[4.4]non-3-en-8-yl]-3-ethyl-5-methylpyrimidine-2,4-dione

Related Compounds

  • 1-[(5-Nitrothiophen-2-yl)methyl]cyclopropan-1-amine
  • 3-(2,3-Dichlorophenyl)-5-methyl-1,2-oxazol-4-ol
  • 3-(3-Chloro-4-fluorophenyl)-5-methyl-1,2-oxazol-4-ol
  • 5-Methyl-3-[4-(propan-2-yloxy)phenyl]-1,2-oxazol-4-ol
  • 1-(2,2,3-Trimethylbutyl)cyclopropane-1-carbaldehyde
  • 2-[(1-Hydroxycyclopentyl)methyl]-2-methylbutanal
  • 1-(2-Chloroethyl)-2,2-dimethylcyclopropane-1-carbaldehyde
  • 2-(4-Methylpent-3-en-1-yl)thiolane-2-carbaldehyde
  • 2-(But-3-en-1-yl)bicyclo[2.2.1]heptane-2-carbaldehyde
  • 2-Butyloxolane-2-carbaldehyde
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