Tetrakis(triphenylphosphine)palladium

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Names

[ CAS No. ]:
14221-01-3

[ Name ]:
Tetrakis(triphenylphosphine)palladium

[Synonym ]:
Terakis(triphenylphosphine)palladium(0)
palladium,triphenylphosphane
Tetrakis(triphenylphosphine) palladium(0)
EINECS 238-086-9
Palladium-tetrakis(triphenylphosphine) (Pd(PPh3)4
MFCD00010012

Chemical & Physical Properties

[ Boiling Point ]:
360ºC at 760 mmHg

[ Melting Point ]:
103-107 °C

[ Molecular Formula ]:
C72H60P4Pd

[ Molecular Weight ]:
1155.56

[ Flash Point ]:
181.7ºC

[ Exact Mass ]:
1154.268066

[ PSA ]:
54.36000

[ LogP ]:
13.77920

[ Storage condition ]:
2-8°C

[ Water Solubility ]:
insoluble

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS08

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H351

[ Precautionary Statements ]:
P281

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ Hazard Codes ]:
Xn: Harmful;Xi: Irritant;

[ Risk Phrases ]:
R20/22

[ Safety Phrases ]:
S22-S24/25-S36/37

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2843900090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Bis(triphenylphosphine) Palladium (II) Chloride
  • Palladium diacetate
  • Triphenylphosphine
  • [(Et3P)2Pd(μ-S)(μ-CH2O)Ge(N(SiMe3)2)2]
  • carbon monoxide
  • o-bis(diphenylphosphino)benzene
  • Pd(η3-methallyl)(acetylacetonato)palladium

DownStream

  • 3-phenyl-9H-carbazole
  • Methyl 5-chloro-2-cyanobenzoate
  • (5-pyridin-3-ylthiophen-2-yl)methanol
  • 2-Phenylfuran
  • Bis[1,2-bis(diphenylphosphino)ethane]palladium(0)
  • 4-CYANOMETHYLBIPHENYL
  • Bis(triphenylphosphine) Palladium (II) Chloride
  • 4-methyltropone

Customs

[ HS Code ]: 2843900090

Articles

Controlled self-assembly of a pyrene-based bolaamphiphile by acetate ions: from nanodisks to nanofibers by fluorescence enhancement.

Soft Matter 11 , 4424-9, (2015)

In this paper, a pyrene moiety is incorporated into a bolaamphiphile to form a novel molecule denoted PRB. Above the critical micelle concentration, PRB forms nanodisks in the aqueous solution. The ad...

Enzymatic primer-extension with glycerol-nucleoside triphosphates on DNA templates.

PLoS ONE 4(3) , e4949, (2009)

Glycerol nucleic acid (GNA) has an acyclic phosphoglycerol backbone repeat-unit, but forms stable duplexes based on Watson-Crick base-pairing. Because of its structural simplicity, GNA is of particula...

Zwitterionic red fluorescent polymeric nanoparticles for cell imaging.

Macromol. Biosci. 14(10) , 1361-7, (2014)

Phospholipid monomer and aggregation-induced emission (AIE) dye-based dimers are incorporated via reversible addition-fragmentation transfer polymerization to afford cross-linked zwitterionic fluoresc...


More Articles

Related Compounds

  • Bis(triphenylphosphine) Palladium (II) Chloride
  • benzylbis(triphenylphosphine)palladium(ii) chloride
  • Diacetatobis(triphenylphosphine) palladium(II)
  • tris(triphenylphosphine)-palladium(II) dichloride
  • benzoylchlorobis(triphenylphosphine)palladium(II)
  • 2-[BIS(TRIPHENYLPHOSPHINE)PALLADIUM(II)BROMIDE]BENZYL ALCOHOL