(r)-(-)-n-benzyl-2-phenylglycinol

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Names

[ CAS No. ]:
14231-57-3

[ Name ]:
(r)-(-)-n-benzyl-2-phenylglycinol

[Synonym ]:
MFCD00674035

Chemical & Physical Properties

[ Density]:
1.1g/cm3

[ Boiling Point ]:
386.4ºC at 760mmHg

[ Molecular Formula ]:
C15H17NO

[ Molecular Weight ]:
227.30200

[ Flash Point ]:
136.9ºC

[ Exact Mass ]:
227.13100

[ PSA ]:
32.26000

[ LogP ]:
2.90070

[ Vapour Pressure ]:
0mmHg at 25°C

[ Index of Refraction ]:
1.594

[ Storage condition ]:
2-8°C

MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
36/37/38

[ Safety Phrases ]:
26-36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2922199090

Synthetic Route

Precursor & DownStream

Precursor

  • D-2-Phenylglycine
  • D-Plenylglycinol
  • Benzyl bromide
  • (R)-2-BENZAMIDO-2-PHENYLACETIC ACID
  • Benzoyl chloride
  • Benzaldehyde
  • Benzyl chloride
  • (R,E)-2-(1-benzyl-2-(2,2,2-trifluoroethylidene)hydrazinyl)-2-phenylethan-1-ol

DownStream

  • Benzylamine
  • D-Plenylglycinol
  • BOC-L-Phenylglycinol
  • Boc-(S)-3-Amino-3-phenylpropionic acid
  • S-ethyl N-benzylcarbamothioate
  • Acetophenone
  • 3-PHENYLMORPHOLINE

Customs

[ HS Code ]: 2922199090

[ Summary ]:
2922199090. other amino-alcohols, other than those containing more than one kind of oxygen function, their ethers and esters; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Articles

Asymmetric Synthesis of alpha-Amino Phosphonic Acids by Diastereoselective Addition of Trimethyl Phosphite onto Chiral Oxazolidines(1).

J. Org. Chem. 61 , 3687, (1996)

A simple and general asymmetric synthesis of alpha-amino phosphonic acids is described. The method involves the highly selective addition of trialkyl phosphite onto various chiral oxazolidines. Oxazap...

Micouin, L. et al.

Tetrahedron Lett. 35 , 7223, (1994)


More Articles


Related Compounds

  • (R)-N-Benzyl-2-bromo-propionamide
  • (R)-N-Benzyl-2-(3-(3,5-bis(trifluoromethyl)phenyl)thioureido)-N,3,3-trimethylbutanamide
  • (R)-N-Benzyl-2-(benzyloxycarbonylamino)-3-hydroxypropionamide
  • (R)-N-benzyl-2-(dibenzylamino)-3-methoxypropanamide
  • (R)-N-benzyl-2-nitro-N-(5-phenylpent-1-en-3-yl)benzenesulfonamide
  • R-(N-BENZYL-2-AMINO)-1-(4-METHOXYPHENYL)PROPANE (S)-MANDELIC ACID SALT
  • 2-(benzylthio)-N-(3-methylisothiazol-5-yl)acetamide
  • 4-[(3,5-Dimethylphenyl)amino]-6-methylquinoline-2-carboxylic acid
  • I+/--Methyl-N-[4-(1H-tetrazol-1-yl)phenyl]-4-pyridinemethanamine
  • methyl 5-{[methyl(4-methylphenyl)amino]sulfonyl}-1H-pyrazole-4-carboxylate
  • ethyl 1,5-dimethyl-3-(morpholin-4-ylsulfonyl)-1H-pyrazole-4-carboxylate
  • Ethyl 6-({[1,4'-bipiperidine]-1'-yl}methyl)-4-(4-ethylphenyl)-2-oxo-1,2,3,4-tetrahydropyrimidine-5-carboxylate
  • Butyl({1-[3-(difluoromethoxy)phenyl]ethyl})amine
  • Pyrimidine-2-sulfonic acid pentafluorophenyl ester
  • 5-Methyl-1,3,4-thiadiazole-2-sulfonic acid pentafluorophenyl ester
  • N-(3-methylisothiazol-5-yl)-2,2-diphenylacetamide
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