(r)-(-)-n-benzyl-2-phenylglycinol

Names

[ CAS No. ]:
14231-57-3

[ Name ]:
(r)-(-)-n-benzyl-2-phenylglycinol

[Synonym ]:
MFCD00674035

Chemical & Physical Properties

[ Density]:
1.1g/cm3

[ Boiling Point ]:
386.4ºC at 760mmHg

[ Molecular Formula ]:
C₁₅H₁₇NO

[ Molecular Weight ]:
227.30200

[ Flash Point ]:
136.9ºC

[ Exact Mass ]:
227.13100

[ PSA ]:
32.26000

[ LogP ]:
2.90070

[ Vapour Pressure ]:
0mmHg at 25°C

[ Index of Refraction ]:
1.594

[ Storage condition ]:
2-8°C

MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
36/37/38

[ Safety Phrases ]:
26-36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2922199090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

D-2-Phenylglycine
D-Plenylglycinol
Benzyl bromide
(R)-2-BENZAMIDO-2-PHENYLACETIC ACID
Benzoyl chloride
Benzaldehyde
Benzyl chloride
(R,E)-2-(1-benzyl-2-(2,2,2-trifluoroethylidene)hydrazinyl)-2-phenylethan-1-ol

DownStream

Benzylamine
D-Plenylglycinol
BOC-L-Phenylglycinol
Boc-(S)-3-Amino-3-phenylpropionic acid
S-ethyl N-benzylcarbamothioate
Acetophenone
3-PHENYLMORPHOLINE

Customs

[ HS Code ]: 2922199090

[ Summary ]:
2922199090. other amino-alcohols, other than those containing more than one kind of oxygen function, their ethers and esters; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Articles

Asymmetric Synthesis of alpha-Amino Phosphonic Acids by Diastereoselective Addition of Trimethyl Phosphite onto Chiral Oxazolidines(1).

J. Org. Chem. 61 , 3687, (1996)

A simple and general asymmetric synthesis of alpha-amino phosphonic acids is described. The method involves the highly selective addition of trialkyl phosphite onto various chiral oxazolidines. Oxazap...

Micouin, L. et al.

Tetrahedron Lett. 35 , 7223, (1994)

(R)-N-Benzyl-2-bromo-propionamide
(R)-N-Benzyl-2-(3-(3,5-bis(trifluoromethyl)phenyl)thioureido)-N,3,3-trimethylbutanamide
(R)-N-Benzyl-2-(benzyloxycarbonylamino)-3-hydroxypropionamide
(R)-N-benzyl-2-(dibenzylamino)-3-methoxypropanamide
(R)-N-benzyl-2-nitro-N-(5-phenylpent-1-en-3-yl)benzenesulfonamide
R-(N-BENZYL-2-AMINO)-1-(4-METHOXYPHENYL)PROPANE (S)-MANDELIC ACID SALT
6-[5-(ethanesulfonyl)-octahydropyrrolo[3,4-c]pyrrol-2-yl]-9-(2-methoxyethyl)-9H-purine
1-(5-{2-methyl-5H,6H,7H-cyclopenta[d]pyrimidin-4-yl}-octahydropyrrolo[3,4-c]pyrrol-2-yl)-3-phenylpropan-1-one
N-(2,3-difluorophenyl)-4-methylthiophene-2-carboxamide
4-[(5-{2-methyl-5H,6H,7H-cyclopenta[d]pyrimidin-4-yl}-octahydropyrrolo[3,4-c]pyrrol-2-yl)sulfonyl]-1H-imidazole
N-(2-chlorophenyl)-5-{2-methyl-5H,6H,7H-cyclopenta[d]pyrimidin-4-yl}-octahydropyrrolo[3,4-c]pyrrole-2-carboxamide
2-{5,6-Dimethyl-[1,2,4]triazolo[1,5-a]pyrimidin-7-yl}-6,7-dimethoxy-1,2,3,4-tetrahydroisoquinoline
[(2-Hydroxy-4,4-dimethyl-6-oxocyclohex-1-en-1-yl)(phenyl)methyl]urea
2-(2-methoxyphenoxy)-1-(5-{2-methyl-5H,6H,7H-cyclopenta[d]pyrimidin-4-yl}-octahydropyrrolo[3,4-c]pyrrol-2-yl)ethan-1-one
2-(3,4-dimethoxyphenyl)-1-(5-{2-methyl-5H,6H,7H-cyclopenta[d]pyrimidin-4-yl}-octahydropyrrolo[3,4-c]pyrrol-2-yl)ethan-1-one
4-[(5-{2-methyl-5H,6H,7H-cyclopenta[d]pyrimidin-4-yl}-octahydropyrrolo[3,4-c]pyrrol-2-yl)sulfonyl]morpholine

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