Benzo[d][1,3]dioxol-5-amine

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Names

[ Name ]:
Benzo[d][1,3]dioxol-5-amine

[Synonym ]:
5-Amino-1,3-benzodioxole
1-Amino-3,4-methylenedioxybenzene
Aniline, 3,4-(methylenedioxy)-
3,4-Methylenedioxyaniline
4-Amino-1,2-methylenedioxybenzene
Benzo[d][1,3]dioxol-5-amine
MFCD00005832
1,3-Benzodioxol-5-amine
EINECS 238-161-6

Chemical & Physical Properties

[ Density]:
1.3±0.1 g/cm3

[ Boiling Point ]:
267.9±0.0 °C at 760 mmHg

[ Melting Point ]:
39-41 °C(lit.)

[ Molecular Formula ]:
C₇H₇NO₂

[ Molecular Weight ]:
137.136

[ Flash Point ]:
142.8±0.0 °C

[ Exact Mass ]:
137.047684

[ PSA ]:
44.48000

[ LogP ]:
0.78

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.631

[ Water Solubility ]:
slightly soluble

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ Packaging Group ]:
I; II; III

[ Hazard Class ]:
6.1

[ HS Code ]:
29329970

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

3,4-Methylenedioxynitrobenzene
2-(benzo[d][1,3]dioxol-5-yloxy)propanamide
5-Bromo-1,3-benzodioxole
1,3-Benzodioxole
1,3-Benzodioxole,5-chloro-
Aqueous ammonia
1,3-benzodioxole-5-carboxamide
2,4-dinitroso-2,4-diaza-glutaric acid diethyl ester
1,3-Benzodioxole-5-carboxylicacid, 6-nitro-
Piperonylonitrile

DownStream

5H-[1,3]Dioxolo[4,5-f]indole-6,7-dione
N-Ethyl-3,4-(methylenedioxy)aniline
Benzamide, 2-amino-N-1,3-benzodioxol-5-yl- (9CI)
N-[4-[(6-chloro-[1,3]dioxolo[4,5-b]acridin-10-yl)amino]-3-methoxyphenyl]methanesulfonamide
5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1,3-benzodioxole
1-(1,3-Benzodioxol-5-yl)piperidin-4-one
N-Hydroxyethyl-3,4-methylene-dioxyanilinehydrochloride
Sesamol
3,4-(Methylenedioxy)phenyl isocyanate
4-Chloro-6,7-methylenedioxyquinazoline

Customs

[ HS Code ]: 2932999099

[ Summary ]:
2932999099. other heterocyclic compounds with oxygen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

Structural analogues of L-glutamic Acid gamma-(4-hydroxyanilide) and gamma-(3,4-dihydroxyanilde) as potential agents against melanoma.

J. Med. Chem. 22(9) , 1034-7, (1979)

Nine heretofore unknown mono- and dihydroxyanilide analogues of the cytotoxic mushroom metabolites L-glutamic acid gamma-(4-hydroxyanilide) (1) and L-glutamic acid gamma-(3,4-dihydroxyanilide) (3, aga...

A general ruthenium-catalyzed synthesis of aromatic amines.

Angew. Chem. Int. Ed. Engl. 46(43) , 8291-94, (2007)

N-hexylbenzo[d][1,3]dioxol-5-amine
N-ethylbenzo[d][1,3]dioxol-5-amine
6-METHYLBENZO[D][1,3]DIOXOL-5-AMINE
N-methylbenzo[d][1,3]dioxol-5-amine
N-(p-tolyl)benzo[d][1,3]dioxol-5-amine
6-Isopropoxybenzo[d][1,3]dioxol-5-amine
N-(2-ethoxyethyl)thieno[3,2-d]pyrimidin-4-amine
2-((3-butyl-4-oxo-3,4-dihydropyrido[3',2':4,5]thieno[3,2-d]pyrimidin-2-yl)thio)-N-(5-chloro-2-methylphenyl)acetamide
(2S)-1-(pyrazin-2-yl)propan-2-amine
3-(2-Chlorophenoxy)-4-(3-methoxyphenyl)-1-[4-(morpholin-4-yl)butyl]azetidin-2-one
{[2-(3,4-Diethoxyphenyl)ethyl]carbamoyl}methyl 2-(3-methoxyphenyl)acetate
(E)-methyl 3-methyl-2-((1-(thiophen-2-ylsulfonyl)piperidine-4-carbonyl)imino)-2,3-dihydrobenzo[d]thiazole-6-carboxylate
(E)-1-((5-chlorothiophen-2-yl)sulfonyl)-N-(3-methyl-6-nitrobenzo[d]thiazol-2(3H)-ylidene)piperidine-4-carboxamide
2-[(2-Ethylphenyl)amino]-2-oxoethyl (3-methoxyphenyl)acetate
tert-Butyl (S)-3-(3-methoxyphenyl)piperazine-1-carboxylate
(R)-tert-butyl 2-amino-2-(4-methoxyphenyl)ethylcarbamate

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