2-Bromo-3-methylthiophene

Suppliers

Names

[ CAS No. ]:
14282-76-9

[ Name ]:
2-Bromo-3-methylthiophene

[Synonym ]:
Thiophene, 2-bromo-3-methyl-
2-bromo-2-methylthiophene
2-bromo-3-methyl-thiophene
MFCD00059741
Thiophene,2-bromo-3-methyl
3-methyl-2-bromothiophene
2-Bromo-3-methylthiophene
EINECS 238-175-2
2-Brom-3-methyl-thiophen
2-bromo-3-methylthiophen

Chemical & Physical Properties

[ Density]:
1.6±0.1 g/cm3

[ Boiling Point ]:
177.3±20.0 °C at 760 mmHg

[ Molecular Formula ]:
C5H5BrS

[ Molecular Weight ]:
177.062

[ Flash Point ]:
68.3±0.0 °C

[ Exact Mass ]:
175.929520

[ PSA ]:
28.24000

[ LogP ]:
3.21

[ Vapour Pressure ]:
1.4±0.3 mmHg at 25°C

[ Index of Refraction ]:
1.582

[ Storage condition ]:
Keep Cold

MSDS

Safety Information

[ Symbol ]:

GHS05, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H302-H318

[ Precautionary Statements ]:
P280-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
T:Toxic;Xn:Harmful;

[ Risk Phrases ]:
R20/21/22;R25;R36/37/38;R41;R43

[ Safety Phrases ]:
S26-S36/37/39-S45

[ RIDADR ]:
UN 2810

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ HS Code ]:
2934999090

Synthetic Route

Precursor & DownStream

Precursor

  • 3-Methylthiophene
  • N-Bromosuccinimide
  • 2,5-DIBROMO-3-METHYLTHIOPHENE
  • Carbon tetrachloride

DownStream

  • 2-Bromo-3-(bromomethyl)thiophene
  • 3-methyl-2-phenylthiophene
  • ethyl (3R)-1-[4,4-bis(3-methylthiophen-2-yl)but-3-enyl]piperidine-3-carboxylate
  • Bromo(3-methyl-2-thienyl)magnesium
  • 3-methyl-2-thienylboronic acid
  • bis(3-methylthiophen-2-yl)methanone
  • 3-Methylthiophene-2-boronic acid pinacol ester
  • 3-Methyl-2-thiophenecarbonitrile
  • 2,3-Dimethylthiophene
  • 3,3'-DIMETHYL-2,2'-BITHIOPHENYL

Customs

[ HS Code ]: 2934999090

[ Summary ]:
2934999090. other heterocyclic compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

The Effect of Benzoyl Peroxide on the Bromination of Methylthiophenes by N-Bromosuccinimide Dittmer K, et al.

J. Am. Chem. Soc. 71(4) , 1201-4, (1949)

Structural studies of poly (dimethyl-tetrathiophene, an intermediate between poly (thiophene) and poly (3-methylthiophene). Fell HJ, et al.

Synthetic Metals 55(1) , 420-25, (1993)

Regioregular poly (thiophene-3-alkanoic acid) s: water soluble conducting polymers suitable for chromatic chemosensing in solution and solid state. Ewbank PC, et al.

Tetrahedron 60(49) , 11269-275, (2004)


More Articles


Related Compounds

  • 2-Bromo-3-methylthiophene
  • 2-Bromo-3-methylthiophene-5-carboxaldehyde
  • 2-Bromo-3-(methyl-d3)thiophene
  • 2-bromo-5-chloro-3-methylthiophene
  • 2-bromo-5-(diethoxymethyl)-3-methylthiophene
  • 2-bromo-3,5-dimethoxyaniline
  • 2-Amino-2-(4-chloropyrrolo[2,1-f][1,2,4]triazin-7-yl)acetonitrile
  • 3-[(1,2,3-Thiadiazol-4-yl)methyl]piperidin-3-ol
  • 2-methyl-3-[(2S)-pyrrolidin-2-yl]-6-(trifluoromethyl)pyridine
  • 2-(Chloromethyl)-1-(propan-2-yloxy)butane
  • [1-(2-Fluoro-4-methoxyphenyl)cyclobutyl]methanamine
  • 2-Hydroxy-3-(1,2,3-thiadiazol-4-yl)propanoic acid
  • [1-(5-Fluoro-2-methoxyphenyl)cyclobutyl]methanamine
  • N-Ethyl-N-(3-methylpyridin-2-yl)-6-methylsulfonylpyridine-3-carboxamide
  • 5-Bromo-1-methyl-1H-indazole-4-carbonitrile
  • 7-(5-Bromo-1,3-benzoxazol-2-yl)-1,7-diazaspiro[3.5]nonan-2-one
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