Zinc Diethyldithiocarbamate

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Names

[ CAS No. ]:
14324-55-1

[ Name ]:
Zinc Diethyldithiocarbamate

[Synonym ]:
Ethyl ziram
zinc,N,N-diethylcarbamodithioate
bis(Diethylcarbamothioylthio)zinc
Carbamodithioic acid, N,N-diethyl-, zinc salt (2:1)
Accelerator EZ & EZ-SP
Zinc Diethyldithiocarbamate
MFCD00064798
Diethyldithiocarbamic Acid Zinc Salt
Perkacit ZDEC
Zinc bis(diethylcarbamodithioate)
Zinc diethylcarbamodithioate
EINECS 238-270-9
ZBDC

Chemical & Physical Properties

[ Density]:
1,48 g/cm3

[ Boiling Point ]:
176.4ºC at 760 mmHg

[ Melting Point ]:
178-181 °C(lit.)

[ Molecular Formula ]:
C10H20N2S4Zn

[ Molecular Weight ]:
361.948

[ Flash Point ]:
60.5ºC

[ Exact Mass ]:
359.980072

[ PSA ]:
70.66000

[ LogP ]:
2.31750

[ Vapour Pressure ]:
1.1mmHg at 25°C

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
ZH0350000
CHEMICAL NAME :
Zinc, bis(diethyldithiocarbamato)-
CAS REGISTRY NUMBER :
14324-55-1
LAST UPDATED :
199710
DATA ITEMS CITED :
13
MOLECULAR FORMULA :
C10-H22-N2-S4.Zn
MOLECULAR WEIGHT :
363.95
WISWESSER LINE NOTATION :
2N2&YUS&S-ZN-SYUS&N2&2

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
700 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
1400 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
142 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
400 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
28 gm/kg/78W-I
TOXIC EFFECTS :
Tumorigenic - equivocal tumorigenic agent by RTECS criteria Lungs, Thorax, or Respiration - tumors Blood - tumors
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Subcutaneous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
464 mg/kg
TOXIC EFFECTS :
Tumorigenic - Carcinogenic by RTECS criteria Blood - tumors

MUTATION DATA

TYPE OF TEST :
Mutation in microorganisms
TEST SYSTEM :
Bacteria - Salmonella typhimurium
DOSE/DURATION :
25 ug/plate
REFERENCE :
MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 68,313,1979 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 84515 No. of Facilities: 905 (estimated) No. of Industries: 2 No. of Occupations: 12 No. of Employees: 7259 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 84515 No. of Facilities: 406 (estimated) No. of Industries: 9 No. of Occupations: 22 No. of Employees: 12279 (estimated) No. of Female Employees: 1610 (estimated)

Safety Information

[ Hazard Codes ]:
Xn:Harmful

[ Risk Phrases ]:
R22;R36/37/38;R43;R50/53

[ Safety Phrases ]:
S24-S37-S60-S61

[ RIDADR ]:
UN 3077 9/PG 3

[ WGK Germany ]:
3

[ RTECS ]:
ZH0350000

[ Packaging Group ]:
III

[ Hazard Class ]:
6.1

[ HS Code ]:
2935009090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Zinc nitrate hexahydrate
  • Ditiocarb sodium trihydrate
  • Sodium diethyldithiocarbamate
  • Zinc chloride
  • Zinc sulphate
  • Disulfiram
  • Zinc

DownStream

Customs

[ HS Code ]: 2935009090

[ Summary ]:
2935009090 other sulphonamides VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:35.0%

Related Compounds

  • ZINC DIETHYLDITHIOCARBAMATE
  • Zinc, bis(carbamodithioato-S,S')-, ditallow alkyl derivs.
  • Zinc, bis (hydrogen dithiocarbonato)-, O,O-diethyl ester
  • Zinc naphthenate
  • ZINC 2,9,16,23-TETRA-TERT-BUTYL-29 H,31 H-PHTHALOCYANINE
  • zinc perchlorate
  • (2R,5R)-5-(2,3-Dihydro-1H-inden-4-yl)pyrrolidine-2-carboxylic acid
  • Methyl (S)-2-amino-3-(2-phenylpyrimidin-5-yl)propanoate
  • (3S)-3-Methyl-9b-(piperazin-1-yl)-2,3-dihydrooxazolo[2,3-a]isoindol-5(9bH)-one
  • 1-(tert-Butyl) 2-methyl (2S,4S)-4-(5-bromo-4-chloro-2,3-difluorophenoxy)pyrrolidine-1,2-dicarboxylate
  • (R)-2-Amino-3-(5-(trifluoromethyl)pyridin-3-yl)propanoic acid
  • tert-Butyl (4aS,7R,7aS)-7-aminooctahydro-2H-cyclopenta[c]pyridine-2-carboxylate
  • tert-Butyl (2S)-4-fluoro-4-(fluoromethyl)-2-(hydroxymethyl)pyrrolidine-1-carboxylate
  • Methyl 2-cyclopropyl-5-ethoxy-4-(hydroxymethyl)benzoate
  • tert-Butyl (2R,4R)-4-((tert-butyldimethylsilyl)oxy)-2-(((ethylsulfonyl)oxy)methyl)pyrrolidine-1-carboxylate
  • N-(((9H-Fluoren-9-yl)methoxy)carbonyl)-N-isopentyl-L-cysteine