Ethyl (2Z)-chloro(hydroxyimino)acetate

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Names

[ CAS No. ]:
14337-43-0

[ Name ]:
Ethyl (2Z)-chloro(hydroxyimino)acetate

[Synonym ]:
2-Chloro-2-hydroxyiminoacetic acid ethyl ester
Acetic acid, 2-chloro-2-(hydroxyimino)-, ethyl ester, (2E)-
Ethyl chlorooximinoacetate
Acetic acid, chloro(hydroxyimino)-, ethyl ester
Acetic acid, 2-chloro-2-(hydroxyimino)-, ethyl ester, (2Z)-
Ethyl (2Z)-chloro(hydroxyimino)acetate
Ethyl (2E)-chloro(hydroxyimino)acetate
Ethylchloroximidoacetate
Ethyl (2E)-chloro(hydroxyimino)ethanoate
(Z)-ethyl 2-chloro-2-(hydroxyimino)acetate
Ethyl 2-chloro-2-(hydroxyimino)acetate
α-Chloroglyoxalic Acid Ethyl Ester Oxime
2-Chloro-2-(hydroxyimino)acetic Acid Ethyl Ester
Ethyl-(2E)-chlor(hydroxyimino)ethanoat
MFCD00010209
ethyl chloro(hydroximino)acetate

Chemical & Physical Properties

[ Density]:
1.4±0.1 g/cm3

[ Boiling Point ]:
230.5±23.0 °C at 760 mmHg

[ Melting Point ]:
70-76 °C(lit.)

[ Molecular Formula ]:
C4H6ClNO3

[ Molecular Weight ]:
151.548

[ Flash Point ]:
93.2±22.6 °C

[ Exact Mass ]:
151.003616

[ PSA ]:
58.89000

[ LogP ]:
1.52

[ Vapour Pressure ]:
0.0±1.0 mmHg at 25°C

[ Index of Refraction ]:
1.481

[ Storage condition ]:
2-8°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS05, GHS07, GHS08

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H315-H318-H334-H335

[ Precautionary Statements ]:
P261-P280-P305 + P351 + P338-P342 + P311

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Faceshields;Gloves

[ Hazard Codes ]:
Xn:Harmful;

[ Risk Phrases ]:
R37/38;R41;R42/43

[ Safety Phrases ]:
S22-S26-S36/37/39-S45

[ RIDADR ]:
UN 3335

[ WGK Germany ]:
3

[ Hazard Class ]:
6.1

[ HS Code ]:
2942000000

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • ethyl 2-(hydroxyimino)acetate
  • Ethyl glycinate
  • ethyl 2-(hydroxyimino)acetate
  • Glycine ethyl ester hydrochloride
  • SodiuM bicarbonate
  • ammonium 1-chloro-2-ethoxy-1-nitro-2-oxoethan-1-ide
  • ETHYL NITROACETATE
  • Ethyl 2-Chloroacetoacetate
  • ETHYL 2-(HYDROXYIMINO)-3-OXOBUTANOATE
  • ethyl oxycyanoformate

DownStream

  • Ethyl 3a,4,6,6a-tetrahydrofuro[3,4-d][1,2]oxazole-3-carboxylate
  • 5,6,7,8-TETRAHYDRO-4 H-CYCLOHEPTA[ D ]ISOXAZOLE-3-CARBOXYLIC ACID
  • ETHYL 5-(CHLOROMETHYL)ISOXAZOLE-3-CARBOXYLATE
  • Ethyl isoxazol-3-carboxylate
  • diethyl 1,2,5-oxadiazole-3,4-dicarboxylate 2-oxide
  • ethyl 5-phenyl-1,2,4-oxadiazole-3-carboxylate
  • 4,5,6,7-TETRAHYDRO-BENZO[D]ISOXAZOLE-3-CARBOXYLIC ACID
  • ethyl 4-((2-methoxy-5-methyl-6-oxopyrimidin-1(6H)-yl)methyl)-5-(pyrrolidin-1-yl)-4,5-dihydroisoxazole-3-carboxylate
  • 4(1H)-Pyrimidinone, 2-methoxy-5-methyl- (9CI)
  • ETHYL 5-(4-CHLOROPHENYL)ISOXAZOLE-3-CARBOXYLATE

Customs

[ HS Code ]: 2928000090

[ Summary ]:
2928000090 other organic derivatives of hydrazine or of hydroxylamine VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0%

Articles

Synthesis of enantiopure Delta2-isoxazoline derivatives and evaluation of their affinity and efficacy profiles at human beta-adrenergic receptor subtypes.

Bioorg. Med. Chem. 14(13) , 4393-401, (2006)

The new enantiomerically pure 3-substituted-Delta(2)-isoxazolin-5-yl-ethanolamines (+)-6a/(-)-6b, (-)-6a/(+)-6b, and (+)-7a/(-)-7b, prepared via a 1,3-dipolar cycloaddition-based approach, were tested...

Occupational allergic contact dermatitis from ethyl chloro oximido acetate.

Contact Dermatitis 27(4) , 277-8, (1992)

Tetrahedron Lett. 47 , 9029, (2006)


More Articles

Related Compounds

  • Acetic acid, (hydroxyimino)-, 2-(dimethylamino)ethyl ester (9CI)
  • Ethyl (2Z)-chloro(phenylhydrazono)acetate
  • Ethyl (2Z)-chloro{[4-(diethylsulfamoyl)phenyl]hydrazono}acetate
  • Ethyl (2Z)-[(3-bromophenyl)hydrazono](chloro)acetate
  • Ethyl 2-Chloro-2-(methylimino)acetate
  • Acetic acid, (hydroxyimino)(methylthio)-, ethyl ester, (2Z)- (9CI)
  • N-(1-cyanocyclohexyl)-2-(quinolin-2-ylsulfanyl)propanamide
  • 2-Amino-1-(3,4-difluorophenyl)propan-1-ol
  • 2-Cyclohexyl-1-(1,4-diazepan-1-yl)ethanone
  • (2-Ethylbutyl)[1-(pyridin-4-yl)ethyl]amine
  • 2-[4-[Cyclopropyl-(5,6-diphenylpyrazin-2-yl)amino]butoxy]acetic acid
  • N-(1-Methylethyl)-5,6-diphenyl-N-[4-(2H-tetrazol-5-ylmethoxy)butyl]-2-pyrazinamine
  • 3-[5-nitro-3-(trifluoromethyl)-1H-pyrazol-1-yl]propanoic acid
  • 2,5-Dihydroxy-7-methyl-1,4-naphthoquinone
  • [2-(4,5-dichloro-3-methyl-1H-pyrazol-1-yl)butyl]amine
  • 1-(5,6,7,8-tetrahydro[1,2,4]triazolo[4,3-a]pyridin-3-ylmethyl)-1H-pyrazole-4-carboxylic acid
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