(R)-(-)-Solketal

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Names

[ Name ]:
(R)-(-)-Solketal

[Synonym ]:
Solketal
L-α,β-Isopropylideneglycerol
R-(-)-(2,2-Dimethyl-[1,3]dioxolan-4-yl)-methanol
R-Glycerol Acetonide
[(4R)-2,2-Dimethyl-1,3-dioxolan-4-yl]methanol
2,3-Isopropylidene-sn-glycerol
(R)-(−)-2,2-Dimethyl-1,3-dioxolane-4-methanol
UNII-3XK098O8ZW
L-(-)-1,2-Isopropylideneglycerol
R-Solketal
(R)-(-)-2,3-O-Isopropylideneglycerol
R-(-)-Sollketal
(R)-(-)-1,2-O-Isopropylideneglycerol
T5O COTJ B1 B1 D1Q &&R Form
(R)-(-)-2,2-Dimethyl-1,3-dioxolae-4-methanol
(R)-(-)-2,2-Dimethyl-1,3-dioxolane-4-methanol
(R)-(2,2-dimethyl-1,3-dioxolan-4-yl)methanol
L-2,3-O-isopropylidene-sn-glycerol
MFCD00003213
1,3-Dioxolane-4-methanol, 2,2-dimethyl-, (4R)-
(R )-(-)-2,2-Dimethyl-1,3-dioxolane-4-methanol

Chemical & Physical Properties

[ Density]:
1.0±0.1 g/cm3

[ Boiling Point ]:
188.5±0.0 °C at 760 mmHg

[ Molecular Formula ]:
C₆H₁₂O₃

[ Molecular Weight ]:
132.158

[ Flash Point ]:
80.0±0.0 °C

[ Exact Mass ]:
132.078644

[ PSA ]:
38.69000

[ LogP ]:
0.06

[ Vapour Pressure ]:
0.2±0.7 mmHg at 25°C

[ Index of Refraction ]:
1.424

[ Storage condition ]:
2~8℃

[ Water Solubility ]:
miscible

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;half-mask respirator (US);multi-purpose combination respirator cartridge (US)

[ Hazard Codes ]:
Xi

[ Safety Phrases ]:
S23-S24/25

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ RTECS ]:
JI0400000

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

5,6-O-isopropylidene-L-gulonic acid γ-lactone
(S)-Methyl 2,2-dimethyl-1,3-dioxolane-4-carboxylate
Solketal
(S)-2,2-Dimethyl-1,3-dioxolane-4-carbaldehyde
(S)-(-)-(2,2-dimethyl-1,3-dioxolan-4-yl)methyl benzoate
acetic acid,[(4R)-2,2-dimethyl-1,3-dioxolan-4-yl]methanol
bis(((S)-2,2-dimethyl-1,3-dioxolan-4-yl)methyl) terephthalate
5,6-0,0-isopropylidene-L-ascorbic acid
(2,2-dimethyl-1,3-dioxolane-4-yl)methyl caproate

DownStream

2,2-dimethyl-4(s)-4-iodomethyl-1,3-dioxalane
(S)-2,2-Dimethyl-1,3-dioxolane-4-carbaldehyde
[(4S)-2,2-dimethyl-1,3-dioxolan-4-yl]methyl 4-methylbenzenesulfonate
1-O-HEXADECYL-RAC-GLYCEROL
(S)-2,2-Dimethyl-1,3-dioxolane-4-carboxylicacid
(R,E)-ETHYL 3-(2,2-DIMETHYL-1,3-DIOXOLAN-4-YL)ACRYLATE
(r)-4-benzyloxymethyl-2,2-dimethyl-1,3-dioxolane
Solketal
2,2-Dimethyl-1,3-dioxolane-4-methanamine
((R)-2,2-Dimethyl-1,3-dioxolan-4-yl)methyl p-toluenesulfonate

Articles

In vitro toxicities of experimental jet fuel system ice-inhibiting agents.

Sci. Total Environ. 274(1-3) , 209-18, (2001)

One research emphasis within the Department of Defense has been to seek the replacement of operational compounds with alternatives that pose less potential risk to human and ecological systems. Altern...

Effects of glycerol acetonide on adrenergic neurotransmission in isolated rabbit heart.

Arzneimittelforschung 42(11) , 1288-91, (1992)

In the present investigation, the solvent glycerol acetonide (GA, CAS 100-79-8) was added (110 mg/min) to the Tyrode buffer perfusing an isolated rabbit heart preloaded with 14C-noradrenaline (NA). GA...

Fourier transform near-infrared vibrational circular dichroism used for on-line monitoring the epimerization of 2,2-dimethyl-1,3-dioxolane-4-methanol: A pseudo racemization reaction.

Chirality 18(10) , 775-82, (2006)

Near-infrared (near-IR) Fourier transform vibrational circular dichroism (FT-VCD) spectroscopy has been used to monitor the epimerization of (S)-(+)-2,2-dimethyl-1,3-dioxolane-4-methanol (S-DDM). The ...

(R)-solketal butyrate
(R)-solketal octanoate
(S)-2,2-dimethyl-1,3-dioxolane-4-methanol butanoate
(S)-1,2-O-isopropylidene glycerol propionate
(R)-2-Amino-2-(3-fluoro-2-methylphenyl)ethanol hydrochloride
(R-(R*,R*))-N-(2-Hydroxy-1-(hydroxymethyl)-2-(4-nitrophenyl)ethyl)-2-o xoacetamide