4-Bromo-3-methylphenol

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Names

[ CAS No. ]:
14472-14-1

[ Name ]:
4-Bromo-3-methylphenol

[Synonym ]:
4-Bromo-m-cresol
4-Br-3-MeC6H3OH
EINECS 238-464-3
Phenol, 4-bromo-3-methyl-
azido-ClickGreen
Phenol,4-bromo-3-methyl
MFCD00079723
4-Bromo-3-methylphenol
3-methyl-4-bromophenol
4-bromo-3-methyl-phenol
4-Br-3-me-phenol
4-brom-3-methylphenol
para-bromo-meta-cresol
4-bromo-5-methyl-phenol

Chemical & Physical Properties

[ Density]:
1.6±0.1 g/cm3

[ Boiling Point ]:
247.4±20.0 °C at 760 mmHg

[ Melting Point ]:
59-61 °C(lit.)

[ Molecular Formula ]:
C7H7BrO

[ Molecular Weight ]:
187.034

[ Flash Point ]:
103.4±21.8 °C

[ Exact Mass ]:
185.968018

[ PSA ]:
20.23000

[ LogP ]:
2.95

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.591

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36-S37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ HS Code ]:
2908199090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • m-Cresol
  • dead
  • 4-Bromo-3-methyl-anisole
  • 4-Bromo-3-methylaniline
  • cyclopentanone O-(4-bromo-3-methylphenyl) oxime
  • 2-Bromo-5-hydroxybenzaldehyde
  • Chloroform
  • Bromine

DownStream

  • BENZENEPROPANOIC ACID,4-HYDROXY-2-METHYL-,METHYL ESTER
  • 1-(4-bromo-2-hydroxy-5-methylphenyl)ethanone
  • 4-Fluoro-3-methylphenol
  • acetic acid,4-bromo-3-methylphenol
  • 1-bromo-4-decoxy-2-methylbenzene
  • 4-Benzyloxy-2-methylphenylboronic acid
  • 4-Bromo-3-methyl-anisole
  • 2,4-Dibromo-5-methylanisole
  • 3-Methylanisole
  • 3-Bromo-5-methylphenol

Customs

[ HS Code ]: 2908199090

[ Summary ]:
HS: 2908199090. derivatives of polyphenols or phenol-alcohols containing only halogen substituents and their salts. VAT:17.0%. tax rebate rate:9.0%. supervision conditions:None. MFN tariff:5.5%. general tariff:30.0%

Articles

3-Methylcalix[4]arene: A New Versatile Precursor to Inherently Chiral Calix[4]arenes.

J. Org. Chem. 61(2) , 802-4, (1996)

End group-functionalization and synthesis of block-copolythiophenes by modified nickel initiators. Smeets A, et al.

Macromolecules 44(5) , 6017-25, (2011)

Influence of the Presence and Length of an Alkyl Spacer on the Supramolecular Chirality of Block Copoly (thiophene) s. Van den Bergh K, et al.

Macromolecules 44(4) , 728-35, (2011)


More Articles

Related Compounds

  • 2-Amino-4-bromo-3-methylphenol
  • acetic acid,4-bromo-3-methylphenol
  • 4-Bromo-3-methylphenol trifluoromethyl ether
  • 4-Bromo-3-fluoro-2-methylphenol
  • 4-Bromo-3-chloro-2-methylphenol
  • 4-bromo-3-(hydroxymethyl)-2-methylphenol
  • N-[(2-bromo-5-chlorophenyl)methyl]cyclobutanamine
  • 3-(5-{[Ethyl(2-methylpropyl)amino]methyl}thiophen-3-yl)prop-2-yn-1-ol
  • 1-(4-Cyclopropyl-1,3-thiazol-2-yl)ethan-1-ol
  • Tert-butyl 1-(4-chloro-2-nitrophenyl)piperidin-4-ylcarbamate
  • (S)-1-(4-Methylpyridin-2-yl)ethan-1-ol
  • 2,2-Dimethyl-3-(pentyloxy)propane-1-sulfonyl chloride
  • tert-butyl N-[3-(aminomethyl)pentan-3-yl]carbamate
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile