SnAP-TM Reagent

Suppliers

Names

[ Name ]:
SnAP-TM Reagent

[Synonym ]:
MFCD23703162
SnAP TM Reagent
2-{[(Tributylstannyl)methyl]sulfanyl}ethanamine
Ethanamine, 2-[[(tributylstannyl)methyl]thio]-

Chemical & Physical Properties

[ Boiling Point ]:
383.3±52.0 °C at 760 mmHg

[ Molecular Formula ]:
C₁₅H₃₅NSSn

[ Molecular Weight ]:
380.220

[ Flash Point ]:
185.6±30.7 °C

[ Exact Mass ]:
381.151215

[ LogP ]:
8.53

[ Vapour Pressure ]:
0.0±0.9 mmHg at 25°C

Safety Information

[ Symbol ]:

GHS06, GHS09

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H301 + H311 + H331-H315-H319-H335-H410

[ Precautionary Statements ]:
Missing Phrase - N15.00950417-P261-P280-P302 + P352 + P312-P304 + P340 + P312-P403 + P233

[ RIDADR ]:
UN 2788 6.1 / PGIII

Articles

SnAP reagents for the transformation of aldehydes into substituted thiomorpholines--an alternative to cross-coupling with saturated heterocycles.

Angew. Chem. Int. Ed. Engl. 52(6) , 1705-8, (2013)

SnAP reagents for the one-step synthesis of medium-ring saturated N-heterocycles from aldehydes.

Nature Chemistry 6(4) , 310-4, (2014)

Interest in saturated N-heterocycles as scaffolds for the synthesis of bioactive molecules is increasing. Reliable and predictable synthetic methods for the preparation of these compounds, especially ...

SnAP Reagents for a Cross-Coupling Approach to the One-Step Synthesis of Saturated N-Heterocycles. Luescher MU, et al.

Aldrichimica Acta 48(2) , 43-48, (2015)