PENTAFLUOROPHENYL TRIFLUOROACETATE

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Names

[ CAS No. ]:
14533-84-7

[ Name ]:
PENTAFLUOROPHENYL TRIFLUOROACETATE

[Synonym ]:
Trifluoroacetic acid pentafluorophenyl ester
Perfluorophenyl 2,2,2-trifluoroacetate
Pentafluorphenyl trifluoracetate
MFCD00134438
EINECS 212-235-8
(2,3,4,5,6-pentafluorophenyl) 2,2,2-trifluoroacetate
Pentafluorophenyl Trifluoroacetate

Chemical & Physical Properties

[ Density]:
1.63 g/mL at 25 °C(lit.)

[ Boiling Point ]:
122-123 °C(lit.)

[ Melting Point ]:
4°C(lit.)

[ Molecular Formula ]:
C8F8O2

[ Molecular Weight ]:
280.07200

[ Flash Point ]:
126 °F

[ Exact Mass ]:
279.97700

[ PSA ]:
26.30000

[ LogP ]:
2.84980

[ Index of Refraction ]:
n20/D 1.368(lit.)

[ Storage condition ]:
Store at RT.

MSDS

Safety Information

[ Symbol ]:

GHS02, GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H226-H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi: Irritant;F: Flammable;

[ Risk Phrases ]:
R10;R36/37/38

[ Safety Phrases ]:
S16-S26-S36

[ RIDADR ]:
UN 3272 3/PG 3

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
3.2

[ HS Code ]:
2915900090

Synthetic Route

Precursor & DownStream

Precursor

  • Pentafluorophenol
  • Trifluoroacetic anhydride
  • Trifluoroacetyl chloride

DownStream

  • Fmoc-Phe-OPfp
  • Fmoc-Tyr(tBu)-OPfp
  • Fmoc-Lys(Boc)-OPfp
  • Fmoc-Trp-OPfp
  • Fmoc-Ile-OPfp
  • Fmoc-Asp(OtBu)-Opfp
  • (2,3,4,5,6-pentafluorophenyl) hexadecanoate
  • Fmoc-Cys(Trt)-OPfp
  • bis(2,3,4,5,6-pentafluorophenyl) benzene-1,4-dicarboxylate
  • Biotin-PFP ester

Customs

[ HS Code ]: 2915900090

[ Summary ]:
2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%

Articles

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ACS Chem. Biol. 10 , 1778-84, (2015)

ADP-ribosylation is essential for cell function, yet there is a dearth of methods for detecting this post-translational modification in cells. Here, we describe a clickable aminooxy alkyne (AO-alkyne)...


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Related Compounds

  • pentafluorophenyl nitrene
  • (pentafluorophenyl)N(SiMe3)2
  • PENTAFLUOROPHENYL 3-FLUORO-BENZENESULFONATE
  • pentafluorophenyl 5-ethyl-2-oxo-1,3-dioxane-5-carboxylate
  • Fmoc-β-Ala-OPfp
  • (pentafluorophenyl)germatrane