Diacetatobis(triphenylphosphine) palladium(II)

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Names

[ Name ]:
Diacetatobis(triphenylphosphine) palladium(II)

[Synonym ]:
Pd(OAc)2(PPh3)2
bis(acetato-κO)palladium - triphenylphosphane (1:2)
Palladium(II)bis(triphenylphosphine) diacetate
MFCD00010013
Palladium, bis(acetato-κO)-, compd. with triphenylphosphine (1:2)
Bis(triphenylphosphine)palladium(II) acetate
EINECS 238-628-4
Bis(acetato-κO)palladium - triphenylphosphine (1:2)
Phosphine, triphenyl-, compd. with acetic acid, palladium(2+) salt (2:2:1)
Diacetatobis(triphenylphosphine) palladium(II)
Palladium(2+) acetate triphenylphosphine (1:2:2)
Diacetatobis(triphenylphosphine)palladium(II)
Bis(acetato)bis(triphenylphosphine)palladium(II)
Bis(triphenylphosphinepalladium) acetate
Bis(triphenylphosphine)palladium(II) Diacetate
Bis(triphenylphosphinepalladium)acetate

Chemical & Physical Properties

[ Boiling Point ]:
360ºC at 760 mmHg

[ Melting Point ]:
136ºC

[ Molecular Formula ]:
C₄₀H₃₆O₄P₂Pd

[ Molecular Weight ]:
749.079

[ Flash Point ]:
181.7ºC

[ Exact Mass ]:
748.112366

[ PSA ]:
79.78000

[ LogP ]:
6.91720

[ Vapour Pressure ]:
4.74E-05mmHg at 25°C

[ Storage condition ]:
−20°C

[ Stability ]:
store cold

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ Hazard Codes ]:
Xn

[ Safety Phrases ]:
S24/25

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

Articles

Palladium(II) Acetate-Tris(triphenylphosphine)rhodium(I) Chloride: A Novel Catalytic Couple for the Intramolecular Heck Reaction.

J. Org. Chem. 64 , 3461, (1999)

A series of crotyl ethers underwent intramolecular cyclizations in the presence of a novel catalytic couple, composed of tris(triphenylphosphine)rhodium(I) chloride and palladium(II) acetate, under He...

Formal total synthesis of oximidine II via a Suzuki-type cross-coupling macrocyclization employing potassium organotrifluoroborates.

J. Am. Chem. Soc. 126 , 10313, (2004)

A formal total synthesis of oximidine II has been achieved, employing a Suzuki-type coupling approach to construct the highly strained, polyunsaturated 12-membered macrolactone. To achieve this goal, ...

Yus, M.; Gomis, J.

Tetrahedron Lett. 42 , 5721, (2001)

benzylbis(triphenylphosphine)palladium(ii) chloride
benzoylchlorobis(triphenylphosphine)palladium(II)
tris(triphenylphosphine)-palladium(II) dichloride
Bis(triphenylphosphine) Palladium (II) Chloride
TRANS-DIBROMOBIS(TRIPHENYLPHOSPHINE)PALLADIUM(II)
2-[BIS(TRIPHENYLPHOSPHINE)PALLADIUM(II)BROMIDE]BENZYL ALCOHOL
2-Methoxy-3-methyl-5-(piperidin-4-yloxy)pyridine
1-[2-methyl-4-(1H-1,2,3,4-tetrazol-1-yl)butan-2-yl]cyclopropan-1-amine
1-(6-chloro-1-methyl-1H-indol-3-yl)-2,2-difluorocyclopropan-1-amine
1,1-Difluoro-2-{4-[(trifluoromethyl)sulfanyl]phenyl}propan-2-amine
(3R,5S)-3,5-dimethyl-1-(2-nitrobenzenesulfonyl)piperazine
3-[(azetidin-3-yl)methyl]-1-(2-methylpropyl)-1H-pyrazole
2-[1-(Oxan-2-yl)cyclopropyl]propan-2-amine
2-(2-Methoxy-6-methylpyridin-4-yl)morpholine
[1-(3-Bromoprop-1-en-2-yl)cyclopropyl]benzene
tert-butyl 4-[(4R)-4-hydroxypentyl]piperazine-1-carboxylate

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