Diacetatobis(triphenylphosphine) palladium(II)
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Names
[ CAS No. ]:
14588-08-0
[ Name ]:
Diacetatobis(triphenylphosphine) palladium(II)
[Synonym ]:
Pd(OAc)2(PPh3)2
bis(acetato-κO)palladium - triphenylphosphane (1:2)
Palladium(II)bis(triphenylphosphine) diacetate
MFCD00010013
Palladium, bis(acetato-κO)-, compd. with triphenylphosphine (1:2)
Bis(triphenylphosphine)palladium(II) acetate
EINECS 238-628-4
Bis(acetato-κO)palladium - triphenylphosphine (1:2)
Phosphine, triphenyl-, compd. with acetic acid, palladium(2+) salt (2:2:1)
Diacetatobis(triphenylphosphine) palladium(II)
Palladium(2+) acetate triphenylphosphine (1:2:2)
Diacetatobis(triphenylphosphine)palladium(II)
Bis(acetato)bis(triphenylphosphine)palladium(II)
Bis(triphenylphosphinepalladium) acetate
Bis(triphenylphosphine)palladium(II) Diacetate
Bis(triphenylphosphinepalladium)acetate
Chemical & Physical Properties
[ Boiling Point ]:
360ºC at 760 mmHg
[ Melting Point ]:
136ºC
[ Molecular Formula ]:
C40H36O4P2Pd
[ Molecular Weight ]:
749.079
[ Flash Point ]:
181.7ºC
[ Exact Mass ]:
748.112366
[ PSA ]:
79.78000
[ LogP ]:
6.91720
[ Vapour Pressure ]:
4.74E-05mmHg at 25°C
[ Storage condition ]:
−20°C
[ Stability ]:
store cold
MSDS
Safety Information
[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter
[ Hazard Codes ]:
Xn
[ Safety Phrases ]:
S24/25
[ RIDADR ]:
NONH for all modes of transport
[ WGK Germany ]:
3
Articles
J. Org. Chem. 64 , 3461, (1999)
A series of crotyl ethers underwent intramolecular cyclizations in the presence of a novel catalytic couple, composed of tris(triphenylphosphine)rhodium(I) chloride and palladium(II) acetate, under He...
J. Am. Chem. Soc. 126 , 10313, (2004)
A formal total synthesis of oximidine II has been achieved, employing a Suzuki-type coupling approach to construct the highly strained, polyunsaturated 12-membered macrolactone. To achieve this goal, ...
Yus, M.; Gomis, J.Tetrahedron Lett. 42 , 5721, (2001)