(R)-(-)-Benzyl glycidyl ether

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Names

[ Name ]:
(R)-(-)-Benzyl glycidyl ether

[Synonym ]:
Benzyl (R)-(-)-Glycidyl Ether
(2R)-2-(phenylmethoxymethyl)oxirane
(R)-(-)-1-Benzyloxy-2,3-epoxypropane
Oxirane, 2-[(phenylmethoxy)methyl]-, (2R)-
Benzyl R-(-)-glycidyl ether
(2R)-2-[(Benzyloxy)methyl]oxirane
MFCD00068409
(R)-(-)-Benzyl Glycidyl Ether
(R)-(-)-2-(Benzyloxymethyl)oxirane
(R)-1-(Benzyloxy)-2,3-epoxypropane
(r)-benzyloxymethyl-oxirane
(R)-2-((Benzyloxy)methyl)oxirane
( R)-(-)-2-(benzyloxymethyl)-oxirane
Z-DL-Gln-OH

Chemical & Physical Properties

[ Density]:
1.077

[ Boiling Point ]:
130 ºC (0.1 mmHg)

[ Molecular Formula ]:
C₁₀H₁₂O₂

[ Molecular Weight ]:
164.201

[ Flash Point ]:
100.9±19.9 °C

[ Exact Mass ]:
164.083725

[ PSA ]:
21.76000

[ LogP ]:
2.04

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.517

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: TX2860030

CHEMICAL NAME :: Propane, 1-(benzyloxy)-2,3-epoxy-, (S)-

CAS REGISTRY NUMBER :: 14618-80-5

BEILSTEIN REFERENCE NO. :: 3588399

LAST UPDATED :: 199612

DATA ITEMS CITED :: 4

MOLECULAR FORMULA :: C10-H12-O2

MOLECULAR WEIGHT :: 164.22

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: Mutation test systems - not otherwise specified

TYPE OF TEST :: Cytogenetic analysis

MUTATION DATA

TEST SYSTEM :: Rodent - mouse

DOSE/DURATION :: 100 mg/kg

REFERENCE :: MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 298,197,1993

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36-S37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ RTECS ]:
TX2860020

[ HS Code ]:
2910900090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

2-((Benzyloxy)methyl)oxirane
(R)-(+)-3-Benzyloxy-1,2-propanediol
(S)-(+)-1-Benzyloxy-3-(p-tosyloxy)-2-propanol
Benzyl bromide
(±)-Glycidol
1-benzyloxy-3-iodo-propan-2-ol
[(Allyloxy)methyl]benzene
(S)-(-)-3-Benzyloxy-1,2-propanediol
(1-chloro-2-methyl-1-oxobutan-2-yl) acetate

DownStream

(S)-1-(benzylamino)-3-(benzyloxy)propan-2-ol
(S)-4-benzyl-2-((benzyloxy)methyl)morpholine
(R)-(-)-Solketal
(2R)-1-phenylmethoxybutan-2-ol
(R)-2-(Benzyloxymethyl)oxetane

Customs

[ HS Code ]: 2910900090

[ Summary ]:
2910900090. epoxides, epoxyalcohols, epoxyphenols and epoxyethers, with a three-membered ring, and their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

Articles

Synthesis , 539, (1989)

J. Org. Chem. 53 , 4495, (1988)

J. Chem. Soc. Chem. Commun. , 291, (1993)

Benzyl Glycidyl Ether
2-((Benzyloxy)methyl)oxirane
3-methyl-phenyl (R)-glycidyl ether
(R)-Benzyl linalyl ether
(R)-glycidyl 4-aminophenyl ether
(R)-(+)-Hexyl glycidyl ether
3,4-Dichloro-5-(1H-indol-3-yl)furan-2(5H)-one
5-Methyl-3-(o-isothiocyanatobenzyl)-1,2,4-triazole
Acetamide, 2-[[5-[(2,6-dimethylphenoxy)methyl]-4-(2-propen-1-yl)-4H-1,2,4-triazol-3-yl]thio]-N-[4-(2-phenyldiazenyl)phenyl]-
2-Ethyl-1,4-difluorobenzene
ethyl 5-(hydroxymethyl)-2-methyl-1H-pyrrole-3-carboxylate
2-amino-N-ethyl-5-nitrobenzamide
2-Ethylcyclopentane-1-thiol
4-(2-Dimethylamino-2-methylpropoxy)benzaldehyde
Diethylmethylidene malonate
Ethyl 2-phenylquinazoline-4-carboxylate

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