(-)-TRANS-2-TERT-BUTYLCYCLOHEXANOL

Suppliers

Names

[ CAS No. ]:
14645-24-0

[ Name ]:
(-)-TRANS-2-TERT-BUTYLCYCLOHEXANOL

[Synonym ]:
Troeger base

Chemical & Physical Properties

[ Density]:
1.21g/cm3

[ Boiling Point ]:
461ºC at 760mmHg

[ Melting Point ]:
127-131ºC

[ Molecular Formula ]:
C17H18N2

[ Molecular Weight ]:
250.33800

[ Flash Point ]:
213.5ºC

[ Exact Mass ]:
250.14700

[ PSA ]:
6.48000

[ LogP ]:
3.73110

[ Vapour Pressure ]:
1.11E-08mmHg at 25°C

[ Index of Refraction ]:
1.685

MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Faceshields;Gloves

[ Hazard Codes ]:
Xn: Harmful;N: Dangerous for the environment;

[ Risk Phrases ]:
22-50/53

[ Safety Phrases ]:
26-60-61

[ RIDADR ]:
UN 2811 6.1/PG 3

[ WGK Germany ]:
3

Synthetic Route

Precursor & DownStream

Precursor

  • 6H,12H-5,11-Methanodibenzo[b,f][1,5]diazocine,2,8-dimethyl-

DownStream

Articles

The covalently bonded cellulose tris(3,5-dimethylphenylcarbamate) on a silica monolithic capillary column for enantioseparation in capillary electrochromatography.

J. Chromatogr. B. Analyt. Technol. Biomed. Life Sci. 875(1) , 317-22, (2008)

A chiral capillary monolithic column for capillary electrochromatography (CEC) was prepared by covalent bonding of cellulose tris(3,5-dimethylphenylcarbamate) (CDMPC) on the silica monolithic matrix w...

Resolution, asymmetric transformation, and configuration of Tröger's base. Application of Tröger's base as a chiral solvating agent. Wilen, Samuel H., Jian Zhong Qi, and Paul G. Williard

Organic Chemistry 56 , 485-487, (1991)


More Articles


Related Compounds

  • (-)-trans-2-tert-butylcyclohexanol
  • trans-2-tert-butoxycarbonylamino-cyclopent-3-enecarboxylic acid methyl ester
  • trans-2-{[(tert-butoxy)carbonyl]amino}cyclobutane-1-carboxylic acid
  • TRANS-2-((TERT-BUTOXYCARBONYL)AMINO)CYCLOHEXANECARBOXYLIC ACID
  • cis-4-tert-butyl-trans-2-methylcyclohexanol
  • (+/-)-TRANS-2-BUTYLCYCLOHEXANOL
  • 2-(1-Ethynylcyclopropoxy)tetrahydro-2h-pyran
  • Isopropyl 6-bromoquinoline-2-carboxylate
  • N-[2-Methyl-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]-2-propenamide
  • N-(2-(4-methylpiperazin-1-yl)-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl) acrylamide
  • 1-(Cyclopropylcarbonyl)-5-oxoproline
  • 4-(3-Methylthiophen-2-yl)oxane-4-carboxylic acid
  • S-[(trans-4-Aminocyclohexyl)methyl]ethanethioate trifluoroacetate
  • (1R,2S)-2-(4-chlorophenyl)-1-methylcyclopropane-1-carboxylic acid
  • Triethylamine 2-((adamantane-1-carbonyl)oxy)-1,1-difluoroethane-1-sulfonate
  • 7-(aminomethyl)-1H-pyrido[2,3-b][1,4]oxazin-2(3H)-one dihydrochloride
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