(-)-TRANS-2-TERT-BUTYLCYCLOHEXANOL

Names

[ CAS No. ]:
14645-24-0

[ Name ]:
(-)-TRANS-2-TERT-BUTYLCYCLOHEXANOL

[Synonym ]:
Troeger base

Chemical & Physical Properties

[ Density]:
1.21g/cm3

[ Boiling Point ]:
461ºC at 760mmHg

[ Melting Point ]:
127-131ºC

[ Molecular Formula ]:
C₁₇H₁₈N₂

[ Molecular Weight ]:
250.33800

[ Flash Point ]:
213.5ºC

[ Exact Mass ]:
250.14700

[ PSA ]:
6.48000

[ LogP ]:
3.73110

[ Vapour Pressure ]:
1.11E-08mmHg at 25°C

[ Index of Refraction ]:
1.685

MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Faceshields;Gloves

[ Hazard Codes ]:
Xn: Harmful;N: Dangerous for the environment;

[ Risk Phrases ]:
22-50/53

[ Safety Phrases ]:
26-60-61

[ RIDADR ]:
UN 2811 6.1/PG 3

[ WGK Germany ]:
3

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Articles

The covalently bonded cellulose tris(3,5-dimethylphenylcarbamate) on a silica monolithic capillary column for enantioseparation in capillary electrochromatography.

J. Chromatogr. B. Analyt. Technol. Biomed. Life Sci. 875(1) , 317-22, (2008)

A chiral capillary monolithic column for capillary electrochromatography (CEC) was prepared by covalent bonding of cellulose tris(3,5-dimethylphenylcarbamate) (CDMPC) on the silica monolithic matrix w...

Resolution, asymmetric transformation, and configuration of Tröger's base. Application of Tröger's base as a chiral solvating agent. Wilen, Samuel H., Jian Zhong Qi, and Paul G. Williard

Organic Chemistry 56 , 485-487, (1991)

(-)-trans-2-tert-butylcyclohexanol
trans-2-tert-butoxycarbonylamino-cyclopent-3-enecarboxylic acid methyl ester
trans-2-{[(tert-butoxy)carbonyl]amino}cyclobutane-1-carboxylic acid
TRANS-2-((TERT-BUTOXYCARBONYL)AMINO)CYCLOHEXANECARBOXYLIC ACID
cis-4-tert-butyl-trans-2-methylcyclohexanol
(+/-)-TRANS-2-BUTYLCYCLOHEXANOL
Methyl 6-(chlorosulfonyl)-4-iodopyridine-2-carboxylate
4-Hydroxy solifenacin, (4R)-
4'-Hydroxy Torsemide-d7
2-(2,6-Dichlorophenyl)-2-(methylamino)acetic acid hydrochloride
N-(4-tert-butyl-1,3-thiazol-2-yl)-2-(4-oxo-1H-phthalazin-1-yl)acetamide
4-(2-Aminoethyl)pyrrolidine-2-carboxylic acid
Methyl 3-amino-2-methyl-2-phenylpropanoate hydrochloride
Methyl 4-[(6-cyanopyridin-3-yl)oxy]benzoate
(1S,2R)-2-Phenylcyclopropanamine, (2S,3S)-2,3-dihydroxybutanedioate
(2S)-2,3-Dimethylbut-3-en-1-ol

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