Wilkinson's catalyst

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Names

[ CAS No. ]:
14694-95-2

[ Name ]:
Wilkinson's catalyst

[Synonym ]:
Chlororhodium - triphenylphosphine (1:3)
Tris(triphenylphosphine)chlororhodium
Chlorotris(triphenyl
MFCD00010016
Rh(PPh3)3Cl
Chlorotris(triphenylphosphine)rhodium(I)
Tris(triphenylphosphine)rhodium(I) Chloride
rhodium,triphenylphosphane,chloride
EINECS 238-744-5
RhCl(PPh3)3
Rhodium(I) tris(triphenylphosphine) chloride
Tris(triphenylphosphine)chloro rhodium

Chemical & Physical Properties

[ Boiling Point ]:
>170°C

[ Melting Point ]:
245-250 °C (dec.)

[ Molecular Formula ]:
C54H45ClP3Rh

[ Molecular Weight ]:
925.215

[ Flash Point ]:
181.7ºC

[ Exact Mass ]:
924.147766

[ PSA ]:
40.77000

[ LogP ]:
11.02390

[ Storage condition ]:
2-8°C

[ Water Solubility ]:
insoluble

MSDS

Click to get detail MSDS

Safety Information

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/38

[ Safety Phrases ]:
S22-S24/25-S37/39-S28A-S26-S15

[ WGK Germany ]:
1

[ Packaging Group ]:
I; II; III

[ HS Code ]:
2942000000

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • trans-Carbonylchlorobis-(triphenylphosphino)-rhodium
  • (1,5-Cyclooctadiene)rhodium chloride dimer
  • cis-[(Ph3P)Rh(Ph)(Ph2PF)]*Et2O
  • Triphenylphosphine
  • Ethene, rhodium(1+) salt, hydrochloride (2:1:1)
  • 2-Butine-1,4-diol

DownStream

  • carbon monoxide; rhodium; triphenylphosphane
  • D-glucopyranose
  • D-Mannitol
  • Sorbitol
  • d-mannono-1,4-lactone
  • D-mannopyranose
  • D-arabinitol
  • 1,3-Dihydroxyacetone
  • Glycerol
  • D-glucono-1,4-lactone

Customs

[ HS Code ]: 2942000000

Related Compounds

  • Wilkinson's catalyst
  • Grubbs Catalyst 2nd Generation
  • Karstedt's catalyst
  • (-)-Dichloro[(4S)-4-(i-propyl)-2-{(S)-2-(diphenylphosphino)ferrocenyl}oxazoline](triphenylphosphine)ruthenium(II)
  • (+)-Dichloro[(4R)-4-(i-propyl)-2-{(R)-2-(diphenylphosphino)ferrocenyl}oxazoline](triphenylphosphine)ruthenium(II)
  • Grela catalyst