C.I. Pigment Blue 15

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Names

[ CAS No. ]:
147-14-8

[ Name ]:
C.I. Pigment Blue 15

[Synonym ]:
29H,31H-Phthalocyanine, copper(2+) salt (1:1)
C.I. Pigment Blue 15
Copper phthalocyanine
Copper(II) Phthalocyanine (α-form)
Phthalocyanine Copper
CuPc,Phthalocyanine blue,Pigment Blue 15
Pigment Blue 15
Copper(2+) phthalocyanine-29,31-diide
Copper, [29H,31H-phthalocyaninato(2-)-κN29,κN30,κN31,κN32]-, (SP-4-1)-
phthalocyanine blue
(SP-4-1)-[29H,31H-Phthalocyaninato(2-)-N29,N30,N31,N32]copper
[29H,31H-phthalocyaninato(2-)-κ2N29,N31]copper
Copper(II) Phthalocyanine (β-forM)
MFCD00010719
EINECS 205-685-1
Copper(II) phthalocyanine
Phthalocyanine Copper(II) (α-form)

Chemical & Physical Properties

[ Melting Point ]:
600°C (dec.)

[ Molecular Formula ]:
C32H16CuN8

[ Molecular Weight ]:
576.069

[ Exact Mass ]:
575.079407

[ PSA ]:
84.02000

[ LogP ]:
1.46190

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
GL8510000
CHEMICAL NAME :
Copper, (phthalocyaninato(2-))-
CAS REGISTRY NUMBER :
147-14-8
LAST UPDATED :
199710
DATA ITEMS CITED :
7
MOLECULAR FORMULA :
C32-H16-Cu-N8

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD - Lethal dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
>15 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 50(1),92,1985
TYPE OF TEST :
LD - Lethal dose
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
>3 gm/kg
TOXIC EFFECTS :
Kidney, Ureter, Bladder - urine volume decreased Kidney, Ureter, Bladder - proteinuria
REFERENCE :
GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 50(1),92,1985 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - M0910 No. of Facilities: 17055 (estimated) No. of Industries: 146 No. of Occupations: 95 No. of Employees: 189292 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - T1720 No. of Facilities: 8155 (estimated) No. of Industries: 54 No. of Occupations: 47 No. of Employees: 104851 (estimated) No. of Female Employees: 25691 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - T1887 No. of Facilities: 19835 (estimated) No. of Industries: 163 No. of Occupations: 114 No. of Employees: 367455 (estimated) No. of Female Employees: 112817 (estimated)

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ Hazard Codes ]:
Xi,Xn

[ Risk Phrases ]:
R36/37/38:Irritating to eyes, respiratory system and skin . R48:Danger of serious damage to health by prolonged exposure. R41:Risk of serious damage to eyes. R37/38:Irritating to respiratory system and skin . R20/21/22:Harmful by inhalation, in contact wit

[ Safety Phrases ]:
22-24/25

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
-

[ RTECS ]:
GL8510000

[ HS Code ]:
3204170000

Synthetic Route

Precursor & DownStream

Precursor

  • Phthalonitrile
  • Cupric bromide
  • bis(1,2-dicyanophenyl)sulfide
  • Hexamethyldisilazane
  • 5-(1,3-dioxoisoindole-5-carbonyl)isoindole-1,3-dione
  • copper bromide
  • Copper(I) iodide
  • Cupric hydroxide

DownStream

  • [1,2,3,4,8,9,10,11,15,16,17,18,22,23,24,25-hexadecachloro-29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]copper

Customs

[ HS Code ]: 3204170000

Articles

Forming End-to-End Oligomers of Gold Nanorods Using Porphyrins and Phthalocyanines.

Langmuir 31 , 6902-8, (2015)

The illumination of aggregated metal nanospecies can create strong local electric fields to brighten Raman scattering. This study describes a procedure to self-assemble gold nanorods (NRs) through the...

Spin-based diagnostic of nanostructure in copper phthalocyanine-C60 solar cell blends.

ACS Nano 6(12) , 10808-15, (2012)

Nanostructure and molecular orientation play a crucial role in determining the functionality of organic thin films. In practical devices, such as organic solar cells consisting of donor-acceptor mixtu...

Contrast and efficiency enhancement in organic light-emitting devices utilizing high absorption and high charge mobility organic layers.

Opt. Express 14 , 7954 - 7959, (2006)

Organic light-emitting devices utilizing copper phthalocyanine (CuPc) and C(60) as the hole- and electron-injection layers were reported. Compared with a conventional device without CuPc and C(60) lay...


More Articles


Related Compounds

  • C.I. Pigment Blue 36
  • C.I. Pigment Blue 74
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  • C.I. Pigment Blue 72
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  • (2s,3r)-3-Amino-1,7,7-trimethylbicyclo[2.2.1]heptan-2-ol
  • 4-Chloro-N-[2-[[tris(1-methylethyl)silyl]oxy]ethyl]-2-pyridinecarboxamide
  • 3-methyl-N-(thiophen-3-ylmethyl)aniline
  • 2-Methoxy-6-{[(3-methylphenyl)amino]methyl}phenol
  • 1-(2-Methoxyphenyl)prop-2-EN-1-amine
  • [4-(2-Methoxyphenyl)piperazin-1-yl][2-(pyridin-3-yl)quinolin-4-yl]methanone
  • 1-(3-Amino-5-bromo-2-methoxy-phenyl)-ethanone
  • 3-(1-Aminoprop-2-EN-1-YL)phenol
  • 2,3-Dimethyl-1-[3-(morpholin-4-yl)propyl]-1,5,6,7,8,9-hexahydrocyclohepta[b]pyrrolo[3,2-e]pyridin-4-amine
  • 2-{[(5-Chloro-2-methylphenyl)amino]methyl}-6-ethoxyphenol
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