(S)-VAPOL
Suppliers
Names
[ CAS No. ]:
147702-15-6
[ Name ]:
(S)-VAPOL
[Synonym ]:
[3,3'-Biphenanthrene]-4,4'-diol, 2,2'-diphenyl-, compd. with dichloromethane (1:1)
2,2'-Diphenyl-3,3'-biphenanthrene-4,4'-diol - dichloromethane (1:1)
Chemical & Physical Properties
[ Density]:
1.287 g/cm3
[ Boiling Point ]:
712.173ºC at 760 mmHg
[ Melting Point ]:
185-191ºC
[ Molecular Formula ]:
C41H28Cl2O2
[ Molecular Weight ]:
623.566
[ Flash Point ]:
298.408ºC
[ Exact Mass ]:
622.146606
[ PSA ]:
40.46000
[ LogP ]:
12.13310
MSDS
Safety Information
[ Symbol ]:
GHS08
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H351
[ Precautionary Statements ]:
P281
[ Hazard Codes ]:
Xn
[ Risk Phrases ]:
37/38-40-41
[ Safety Phrases ]:
26-36/37/39-36/37-24/25-23
[ RIDADR ]:
NONH for all modes of transport
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Articles
Org. Lett. 7 , 367, (2005)
[reaction: see text] In an effort to develop a synthesis of the VAPOL ligand that avoids the use of a chromium carbene complex, a route was examined that involved the annulation of a naphthalene carbo...
Org. Lett. 5 , 1813, (2003)
[reaction: see text] A copper-mediated deracemization of the vaulted biaryl ligands VANOL and VAPOL can be readily achieved in the presence of (-)-spartiene. The optimal procedure involves the in situ...
Bao. J. et al.J. Am. Chem. Soc. 118 , 3392, (1996)