4-Bromo-1-methoxy-2-methylbenzene

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Names

[ CAS No. ]:
14804-31-0

[ Name ]:
4-Bromo-1-methoxy-2-methylbenzene

[Synonym ]:
4-Bromo-2-methylanisole
5-BroMo-2-Methoxytoluene
MFCD01321139
4-Bromo-1-methoxy-2-methylbenzene
4-Bromo-2-methylphenyl methyl ether
Benzene, 4-bromo-1-methoxy-2-methyl-

Chemical & Physical Properties

[ Density]:
1.4±0.1 g/cm3

[ Boiling Point ]:
226.1±20.0 °C at 760 mmHg

[ Melting Point ]:
66-69 °C(lit.)

[ Molecular Formula ]:
C8H9BrO

[ Molecular Weight ]:
201.061

[ Flash Point ]:
102.3±7.8 °C

[ Exact Mass ]:
199.983673

[ PSA ]:
9.23000

[ LogP ]:
3.63

[ Vapour Pressure ]:
0.1±0.4 mmHg at 25°C

[ Index of Refraction ]:
1.535

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ Hazard Codes ]:
Xi: Irritant;

[ Safety Phrases ]:
S24/25

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2909309090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 2-Methylanisole
  • 2,4-Dibromoanisole
  • methyl iodide
  • 4-Bromo-o-cresol
  • Dimethyl sulfate
  • 4-bromo-2-(chloromethyl)-1-methoxybenzene
  • 4-Bromoanisole
  • ETHYLMAGNESIUM BROMIDE
  • 6-methoxy-toluene-3-sulfonic acid
  • Bromine

DownStream

  • 5-Bromo-2-hydroxybenzonitrile
  • 4-Methoxy-3-methylbenzaldehyde
  • 5-Bromo-2-anisaldehyde
  • 4-Methoxy-3-methylphenylacetonitrile
  • 2-Methylanisole
  • 4-Bromo-o-cresol
  • 4-Methoxy-3-methylbenzyl alcohol
  • 5-bromo-2-hydroxy-3-methylbenzaldehyde
  • 5-Bromo-2-methoxybenzonitrile
  • 4-Methoxy-3-methylbenzoic acid

Customs

[ HS Code ]: 2909309090

[ Summary ]:
2909309090 other aromatic ethers and their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Articles

A useful Pd-catalyzed Negishi coupling approach to benzylic sulfonamide derivatives.

Org. Lett. 10(12) , 2517-20, (2008)

A mild catalytic system to access diversely functionalized benzylic sulfonamides has been developed. Palladium-catalyzed alpha-arylation by Negishi cross-coupling of sulfonamide-stabilized anions and ...

Synthesis of aromatic bisabolene natural products via palladium-catalyzed cross-couplings of organozinc reagents.

J. Org. Chem. 69(7) , 2461-8, (2004)

Aromatic bisabolene derivatives were prepared by two methods involving cross-coupling of organozinc reagents. The first synthesis of (+/-)-glandulone A (10), as well as syntheses of (+/-)-curcuhydroqu...

Total synthesis of (±)-heliannuol D, an allelochemical from Helianthus annuus. Vyvyan JR and Looper RE.

Tetrahedron Lett. 41(8) , 1151-1154, (2000)


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