2-chloro-4,4,5,5-tetramethyl-1,3,2-dioxaphospholane

Suppliers

Names

[ CAS No. ]:
14812-59-0

[ Name ]:
2-chloro-4,4,5,5-tetramethyl-1,3,2-dioxaphospholane

[Synonym ]:
MFCD00274239
2-chloro-4,4,5,5-tetramethyldioxaphospholane
pinacol chlorophosphite

Chemical & Physical Properties

[ Density]:
1.149 g/mL at 25ºC(lit.)

[ Boiling Point ]:
81.5-82ºC13 mm Hg(lit.)

[ Molecular Formula ]:
C6H12ClO2P

[ Molecular Weight ]:
182.58500

[ Flash Point ]:
>230 °F

[ Exact Mass ]:
182.02600

[ PSA ]:
32.05000

[ LogP ]:
3.05610

[ Vapour Pressure ]:
2.57mmHg at 25°C

[ Index of Refraction ]:
n20/D 1.471(lit.)

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314

[ Supplemental HS ]:
Reacts violently with water.

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
C: Corrosive;

[ Risk Phrases ]:
14-34

[ Safety Phrases ]:
22-26-27-36/37/39-45

[ RIDADR ]:
UN 3265 8/PG 2

[ WGK Germany ]:
3

[ Hazard Class ]:
8.0

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Pinacol

DownStream

  • 4,4,5,5-TETRAMETHYL-1,3,2-DIOXAPHOSPHOLAN-2-OL
  • 4,4,5,5-tetramethyl-2-phenoxy-1,3,2-dioxaphospholane
  • 2-METHOXY-4,4,5,5-TETRAMETHYL-[1,3,2]-DIOXAPHOSPHOLANE
  • 2-ISOCYANATO-4,4,5,5-TETRAMETHYL-[1,3,2]-DIOXAPHOSPHOLANE
  • 1,3,2-Dioxaphospholane,2-ethoxy-4,4,5,5-tetramethyl-

Articles

Lignin Modification for Biopolymer/Conjugated Polymer Hybrids as Renewable Energy Storage Materials.

ChemSusChem 8 , 4081-5, (2015)

Lignin derivatives, which arise as waste products from the pulp and paper industry and are mainly used for heating, can be used as charge storage materials. The charge storage function is a result of ...

Characterization and Physicochemical Properties of Condensed Tannins from Acacia catechu.

J. Agric. Food Chem. 64 , 1751-60, (2016)

Condensed tannins from Acacia catechu were carefully studied to determine their chemical structure and physicochemical properties. The combined use of MALDI-TOF-MS and (13)C NMR revealed that catechin...

Synthesis of complex carbohydrates and glycoconjugates: enzyme-based and programmable one-pot strategies.

Chem. Rev. 100 , 4465, (2000)


More Articles