Dicarbonylacetylacetonato rhodium(I)
Suppliers
Names
[ CAS No. ]:
14874-82-9
[ Name ]:
Dicarbonylacetylacetonato rhodium(I)
[Synonym ]:
Acetylacetonatorhodium(I) dicarbonyl
[4-(Hydroxy-κO)-3-penten-2-onato]rhodium - carbon monooxide (1:2)
Dicarbonylacetylacetonato rhodium(I)
Dicarbonyl(2,4-pentanedionato)rhodium(I)
EINECS 238-947-9
MFCD00009884
Chemical & Physical Properties
[ Melting Point ]:
154-156ºC
[ Molecular Formula ]:
C7H7O4Rh
[ Molecular Weight ]:
258.034
[ Exact Mass ]:
257.939941
[ PSA ]:
26.30000
[ LogP ]:
0.54410
[ Water Solubility ]:
insoluble
MSDS
Safety Information
[ Symbol ]:
GHS06
[ Signal Word ]:
Danger
[ Hazard Statements ]:
H301-H315-H317-H319-H335
[ Supplemental HS ]:
Risk of explosion if heated under confinement.
[ Precautionary Statements ]:
P261-P280-P301 + P310-P305 + P351 + P338
[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves
[ Hazard Codes ]:
Xi:Irritant;
[ Risk Phrases ]:
R36/37/38
[ Safety Phrases ]:
S26-S37/39
[ RIDADR ]:
UN 3282
[ WGK Germany ]:
3
[ Packaging Group ]:
III
[ Hazard Class ]:
6.1
Articles
J. Phys. Chem. A 112(28) , 6320-9, (2008)
Triply vibrationally enhanced four-wave mixing spectroscopy is employed to observe vibrational coherence transfer between the asymmetric and symmetric CO-stretching modes of rhodium(I) dicarbonyl acet...
Phys. Rev. Lett. 86(17) , 3899-902, (2001)
2D spectrally resolved ultrafast (<200 fs) IR vibrational echo experiments were performed on Rh(CO)(2)acac [(acetylacetonato)dicarbonylrhodium (I)]. The 2D spectra display features that reflect the 0-...
Horvath, I.T. et al.J. Am. Chem. Soc. 120 , 3133, (1998)