Dicarbonylacetylacetonato rhodium(I)

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Names

[ CAS No. ]:
14874-82-9

[ Name ]:
Dicarbonylacetylacetonato rhodium(I)

[Synonym ]:
Acetylacetonatorhodium(I) dicarbonyl
[4-(Hydroxy-κO)-3-penten-2-onato]rhodium - carbon monooxide (1:2)
Dicarbonylacetylacetonato rhodium(I)
Dicarbonyl(2,4-pentanedionato)rhodium(I)
EINECS 238-947-9
MFCD00009884

Chemical & Physical Properties

[ Melting Point ]:
154-156ºC

[ Molecular Formula ]:
C7H7O4Rh

[ Molecular Weight ]:
258.034

[ Exact Mass ]:
257.939941

[ PSA ]:
26.30000

[ LogP ]:
0.54410

[ Water Solubility ]:
insoluble

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS06

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H301-H315-H317-H319-H335

[ Supplemental HS ]:
Risk of explosion if heated under confinement.

[ Precautionary Statements ]:
P261-P280-P301 + P310-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S37/39

[ RIDADR ]:
UN 3282

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
6.1

Articles

Frequency-domain time-resolved four wave mixing spectroscopy of vibrational coherence transfer with single-color excitation.

J. Phys. Chem. A 112(28) , 6320-9, (2008)

Triply vibrationally enhanced four-wave mixing spectroscopy is employed to observe vibrational coherence transfer between the asymmetric and symmetric CO-stretching modes of rhodium(I) dicarbonyl acet...

Two-dimensional time-frequency ultrafast infrared vibrational echo spectroscopy.

Phys. Rev. Lett. 86(17) , 3899-902, (2001)

2D spectrally resolved ultrafast (<200 fs) IR vibrational echo experiments were performed on Rh(CO)(2)acac [(acetylacetonato)dicarbonylrhodium (I)]. The 2D spectra display features that reflect the 0-...

Horvath, I.T. et al.

J. Am. Chem. Soc. 120 , 3133, (1998)


More Articles

Related Compounds

  • dicarbonyldiphenylaminedithiocarbamate rhodium(I)
  • (tetramesitylporphyrinato)rhodium(I)
  • NITROSYLTRIS(TRIPHENYLPHOSPHINE)RHODIUM(I)
  • acetylacetonato(norbornadiene)rhodium(i)
  • Hydridotetrakis(triphenylphosphine)rhodium(I)
  • DICARBONYL(PENTAMETHYLCYCLOPENTADIENYL)RHODIUM (I)
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