(R)-(-)-2-Butanol

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Names

[ CAS No. ]:
14898-79-4

[ Name ]:
(R)-(-)-2-Butanol

[Synonym ]:
L-Proline, 1-methyl-, hydrate (1:1)
(R)-(-)-sec-Butanol
R-(-)-2-Butanol
(R)-(-)-sec-Butyl Alcohol
1-Methyl-L-proline hydrate (1:1)
MFCD00064280
(R)-(-)-2-Butanol
EINECS 238-967-8

Chemical & Physical Properties

[ Density]:
0.807

[ Boiling Point ]:
99-100ºC

[ Melting Point ]:
-114ºC

[ Molecular Formula ]:
C4H10O

[ Molecular Weight ]:
147.172

[ Flash Point ]:
26ºC

[ Exact Mass ]:
147.089539

[ PSA ]:
20.23000

[ LogP ]:
0.77720

[ Vapour Pressure ]:
25.2mmHg at 25°C

[ Index of Refraction ]:
1.396-1.398

[ Storage condition ]:
2~8℃

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02, GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H226-H319-H335-H335 + H336-H336

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R10;R36/37;R67

[ Safety Phrases ]:
S13-S24/25-S26-S7/9

[ RIDADR ]:
UN 1120

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
3.0

[ HS Code ]:
2905199090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 2-Butanone
  • (±)-2-Butanol
  • (R)-((sec-butoxymethoxy)methyl)benzene
  • cis-2-butene
  • Methyl vinyl ketone
  • (R)-(+)-3-Butyn-2-ol
  • (R)-(+)-Propylene oxide
  • 2-butene

DownStream

  • 2-Iodobutane
  • 2-Butanone
  • 2-Bromobutane
  • [R,(-)]-2-Bromobutane
  • Phosphine oxide, 1,1'-(1,2-ethanediyl)bis[diphenyl-
  • (R)-sec-Butyl 4-methylbenzenesulfonate

Customs

[ HS Code ]: 2905199090

[ Summary ]:
2905199090. saturated monohydric alcohols. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

Articles

The substrate binding cavity of particulate methane monooxygenase from Methylosinus trichosporium OB3b expresses high enantioselectivity for n-butane and n-pentane oxidation to 2-alcohol.

Biotechnol. Lett. 33(11) , 2241-6, (2011)

The particulate methane monooxygenase (pMMO) of Methylosinus trichosporium OB3b oxidized n-butane and n-pentane and mainly produced (R)-2-butanol and (R)-2-pentanol that comprised 78 and 89% of the pr...

Human phosphoglycerate dehydrogenase produces the oncometabolite D-2-hydroxyglutarate.

ACS Chem. Biol. 10(2) , 510-6, (2015)

Human d-3-phosphoglycerate dehydrogenase (PHGDH), the first enzyme in the serine biosynthetic pathway, is genomically amplified in tumors including breast cancer and melanoma. In PHGDH-amplified cance...

Interplay of metalloligand and organic ligand to tune micropores within isostructural mixed-metal organic frameworks (M'MOFs) for their highly selective separation of chiral and achiral small molecules.

J. Am. Chem. Soc. 134(20) , 8703-10, (2012)

Four porous isostructural mixed-metal-organic frameworks (M'MOFs) have been synthesized and structurally characterized. The pores within these M'MOFs are systematically tuned by the interplay of both ...


More Articles

Related Compounds

  • (R)-(-)-2-Amino-1-butanol
  • [R,(-)]-2,3-Dimethyl-1-butanol
  • (r)-2-(dibenzylamino)-3-methyl-1-butanol
  • (R)-2,3-Dimethyl-4-(triphenylphosphoranylidene)-2-butanol
  • (R)-2-[[(4-Chlorophenyl)methyl]amino]-1-butanol
  • (R)-2,3-dimethyl-4-phenylthio-2-butanol