4-(methylsulfonyl)phenylboronic acid

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Names

[ CAS No. ]:
149104-88-1

[ Name ]:
4-(methylsulfonyl)phenylboronic acid

[Synonym ]:
4-(Methylsu
4-(Methanesulfonyl)phenylboronic acid
(4-(Methylsulfonyl)phenyl)boronic acid
4-(Methylsulfonyl)phenylboronic Acid
4-(Methanesulfonyl)benzeneboronic Acid
MFCD01630820
(4-methylsulfonylphenyl)boronic acid

Chemical & Physical Properties

[ Density]:
1.4±0.1 g/cm3

[ Boiling Point ]:
445.5±51.0 °C at 760 mmHg

[ Melting Point ]:
275-277 °C

[ Molecular Formula ]:
C7H9BO4S

[ Molecular Weight ]:
200.02

[ Flash Point ]:
223.2±30.4 °C

[ Exact Mass ]:
200.031464

[ PSA ]:
82.98000

[ LogP ]:
-0.13

[ Vapour Pressure ]:
0.0±1.1 mmHg at 25°C

[ Index of Refraction ]:
1.566

[ Storage condition ]:
0-6°C

MSDS

Safety Information

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S37/39-S26

[ RIDADR ]:
NONH for all modes of transport

[ HS Code ]:
2931900090

Synthetic Route

Precursor & DownStream

Precursor

  • trifluoro(4-(methylsulfonyl)phenyl)borate

DownStream

  • NMS-873
  • 6-(4-(METHYLSULFONYL)PHENYL)-2-PYRIDINE&
  • 4'-(METHYLSULFONYL)-[1,1'-BIPHENYL]-4-OL
  • 6-(4-(Methylsulfonyl)phenyl)pyridin-3-ol
  • 4-BROMO-4'-(METHYLSULFONYL)-1,1'-BIPHENYL
  • 1-(2-bromocyclopenten-1-yl)-4-methylsulfonylbenzene
  • 1-azido-4-methylsulfonylbenzene
  • 3-(4-Methanesulfonylphenyl)benzaldehyde
  • 2,2,2-trifluoro-1-(4'-(Methylsulfonyl)biphenyl-4-yl)ethanone

Customs

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

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J. Org. Chem. 76 , 8203-8214, (2011)

A regiocontrolled synthesis of unsymmetrical 3,4-diaryl-3-pyrrolin-2-ones has been achieved in three steps from 1,2-diaryl-1-nitroethenes with pyrrole-2-carboxamides (pyrrole Weinreb amides) serving a...


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Related Compounds

  • 2-Fluoro-4-(methylsulfonyl)phenylboronic acid
  • 2-Fluoro-4-(methylsulfonyl)phenylboronic Acid Pinacol Ester
  • 3-Fluoro-4-(methylsulfonyl)phenylboronic Acid Pinacol Ester
  • [4-methylsulfonyl-2-(trifluoromethyl)phenyl]boronic acid
  • {4-[(Methylsulfonyl)amino]phenyl}boronic acid
  • 4-Fluoro-3-(methylsulfonyl)phenylboronic acid pinacol ester
  • rel-(2R,3S)-3-(Ethoxycarbonyl)oxirane-2-carboxylic acid
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • N-[(2-bromophenyl)methyl]-5,6-dichloro-N-methylpyridine-3-carboxamide
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • tert-Butyl-DL-alanine