Chromyl chloride

Suppliers

Names

[ CAS No. ]:
14977-61-8

[ Name ]:
Chromyl chloride

[Synonym ]:
Chromyl chloride
chromium chloride
MFCD00010951
CHROMOUS CHLORIDE
chromium dichloride
chromylchloride
EINECS 239-056-8
chromium oxychloride

Chemical & Physical Properties

[ Density]:
1.91

[ Boiling Point ]:
117ºC

[ Melting Point ]:
-96.5ºC

[ Molecular Formula ]:
Cl2CrO2

[ Molecular Weight ]:
154.90100

[ Flash Point ]:
117ºC

[ Exact Mass ]:
153.86800

[ PSA ]:
34.14000

[ LogP ]:
1.14140

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
GB5775000
CHEMICAL NAME :
Chromium, dichlorodioxo-
CAS REGISTRY NUMBER :
14977-61-8
LAST UPDATED :
199712
DATA ITEMS CITED :
18
MOLECULAR FORMULA :
Cl2-Cr-O2
MOLECULAR WEIGHT :
154.90
WISWESSER LINE NOTATION :
CR G2 O2

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

MUTATION DATA

TYPE OF TEST :
Mutation in microorganisms
TEST SYSTEM :
Bacteria - Salmonella typhimurium
REFERENCE :
CRNGDP Carcinogenesis (London). (Oxford Univ. Press, Pinkhill House, Southfield Road, Eynsham, Oxford OX8 1JJ, UK) V.1- 1980- Volume(issue)/page/year: 1,583,1980 *** REVIEWS *** ACGIH TLV-TWA 0.16 mg/m3 (0.025 ppm) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 IARC Cancer Review:Human Sufficient Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 49,49,1990 IARC Cancer Review:Group 1 IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 49,49,1990 *** U.S. STANDARDS AND REGULATIONS *** OSHA PEL (Gen Indu):8H TWA 0.5 mg(Cr)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 0.5 mg(Cr)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 0.5 mg(Cr)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 0.5 mg(Cr)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-BELGIUM:TWA 0.025 ppm (0.16 mg/m3) JAN 1993 OEL-FINLAND;Carcinogen JAN 1993 OEL-GERMANY;Carcinogen JAN 1993 OEL-THE NETHERLANDS:TWA 0.025 ppm (0.15 mg/m3) JAN 1993 OEL-SWITZERLAND:TWA 0.05 mg/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO CHROMYL CHLORIDE-air:10H CA TWA 0.001 mg(Cr)/m3 REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992 NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X4593 No. of Facilities: 7 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 35 (estimated)

Safety Information

[ Symbol ]:

GHS03, GHS05, GHS07, GHS08, GHS09

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H271-H314-H317-H340-H350i-H410

[ Precautionary Statements ]:
P201-P210-P273-P280-P303 + P361 + P353-P305 + P351 + P338

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
O:Oxidizing;T:Toxic;N:Dangerousfortheenvironment;

[ Risk Phrases ]:
R35;R43;R46;R49;R50/53;R8

[ Safety Phrases ]:
S45-S53-S60-S61

[ RIDADR ]:
UN 3244 8/PG 2

[ WGK Germany ]:
3

[ RTECS ]:
GB5775000

[ Packaging Group ]:
I

[ Hazard Class ]:
8

[ HS Code ]:
2914700090

Synthetic Route

Precursor & DownStream

Precursor

  • Chromium(III) chloride
  • Chlorotrimethylsilane
  • dioxochloro(trimethylsiloxy)chromate(VI)
  • Chloroform
  • Oxalyl chloride
  • Sulfuric acid

DownStream

  • 2-Methyl-3-pentanone
  • 4-Methyl-2-pentanone
  • 3-Methyl-2-pentanone
  • Tritanol
  • Cyclohexanone
  • 2,4,5-Trimethoxybenzaldehyde
  • Stannane,chlorotriethyl-
  • 3-Methyl-2-butanone
  • b-Tetralone
  • 3,4-Dihydronaphthalen-1(2H)-one

Customs

[ HS Code ]: 2914700090

[ Summary ]:
HS: 2914700090 halogenated, sulphonated, nitrated or nitrosated derivatives of ketones and quinones, whether or not with other oxygen function Tax rebate rate:9.0% Supervision conditions:none VAT:17.0% MFN tariff:5.5% General tariff:30.0%


Related Compounds

  • chromyl chloride
  • Strontium chloride-Sr82
  • Benzoyl chloride, 4-(1-methylpropyl)- (9CI)
  • Benzenebutanoyl chloride, 3-chloro-
  • cyclopentadienylmagnesium chloride
  • Cyclohexanecarbonyl chloride, 2-(acetyloxy)-, trans- (9CI)
  • tert-butyl 3-phenyl-2,5-dihydro-1H-pyrrole-1-carboxylate
  • 7-(3',4',6'-Trimethyl-2',5'-dioxo-2',5'-dihydro-[1,1'-biphenyl]-3-yl)heptanoic acid
  • N-(3,4-dihydro-2H-pyrrol-5-yl)-1H-indol-6-amine
  • N-(3-(4-cyano-3-fluorophenyl)-1-isopropyl-1H-indol-6-yl)methanesulfonamide
  • N-(1-benzofuran-5-yl)-3,4-dihydro-2H-pyrrol-5-amine
  • N-methyl-(1-(naphthalen-2-yl)cyclohexyl)-methanamine
  • 3-(4-((5-Methyl-2-(4-(trifluoromethyl)phenyl)oxazol-4-yl)methoxy)benzyl)thiazolidine-4-carboxylic acid
  • 1-(5-Bromo-2-methoxyphenyl)guanidine
  • 4-bromo-N-methyl-N-(2-morpholin-4-yl-ethyl)-benzenesulfonamide
  • 2-(4-bromo-3,5-dimethylphenoxy)tetrahydro-2H-pyran
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