Glycinonitrile bisulfate

Suppliers

Names

[ CAS No. ]:
151-63-3

[ Name ]:
Glycinonitrile bisulfate

[Synonym ]:
Aminoacetonitrile bisulfate
EINECS 205-794-4
aminoacetonitrilesulfate(1:1)
Aminomethylcyanide Hydrogen Sulfate
2-Aminoacetonitrile sulfate
Aminoacetonitrile Hydrogen Sulfate
Aminoacetonitrile sulfate
amino-acetonitrilbisulfate
GLYCINONITRILESULFATE
AMINOACETONITRILE SULPHATE
aminoacetonitrile sulfuric acid salt
Glycinonitrile Hydrogen Sulfate
Aminoacetonitrile bisulphate
MFCD00012851
Acetonitrile, 2-amino-, sulfate (1:1)
cyanomethylammonium hydrogen sulfate
Glycinonitrile bisulfate
AMinoacetonitril bisulfat
cyanomethylammonium hydrogenesulfate
Glycinonitrile sulphate
Aminoacetonitrile monosulfate
Aminoacetonitrile hydrogensulfate
Aminoacetonitrile sulfate (1:1)
Cyanomethylamine hydrogen sulfate
aminoacetonitrile hydrogen sulphate

Chemical & Physical Properties

[ Boiling Point ]:
330ºC at 760mmHg

[ Melting Point ]:
120-125 °C(lit.)

[ Molecular Formula ]:
C2H6N2O4S

[ Molecular Weight ]:
154.145

[ Flash Point ]:
208.5ºC

[ Exact Mass ]:
154.004822

[ PSA ]:
132.79000

[ LogP ]:
0.59698

[ Vapour Pressure ]:
3.35E-05mmHg at 25°C

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
AL7800000
CHEMICAL NAME :
Acetonitrile, amino-, bisulfate
CAS REGISTRY NUMBER :
151-63-3
LAST UPDATED :
199707
DATA ITEMS CITED :
5
MOLECULAR FORMULA :
C2-H4-N2.H2-O4-S
MOLECULAR WEIGHT :
154.16
WISWESSER LINE NOTATION :
Z1CN &..H2.S-O4

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
DOSE :
200 mg/kg
SEX/DURATION :
female 15 day(s) after conception
TOXIC EFFECTS :
Reproductive - Specific Developmental Abnormalities - craniofacial (including nose and tongue)
REFERENCE :
SHKKAN Shika Kiso Igakkai Zasshi. Journal of the Japanese Association for Basic Dentistry. (Shika Kiso Igakkai, Hanayama Bldg., 1-44-2 Komagome, Toshima-ku, Tokyo 170, Japan) V.1- 1959- Volume(issue)/page/year: 26,882,1984
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
DOSE :
400 mg/kg
SEX/DURATION :
female 7 day(s) after conception
TOXIC EFFECTS :
Reproductive - Fertility - post-implantation mortality (e.g. dead and/or resorbed implants per total number of implants) Reproductive - Effects on Embryo or Fetus - fetal death Reproductive - Specific Developmental Abnormalities - Central Nervous System
REFERENCE :
ACATA5 Acta Anatomica. (S. Karger Pub., Inc., 79 Fifth Ave., New York, NY 10003) V.1- 1945- Volume(issue)/page/year: 100,347,1978
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
DOSE :
400 mg/kg
SEX/DURATION :
female 7 day(s) after conception
TOXIC EFFECTS :
Reproductive - Specific Developmental Abnormalities - musculoskeletal system
REFERENCE :
ACATA5 Acta Anatomica. (S. Karger Pub., Inc., 79 Fifth Ave., New York, NY 10003) V.1- 1945- Volume(issue)/page/year: 100,347,1978
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
DOSE :
800 mg/kg
SEX/DURATION :
female 7 day(s) after conception
TOXIC EFFECTS :
Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death, e.g., stunted fetus)
REFERENCE :
ACATA5 Acta Anatomica. (S. Karger Pub., Inc., 79 Fifth Ave., New York, NY 10003) V.1- 1945- Volume(issue)/page/year: 100,347,1978 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X5761 No. of Facilities: 7 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 1822 (estimated) No. of Female Employees: 272 (estimated)

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
T:Toxic;

[ Risk Phrases ]:
R23/24

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ RTECS ]:
AL7800000

[ HS Code ]:
2926909090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Methylenaminoacetonitrile

DownStream

  • Benzyl (cyanomethyl)carbamate
  • methyl N-(cyanomethyl)carbamate
  • n-(cyanomethyl)acetamide
  • N-cyanomethyl-4-methyl-benzenesulfonamide
  • 2-chloro-N-(cyanomethyl)acetamide
  • N-(tert-Butoxycarbonyl)-2-aminoacetonitrile
  • Diphenylmethyleniminoacetonitrile
  • 2-[(4-nitrophenyl)amino]diazenylacetonitrile
  • Benzoicacid, 4-[3-(cyanomethyl)-2-triazen-1-yl]-, methylester
  • N-(cyanomethyl)-2,2,2-trifluoroacetamide

Customs

[ HS Code ]: 2926909090

[ Summary ]:
HS:2926909090 other nitrile-function compounds VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Related Compounds

  • Glycinonitrile, N-(4-methyl-2-pyridyl)- (6CI)
  • graphite bisulfate)
  • Sodium bisulfate
  • Potassium bisulfate
  • Sodium bisulfate monohydrate
  • quinine bisulfate heptahydrate