Nickel-triphenylphosphine (1:4)

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Names

[ Name ]:
Nickel-triphenylphosphine (1:4)

[Synonym ]:
Nickel - triphenylphosphine (1:4)
Phosphine, triphenyl-, nickel salt (4:1)
4-Methylsalicylic acid
Tetrakis(triphenylphosphine)nickel(0)
MFCD00010011
nickel,triphenylphosphane
Tetrakis(triphenylphosphine)nickel

Chemical & Physical Properties

[ Boiling Point ]:
360ºC at 760mmHg

[ Melting Point ]:
123-128ºC

[ Molecular Formula ]:
C₇₂H₆₀NiP₄

[ Molecular Weight ]:
1107.835

[ Flash Point ]:
181.7ºC

[ Exact Mass ]:
1106.299927

[ PSA ]:
54.36000

[ LogP ]:
13.77920

[ Appearance of Characters ]:
Fine Powder | Rust-brown to brown

[ Vapour Pressure ]:
4.74E-05mmHg at 25°C

[ Storage condition ]:
2-8°C

[ Water Solubility ]:
Insoluble in water.

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02, GHS07, GHS08

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H228-H317-H351

[ Precautionary Statements ]:
P210-P280

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Faceshields;Gloves

[ Hazard Codes ]:
Xn:Harmful;

[ Risk Phrases ]:
R40;R43

[ Safety Phrases ]:
S22-S36

[ RIDADR ]:
UN 1325

[ WGK Germany ]:
3

[ Packaging Group ]:
II

[ Hazard Class ]:
4.2

[ HS Code ]:
29319090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

ethene
4-Vinylcyclohexene
Nickel-acetic acid (1:1)
Bis(triphenylphosphine)dicarbonylnickel
N,N-diphenylaniline,nickel
Bis(triphenylphosphine)nickel(II)chloride
CHLOROTRIS(TRIPHENYLPHOSPHINE)COBALT(I)
chlorotris(triphenylphosphine)nickel

Articles

Iyoda, M.; Kuwatani, Y.; Oda, M.

J. Am. Chem. Soc. 111 , 3761, (1989)

Negishi, E-i.; Takahashi, et al.

J. Am. Chem. Soc. 109 , 2393, (1987)

Iyoda, M.; Tanaka, S. et al.

J. Am. Chem. Soc. 110 , 8494, (1988)