Nickel-triphenylphosphine (1:4)

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Names

[ CAS No. ]:
15133-82-1

[ Name ]:
Nickel-triphenylphosphine (1:4)

[Synonym ]:
Nickel - triphenylphosphine (1:4)
Phosphine, triphenyl-, nickel salt (4:1)
4-Methylsalicylic acid
Tetrakis(triphenylphosphine)nickel(0)
MFCD00010011
nickel,triphenylphosphane
Tetrakis(triphenylphosphine)nickel

Chemical & Physical Properties

[ Boiling Point ]:
360ºC at 760mmHg

[ Melting Point ]:
123-128ºC

[ Molecular Formula ]:
C72H60NiP4

[ Molecular Weight ]:
1107.835

[ Flash Point ]:
181.7ºC

[ Exact Mass ]:
1106.299927

[ PSA ]:
54.36000

[ LogP ]:
13.77920

[ Appearance of Characters ]:
Fine Powder | Rust-brown to brown

[ Vapour Pressure ]:
4.74E-05mmHg at 25°C

[ Storage condition ]:
2-8°C

[ Water Solubility ]:
Insoluble in water.

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02, GHS07, GHS08

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H228-H317-H351

[ Precautionary Statements ]:
P210-P280

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Faceshields;Gloves

[ Hazard Codes ]:
Xn:Harmful;

[ Risk Phrases ]:
R40;R43

[ Safety Phrases ]:
S22-S36

[ RIDADR ]:
UN 1325

[ WGK Germany ]:
3

[ Packaging Group ]:
II

[ Hazard Class ]:
4.2

[ HS Code ]:
29319090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Triphenylphosphine
  • 1,2,5,6-cyclooctanetetraylidene, nickel salt
  • Zinc
  • nickel(2+) dicyclopenta-2,4-dienide
  • Nickel(2+) acetylacetonate
  • Bis(triphenylphosphine)nickel(II)chloride
  • Nickel

DownStream

  • ethene
  • 4-Vinylcyclohexene
  • Nickel-acetic acid (1:1)
  • Bis(triphenylphosphine)dicarbonylnickel
  • N,N-diphenylaniline,nickel
  • Bis(triphenylphosphine)nickel(II)chloride
  • CHLOROTRIS(TRIPHENYLPHOSPHINE)COBALT(I)
  • chlorotris(triphenylphosphine)nickel

Articles

Iyoda, M.; Kuwatani, Y.; Oda, M.

J. Am. Chem. Soc. 111 , 3761, (1989)

Negishi, E-i.; Takahashi, et al.

J. Am. Chem. Soc. 109 , 2393, (1987)

Iyoda, M.; Tanaka, S. et al.

J. Am. Chem. Soc. 110 , 8494, (1988)


More Articles

Related Compounds

  • Platinum-triphenylphosphine (1:4)
  • Platinum-triphenylphosphine (1:4)
  • molybdenum,nickel (1:4)
  • cerium,nickel(1:4)
  • lanthanum,nickel (1:4)
  • nickel,tin (1:4)
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 3-(2-Chloro-5-methylphenyl)-2,2-dimethylpropan-1-ol
  • 2-{[4-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-1-methyl-1H-pyrazol-5-yl]formamido}-3,3,3-trifluoropropanoic acid
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • 3-(1-Cyclobutylpropoxy)-4-iodo-1lambda6-thiolane-1,1-dione