(1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE

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Names

[ Name ]:
(1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE

[Synonym ]:
(1S)-2-Isopropyl-5-methylcyclohexyl 4-methylbenzenesulfinate
Benzenesulfinic acid, 4-methyl-, (1R,2S,5R)-5-methyl-2-(1-methylethyl)cyclohexyl ester
(1R,2S,5R)-(-)-Menthyl (S)-p-Toluenesulfinate
MFCD00010192
(1R,2S,5R)-2-Isopropyl-5-methylcyclohexyl 4-methylbenzenesulfinate

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
402.3±38.0 °C at 760 mmHg

[ Melting Point ]:
99-104ºC

[ Molecular Formula ]:
C₁₇H₂₆O₂S

[ Molecular Weight ]:
294.452

[ Flash Point ]:
197.1±26.8 °C

[ Exact Mass ]:
294.165344

[ PSA ]:
45.51000

[ LogP ]:
5.25

[ Vapour Pressure ]:
0.0±0.9 mmHg at 25°C

[ Index of Refraction ]:
1.551

[ Storage condition ]:
-20°C

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ Hazard Codes ]:
Xi

[ Safety Phrases ]:
S22

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2930909090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

L-Menthol
Tosyl chloride
Tosyl cyanide
1-methyl-4-(4-methylphenyl)sulfonylsulfinylbenzene
4-Methylbenzenesulfinic acid
(1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE
4-Methylbenzenesulfinamide
N-(p-tolylsulfinylimino)triphenylphosphorane
P-TOLUENESULFINYL CHLORIDE

DownStream

Sulfinyldibenzene
2-[(S)-(4-methylphenyl)sulfinyl]-1H-pyrrole
L-Menthol
4-Methylbenzenesulfinamide
(SS)-(+)-N-(benzylidene)-p-toluenesulfinamide
P-toluenethiol
1-butylsulfinyl-4-methylbenzene
1-methyl-2-(4-methylphenyl)sulfinylbenzene

Customs

[ HS Code ]: 2930909090

[ Summary ]:
2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Articles

G. Solladié et al.

J. Org. Chem. 51 , 1912, (1986)

D.L. Fanelli et al.

Organic Synth. 77 , 50, (2000)

Y. Shinohara et al.

Synlett , 1245, (2002)

(1R,2S,5R)-menthyl (S)-p-bromobenzene sulfinate
(1R,2S,5R)-(-)-menthyl (S)-4-methoxyphenylsulfinate
(-)-(1R,2S,5R)-menthyl (S)-2-methoxynaphthalene-1-sulfinate
(1R,2S,5R)-(-)-menthyl (S)-2-hydroxy-2-(2-naphthyl)propionate
(1R,2S,5R)-menthyl-N-(diphenylmethylidene)-glycinate
(1R,2S,5R)-(-)-Menthyl amine
9-(1,3-Thiazol-2-yl)-2,5-dioxa-8-azaspiro[3.5]nonane
3-(2,3-Difluorophenyl)-4,4-difluorobutanoic acid
2,2-Dimethyl-3-(quinolin-2-yl)cyclopropane-1-carboxylic acid
1-[3-Fluoro-5-(trifluoromethyl)phenyl]-2,2-dimethylcyclopropane-1-carboxylic acid
4,4-difluoro-3-(1-methyl-1H-1,3-benzodiazol-5-yl)butanoic acid
2-{1-[2-(Dimethylamino)pyridin-3-yl]cyclobutyl}acetic acid
4,4-Difluoro-3-(1,3-thiazol-2-yl)butanoic acid
3-Methoxy-5-(4-methylphenyl)aniline
tert-butyl N-[3-(azetidin-3-yloxy)phenyl]carbamate
4-(1-Benzothiophen-2-yl)butan-2-one

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