(1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE

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Names

[ CAS No. ]:
1517-82-4

[ Name ]:
(1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE

[Synonym ]:
(1S)-2-Isopropyl-5-methylcyclohexyl 4-methylbenzenesulfinate
Benzenesulfinic acid, 4-methyl-, (1R,2S,5R)-5-methyl-2-(1-methylethyl)cyclohexyl ester
(1R,2S,5R)-(-)-Menthyl (S)-p-Toluenesulfinate
MFCD00010192
(1R,2S,5R)-2-Isopropyl-5-methylcyclohexyl 4-methylbenzenesulfinate

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
402.3±38.0 °C at 760 mmHg

[ Melting Point ]:
99-104ºC

[ Molecular Formula ]:
C17H26O2S

[ Molecular Weight ]:
294.452

[ Flash Point ]:
197.1±26.8 °C

[ Exact Mass ]:
294.165344

[ PSA ]:
45.51000

[ LogP ]:
5.25

[ Vapour Pressure ]:
0.0±0.9 mmHg at 25°C

[ Index of Refraction ]:
1.551

[ Storage condition ]:
-20°C

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ Hazard Codes ]:
Xi

[ Safety Phrases ]:
S22

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2930909090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • L-Menthol
  • Tosyl chloride
  • Tosyl cyanide
  • 1-methyl-4-(4-methylphenyl)sulfonylsulfinylbenzene
  • 4-Methylbenzenesulfinic acid
  • (1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE
  • 4-Methylbenzenesulfinamide
  • N-(p-tolylsulfinylimino)triphenylphosphorane
  • P-TOLUENESULFINYL CHLORIDE

DownStream

  • Sulfinyldibenzene
  • 2-[(S)-(4-methylphenyl)sulfinyl]-1H-pyrrole
  • L-Menthol
  • 4-Methylbenzenesulfinamide
  • (SS)-(+)-N-(benzylidene)-p-toluenesulfinamide
  • P-toluenethiol
  • 1-butylsulfinyl-4-methylbenzene
  • 1-methyl-2-(4-methylphenyl)sulfinylbenzene

Customs

[ HS Code ]: 2930909090

[ Summary ]:
2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Articles

G. Solladié et al.

J. Org. Chem. 51 , 1912, (1986)

D.L. Fanelli et al.

Organic Synth. 77 , 50, (2000)

Y. Shinohara et al.

Synlett , 1245, (2002)


More Articles

Related Compounds

  • (1R,2S,5R)-menthyl (S)-p-bromobenzene sulfinate
  • (1R,2S,5R)-(-)-menthyl (S)-4-methoxyphenylsulfinate
  • (-)-(1R,2S,5R)-menthyl (S)-2-methoxynaphthalene-1-sulfinate
  • (1R,2S,5R)-(-)-menthyl (S)-2-hydroxy-2-(2-naphthyl)propionate
  • (1R,2S,5R)-menthyl-N-(diphenylmethylidene)-glycinate
  • (1R,2S,5R)-(-)-Menthyl amine
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 2-Bromo-3-chloro-7-ethyl-6,7-dihydro-5H-cyclopenta[b]pyridin-7-ol
  • 1,1,1-trifluoro-3-(1-methyl-1H-imidazol-4-yl)propan-2-amine
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • tert-Butyl-DL-alanine